Source of highly potassic basalts in northeast China: Evidence from Re–Os, Sr–Nd–Hf isotopes and PGE geochemistry
The origin of the very young (0.5Ma to 1721AD) Wudalianchi-Erkeshan (WDLC and EKS) highly potassic basalts in northeast (NE) China has been the subject of considerable debate. In this study, we present new major-, trace- and platinum group element (PGE) data together with Re–Os, Lu–Hf, and Sr–Nd iso...
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| Published in | Chemical geology Vol. 357; pp. 52 - 66 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
24.10.2013
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| Abstract | The origin of the very young (0.5Ma to 1721AD) Wudalianchi-Erkeshan (WDLC and EKS) highly potassic basalts in northeast (NE) China has been the subject of considerable debate. In this study, we present new major-, trace- and platinum group element (PGE) data together with Re–Os, Lu–Hf, and Sr–Nd isotopic analyses for these potassic basalts in order to further constrain their source. It has been shown that the WDLC and EKS basalts have unradiogenic to only moderately radiogenic osmium isotope ratios with 187Os/188Os ranging from 0.1187 to ~0.17, and only slight PPGE (Pt and Pd) enrichments relative to IPGE (Os, Ir and Ru). The positive correlations between 187Os/188Os and 1/Os suggests that these basalts have probably experienced about 2–8% of lower continental crust addition during magma ascent. On the other hand, the incorporation of sub-continental lithospheric mantle (SCLM)-derived, primary sulphides and/or PGE micro-alloys during magma ascent seems likely in some basalts, which preserve particularly unradiogenic Os compositions. The complex interplay of signatures derived from crustal and SCLM contamination means that the Os isotope systematics of the basalts do not unequivocally fingerprint the source of the WDLC and EKS basalts.
The strong enrichments of light rare earth elements (LREE) and large ion lithophile elements (LILE), high-K, EM1-like Sr–Nd–Hf isotopic characteristics, and particularly strong fractionation of the heavy REE ((Sm/Yb)N=9.7±0.6), suggest that the WDLC and EKS basalts mainly originated from phlogopite-bearing garnet-peridotite in the SCLM. Combined with low Ce/Pb ratios (~9.4–13.5), the most likely source of WDLC and EKS basalts is SCLM that has been metasomatized by delaminated old, lower continental crust. This is different from previous hypotheses that implicate a dominantly asthenospheric source with a contribution from delaminated ancient SCLM or subducted oceanic crust with sediments, or a SCLM source that has been metasomatized by melts derived from deep asthenosphere during the Proterozoic.
•Unradiogenic to only moderately radiogenic Os isotopic compositions•Only slight PPGE (Pt and Pd) enrichments relative to IPGE (Ir, Os and Ru)•Minor lower crustal contamination reflected by Os isotopes and Pd/Ir ratios•The old lower crust in WEK area has foundered together with SCLM.•The newly-formed SCLM has been metasomatized by delaminated old lower crust. |
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| AbstractList | The origin of the very young (0.5Ma to 1721AD) Wudalianchi-Erkeshan (WDLC and EKS) highly potassic basalts in northeast (NE) China has been the subject of considerable debate. In this study, we present new major-, trace- and platinum group element (PGE) data together with Re-Os, Lu-Hf, and Sr-Nd isotopic analyses for these potassic basalts in order to further constrain their source. It has been shown that the WDLC and EKS basalts have unradiogenic to only moderately radiogenic osmium isotope ratios with 187Os/188Os ranging from 0.1187 to ~0.17, and only slight PPGE (Pt and Pd) enrichments relative to IPGE (Os, Ir and Ru). The positive correlations between 187Os/188Os and 1/Os suggests that these basalts have probably experienced about 2-8% of lower continental crust addition during magma ascent. On the other hand, the incorporation of sub-continental lithospheric mantle (SCLM)-derived, primary sulphides and/or PGE micro-alloys during magma ascent seems likely in some basalts, which preserve particularly unradiogenic Os compositions. The complex interplay of signatures derived from crustal and SCLM contamination means that the Os isotope systematics of the basalts do not unequivocally fingerprint the source of the WDLC and EKS basalts. The strong enrichments of light rare earth elements (LREE) and large ion lithophile elements (LILE), high-K, EM1-like Sr-Nd-Hf isotopic characteristics, and particularly strong fractionation of the heavy REE ((Sm/Yb)N =9.7 plus or minus 0.6), suggest that the WDLC and EKS basalts mainly originated from phlogopite-bearing garnet-peridotite in the SCLM. Combined with low Ce/Pb ratios (~9.4-13.5), the most likely source of WDLC and EKS basalts is SCLM that has been metasomatized by delaminated old, lower continental crust. This is different from previous hypotheses that implicate a dominantly asthenospheric source with a contribution from delaminated ancient SCLM or subducted oceanic crust with sediments, or a SCLM source that has been metasomatized by melts derived from deep asthenosphere during the Proterozoic. The origin of the very young (0.5Ma to 1721AD) Wudalianchi-Erkeshan (WDLC and EKS) highly potassic basalts in northeast (NE) China has been the subject of considerable debate. In this study, we present new major-, trace- and platinum group element (PGE) data together with Re–Os, Lu–Hf, and Sr–Nd isotopic analyses for these potassic basalts in order to further constrain their source. It has been shown that the WDLC and EKS basalts have unradiogenic to only moderately radiogenic osmium isotope ratios with ¹⁸⁷Os/¹⁸⁸Os ranging from 0.1187 to ~0.17, and only slight PPGE (Pt and Pd) enrichments