Phosphotungstic Acid Immobilized on Ionic Liquid-Modified SBA-15: Efficient Hydrophobic Heterogeneous Catalyst for Oxidative Desulfurization in Fuel
A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-r...
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Published in | Industrial & engineering chemistry research Vol. 53; no. 51; pp. 19895 - 19904 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
24.12.2014
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Subjects | |
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Abstract | A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity. |
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AbstractList | A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N sub(2) adsorption-desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 degree C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity. A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N₂ adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity. A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative desulfurization. Structure and properties of catalyst were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the contact angle. The results demonstrated that the synthesized catalyst possessed ordered mesopore structure and high special surface area. Due to the introduction of imidazole-based ionic liquid, the catalyst exhibited good wettability for model oil, which had significant contribution to desulfurization activity. Both DBT and 4,6-DMDBT could be removed completely at mild conditions (60 °C, 40 min). The removal of BT also can reach 81.3% within 60 min. Furthermore, the catalyst was recovered and reused in four reaction runs with a slight decrease in activity. |
Author | Chao, Yanhong Yang, Lei Li, Hongping Li, Huaming Xiong, Jun Zhu, Wenshuai Ding, Wenjing Zhu, Fengxia |
AuthorAffiliation | Jiangsu University Huaiyin Normal University School of Chemistry and Chemical Engineering |
AuthorAffiliation_xml | – name: Huaiyin Normal University – name: Jiangsu University – name: School of Chemistry and Chemical Engineering |
Author_xml | – sequence: 1 givenname: Jun surname: Xiong fullname: Xiong, Jun organization: Jiangsu University – sequence: 2 givenname: Wenshuai surname: Zhu fullname: Zhu, Wenshuai email: zhuws@ujs.edu.cn organization: Jiangsu University – sequence: 3 givenname: Wenjing surname: Ding fullname: Ding, Wenjing organization: Jiangsu University – sequence: 4 givenname: Lei surname: Yang fullname: Yang, Lei organization: Jiangsu University – sequence: 5 givenname: Yanhong surname: Chao fullname: Chao, Yanhong organization: Jiangsu University – sequence: 6 givenname: Hongping surname: Li fullname: Li, Hongping organization: Jiangsu University – sequence: 7 givenname: Fengxia surname: Zhu fullname: Zhu, Fengxia organization: Huaiyin Normal University – sequence: 8 givenname: Huaming surname: Li fullname: Li, Huaming email: lihm@ujs.edu.cn organization: Jiangsu University |
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Snippet | A heterogeneous catalyst system was synthesized by immobilizing phosphotungstic acid on ionic liquid-modified mesoporous silica SBA-15 and applied in oxidative... |
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SubjectTerms | Catalysts Contact angle desulfurization Desulfurizing Diffraction engineering Fourier transform infrared spectroscopy fuels hydrophobicity ionic liquids nitrogen oils phosphotungstic acid porous media Scanning electron microscopy silica surface area transmission electron microscopy Wettability X-ray diffraction X-ray photoelectron spectroscopy X-rays |
Title | Phosphotungstic Acid Immobilized on Ionic Liquid-Modified SBA-15: Efficient Hydrophobic Heterogeneous Catalyst for Oxidative Desulfurization in Fuel |
URI | http://dx.doi.org/10.1021/ie503322a https://www.proquest.com/docview/1701010927 https://www.proquest.com/docview/2045833028 |
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