Structure–Activity Relationships for Rates of Aromatic Amine Oxidation by Manganese Dioxide

• Published in: Environmental science & technology Vol. 50; no. 10; pp. 5094 - 5102
• Main Authors: Salter-Blanc, Alexandra J, Bylaska, Eric J, Lyon, Molly A, Ness, Stuart C, Tratnyek, Paul G
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 17.05.2016; American Chemical Society (ACS)
• Subjects: Amines; aromatic amines; chlorine dioxide; Correlation analysis; Environmental impact; ENVIRONMENTAL SCIENCES; free radicals; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Kinetics; manganese dioxide; Oxidants; Oxidation; Oxidation-Reduction; ozone; phosphates; Quantitative Structure-Activity Relationship; quantitative structure-activity relationships; Studies

New energetic compounds are designed to minimize their potential environmental impacts, which includes their transformation and the fate and effects of their transformation products. The nitro groups of energetic compounds are readily reduced to amines, and the resulting aromatic amines are subject...