relative to IPGE (Os, Ir and Ru). The positive correlations between ¹⁸⁷Os/¹⁸⁸Os and 1/Os suggests that these basalts have probably experienced about 2–8% of lower continental crust addition during magma ascent. On the other hand, the incorporation of sub-continental lithospheric mantle (SCLM)-derived, primary sulphides and/or PGE micro-alloys during magma ascent seems likely in some basalts, which preserve particularly unradiogenic Os compositions. The complex interplay of signatures derived from crustal and SCLM contamination means that the Os isotope systematics of the basalts do not unequivocally fingerprint the source of the WDLC and EKS basalts. The strong enrichments of light rare earth elements (LREE) and large ion lithophile elements (LILE), high-K, EM1-like Sr–Nd–Hf isotopic characteristics, and particularly strong fractionation of the heavy REE ((Sm/Yb)N=9.7±0.6), suggest that the WDLC and EKS basalts mainly originated from phlogopite-bearing garnet-peridotite in the SCLM. Combined with low Ce/Pb ratios (~9.4–13.5), the most likely source of WDLC and EKS basalts is SCLM that has been metasomatized by delaminated old, lower continental crust. This is different from previous hypotheses that implicate a dominantly asthenospheric source with a contribution from delaminated ancient SCLM or subducted oceanic crust with sediments, or a SCLM source that has been metasomatized by melts derived from deep asthenosphere during the Proterozoic. The origin of the very young (0.5Ma to 1721AD) Wudalianchi-Erkeshan (WDLC and EKS) highly potassic basalts in northeast (NE) China has been the subject of considerable debate. In this study, we present new major-, trace- and platinum group element (PGE) data together with Re–Os, Lu–Hf, and Sr–Nd isotopic analyses for these potassic basalts in order to further constrain their source. It has been shown that the WDLC and EKS basalts have unradiogenic to only moderately radiogenic osmium isotope ratios with 187Os/188Os ranging from 0.1187 to ~0.17, and only slight PPGE (Pt and Pd) enrichments relative to IPGE (Os, Ir and Ru). The positive correlations between 187Os/188Os and 1/Os suggests that these basalts have probably experienced about 2–8% of lower continental crust addition during magma ascent. On the other hand, the incorporation of sub-continental lithospheric mantle (SCLM)-derived, primary sulphides and/or PGE micro-alloys during magma ascent seems likely in some basalts, which preserve particularly unradiogenic Os compositions. The complex interplay of signatures derived from crustal and SCLM contamination means that the Os isotope systematics of the basalts do not unequivocally fingerprint the source of the WDLC and EKS basalts. The strong enrichments of light rare earth elements (LREE) and large ion lithophile elements (LILE), high-K, EM1-like Sr–Nd–Hf isotopic characteristics, and particularly strong fractionation of the heavy REE ((Sm/Yb)N=9.7±0.6), suggest that the WDLC and EKS basalts mainly originated from phlogopite-bearing garnet-peridotite in the SCLM. Combined with low Ce/Pb ratios (~9.4–13.5), the most likely source of WDLC and EKS basalts is SCLM that has been metasomatized by delaminated old, lower continental crust. This is different from previous hypotheses that implicate a dominantly asthenospheric source with a contribution from delaminated ancient SCLM or subducted oceanic crust with sediments, or a SCLM source that has been metasomatized by melts derived from deep asthenosphere during the Proterozoic. •Unradiogenic to only moderately radiogenic Os isotopic compositions•Only slight PPGE (Pt and Pd) enrichments relative to IPGE (Ir, Os and Ru)•Minor lower crustal contamination reflected by Os isotopes and Pd/Ir ratios•The old lower crust in WEK area has foundered together with SCLM.•The newly-formed SCLM has been metasomatized by delaminated old lower crust. |
| Author | Harvey, Jason Liu, Chuan-Zhou Yang, Yue-Heng Zhang, Yan-Long Wu, Fu-Yuan Guo, Jing-Hui Tian, Wei Chu, Zhu-Yin |
| Author_xml | – sequence: 1 givenname: Zhu-Yin surname: Chu fullname: Chu, Zhu-Yin email: zhychu@mail.igcas.ac.cn organization: State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China – sequence: 2 givenname: Jason surname: Harvey fullname: Harvey, Jason organization: School of Earth and Environment, University of Leeds, Leeds LS2 9JT, UK – sequence: 3 givenname: Chuan-Zhou surname: Liu fullname: Liu, Chuan-Zhou organization: State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China – sequence: 4 givenname: Jing-Hui surname: Guo fullname: Guo, Jing-Hui organization: State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China – sequence: 5 givenname: Fu-Yuan surname: Wu fullname: Wu, Fu-Yuan organization: State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China – sequence: 6 givenname: Wei surname: Tian fullname: Tian, Wei organization: Key Laboratory of Orogenic Belts and Crustal Evolution, MOE, School of Earth and Space Sciences, Peking University, Beijing 100871, China – sequence: 7 givenname: Yan-Long surname: Zhang fullname: Zhang, Yan-Long organization: College of Earth Sciences, Jilin University, Changchun 130026, China – sequence: 8 givenname: Yue-Heng surname: Yang fullname: Yang, Yue-Heng organization: State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China |
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| SubjectTerms | Ascent Basalt China Crusts Delaminating Enrichment fractionation geochemistry Isotopes lead Marine melting NE China osmium PGE platinum Potassic basalts Rare earth elements Re–Os isotopes sediments Sr–Nd–Hf isotopes Strontium sulfides Sulphide |
| Title | Source of highly potassic basalts in northeast China: Evidence from Re–Os, Sr–Nd–Hf isotopes and PGE geochemistry |
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