Phosphotungstic Acid Immobilized on Ionic Liquid-Modified SBA-15: Efficient Hydrophobic Heterogeneous Catalyst for Oxidative Desulfurization in Fuel

A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-r...

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Published inIndustrial & engineering chemistry research Vol. 53; no. 51; pp. 19895 - 19904
Main Authors Xiong, Jun, Zhu, Wenshuai, Ding, Wenjing, Yang, Lei, Chao, Yanhong, Li, Hongping, Zhu, Fengxia, Li, Huaming
Format Journal Article
LanguageEnglish
Published American Chemical Society 24.12.2014
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Abstract A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity.
AbstractList A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N sub(2) adsorption-desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 degree C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity.
A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N₂ adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity.
A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity.
Author Chao, Yanhong
Yang, Lei
Li, Hongping
Li, Huaming
Xiong, Jun
Zhu, Wenshuai
Ding, Wenjing
Zhu, Fengxia
AuthorAffiliation Jiangsu University
Huaiyin Normal University
School of Chemistry and Chemical Engineering
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Snippet A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative...
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SubjectTerms Catalysts
Contact angle
desulfurization
Desulfurizing
Diffraction
engineering
Fourier transform infrared spectroscopy
fuels
hydrophobicity
ionic liquids
nitrogen
oils
phosphotungstic acid
porous media
Scanning electron microscopy
silica
surface area
transmission electron microscopy
Wettability
X-ray diffraction
X-ray photoelectron spectroscopy
X-rays
Title Phosphotungstic Acid Immobilized on Ionic Liquid-Modified SBA-15: Efficient Hydrophobic Heterogeneous Catalyst for Oxidative Desulfurization in Fuel
URI http://dx.doi.org/10.1021/ie503322a
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Volume 53
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