MOF Linker Extension Strategy for Enhanced Atmospheric Water Harvesting

• Published in: ACS central science Vol. 9; no. 3; pp. 551 - 557
• Main Authors: Hanikel, Nikita, Kurandina, Daria, Chheda, Saumil, Zheng, Zhiling, Rong, Zichao, Neumann, S. Ephraim, Sauer, Joachim, Siepmann, J. Ilja, Gagliardi, Laura, Yaghi, Omar M.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 22.03.2023; American Chemical Society (ACS)
• Subjects: Adsorption; Aluminum; Arid environments; Atmospheric water; Chemistry; Density functional theory; Energy consumption; Humidity; Hydrogen bonds; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Metal-organic frameworks; Monte Carlo simulation; Pyrazole; Pyrazoles; Water harvesting

A linker extension strategy for generating metal–organic frameworks (MOFs) with superior moisture-capturing properties is presented. Applying this design approach involving experiment and computation results in MOF-LA2-1 {[Al­(OH)­(PZVDC)], where PZVDC2– is (E)-5-(2-carboxylatovinyl)-1H-pyrazole-3-c...