A Truncated Manganese Spinel Cathode for Excellent Power and Lifetime in Lithium-Ion Batteries
Spinel-structured lithium manganese oxide (LiMn2O4) cathodes have been successfully commercialized for various lithium battery applications and are among the strongest candidates for emerging large-scale applications. Despite its various advantages including high power capability, however, LiMn2O4 c...
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Published in | Nano letters Vol. 12; no. 12; pp. 6358 - 6365 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
12.12.2012
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Subjects | |
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Abstract | Spinel-structured lithium manganese oxide (LiMn2O4) cathodes have been successfully commercialized for various lithium battery applications and are among the strongest candidates for emerging large-scale applications. Despite its various advantages including high power capability, however, LiMn2O4 chronically suffers from limited cycle life, originating from well-known Mn dissolution. An ironical feature with the Mn dissolution is that the surface orientations supporting Li diffusion and thus the power performance are especially vulnerable to the Mn dissolution, making both high power and long lifetime very difficult to achieve simultaneously. In this investigation, we address this contradictory issue of LiMn2O4 by developing a truncated octahedral structure in which most surfaces are aligned to the crystalline orientations with minimal Mn dissolution, while a small portion of the structure is truncated along the orientations to support Li diffusion and thus facilitate high discharge rate capabilities. When compared to control structures with much smaller dimensions, the truncated octahedral structure as large as 500 nm exhibits better performance in both discharge rate performance and cycle life, thus resolving the previously conflicting aspects of LiMn2O4. |
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AbstractList | Spinel-structured lithium manganese oxide (LiMn2O4) cathodes have been successfully commercialized for various lithium battery applications and are among the strongest candidates for emerging large-scale applications. Despite its various advantages including high power capability, however, LiMn2O4 chronically suffers from limited cycle life, originating from well-known Mn dissolution. An ironical feature with the Mn dissolution is that the surface orientations supporting Li diffusion and thus the power performance are especially vulnerable to the Mn dissolution, making both high power and long lifetime very difficult to achieve simultaneously. In this investigation, we address this contradictory issue of LiMn2O4 by developing a truncated octahedral structure in which most surfaces are aligned to the crystalline orientations with minimal Mn dissolution, while a small portion of the structure is truncated along the orientations to support Li diffusion and thus facilitate high discharge rate capabilities. When compared to control structures with much smaller dimensions, the truncated octahedral structure as large as 500 nm exhibits better performance in both discharge rate performance and cycle life, thus resolving the previously conflicting aspects of LiMn2O4. Spinel-structured lithium manganese oxide (LiMn(2)O(4)) cathodes have been successfully commercialized for various lithium battery applications and are among the strongest candidates for emerging large-scale applications. Despite its various advantages including high power capability, however, LiMn(2)O(4) chronically suffers from limited cycle life, originating from well-known Mn dissolution. An ironical feature with the Mn dissolution is that the surface orientations supporting Li diffusion and thus the power performance are especially vulnerable to the Mn dissolution, making both high power and long lifetime very difficult to achieve simultaneously. In this investigation, we address this contradictory issue of LiMn(2)O(4) by developing a truncated octahedral structure in which most surfaces are aligned to the crystalline orientations with minimal Mn dissolution, while a small portion of the structure is truncated along the orientations to support Li diffusion and thus facilitate high discharge rate capabilities. When compared to control structures with much smaller dimensions, the truncated octahedral structure as large as 500 nm exhibits better performance in both discharge rate performance and cycle life, thus resolving the previously conflicting aspects of LiMn(2)O(4). Spinel-structured lithium manganese oxide (LiMn sub(2)O sub(4)) cathodes have been successfully commercialized for various lithium battery applications and are among the strongest candidates for emerging large-scale applications. Despite its various advantages including high power capability, however, LiMn sub(2)O sub(4) chronically suffers from limited cycle life, originating from well-known Mn dissolution. An ironical feature with the Mn dissolution is that the surface orientations supporting Li diffusion and thus the power performance are especially vulnerable to the Mn dissolution, making both high power and long lifetime very difficult to achieve simultaneously. In this investigation, we address this contradictory issue of LiMn sub(2)O sub(4) by developing a truncated octahedral structure in which most surfaces are aligned to the crystalline orientations with minimal Mn dissolution, while a small portion of the structure is truncated along the orientations to support Li diffusion and thus facilitate high discharge rate capabilities. When compared to control structures with much smaller dimensions, the truncated octahedral structure as large as 500 nm exhibits better performance in both discharge rate performance and cycle life, thus resolving the previously conflicting aspects of LiMn sub(2)O sub(4). |
Author | Kim, Joo-Seong Cho, Woosuk Shin, Weon Ho Choi, Jang Wook Kim, KyungSu Kanno, Ryoji |
AuthorAffiliation | Tokyo Institute of Technology Korea Advanced Institute of Science and Technology (KAIST) Korea Electronics Technology Institute (KETI) |
AuthorAffiliation_xml | – name: Korea Advanced Institute of Science and Technology (KAIST) – name: Korea Electronics Technology Institute (KETI) – name: Tokyo Institute of Technology |
Author_xml | – sequence: 1 givenname: Joo-Seong surname: Kim fullname: Kim, Joo-Seong – sequence: 2 givenname: KyungSu surname: Kim fullname: Kim, KyungSu – sequence: 3 givenname: Woosuk surname: Cho fullname: Cho, Woosuk – sequence: 4 givenname: Weon Ho surname: Shin fullname: Shin, Weon Ho – sequence: 5 givenname: Ryoji surname: Kanno fullname: Kanno, Ryoji email: kanno@echem.titech.ac.jp, jangwookchoi@kaist.ac.kr – sequence: 6 givenname: Jang Wook surname: Choi fullname: Choi, Jang Wook email: kanno@echem.titech.ac.jp, jangwookchoi@kaist.ac.kr |
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Snippet | Spinel-structured lithium manganese oxide (LiMn2O4) cathodes have been successfully commercialized for various lithium battery applications and are among the... Spinel-structured lithium manganese oxide (LiMn(2)O(4)) cathodes have been successfully commercialized for various lithium battery applications and are among... Spinel-structured lithium manganese oxide (LiMn sub(2)O sub(4)) cathodes have been successfully commercialized for various lithium battery applications and are... |
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SubjectTerms | Applied sciences Cathodes Condensed matter: structure, mechanical and thermal properties Crystal structure Diffusion Diffusion in nanoscale solids Diffusion in solids Direct energy conversion and energy accumulation Discharge Dissolution Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Lithium-ion batteries Manganese Orientation Physics Spinel Transport properties of condensed matter (nonelectronic) |
Title | A Truncated Manganese Spinel Cathode for Excellent Power and Lifetime in Lithium-Ion Batteries |
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