Enhanced Electrochemiluminescence of Porphyrin-Based Metal–Organic Frameworks Controlled via Coordination Modulation

• Published in: Analytical chemistry (Washington) Vol. 92; no. 2; pp. 1916 - 1924
• Main Authors: Cai, Wen-Rong, Zeng, Hai-Bo, Xue, Huai-Guo, Marks, Robert S, Cosnier, Serge, Zhang, Xue-Ji, Shan, Dan
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 21.01.2020
• Subjects: Chemical Sciences; Chemistry; Coordination; Coordination chemistry; coordination polymers; Crystal growth; Electrochemiluminescence; Emitters; Hydrogen peroxide; ions; ligands; Metal-organic frameworks; Morphology; Optoelectronics; solvents; spectroscopy; sulfonic acids; voltammetry; Zinc

Precise control over the composition, morphology, and size of porphyrin-based metal–organic frameworks is challenging, but the extension of these hybrid materials will enable the creation of novel electrochemiluminescence (ECL) emitters. The coordination of various entities is made from Zn2+ ions an...