Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E‑Alkenes - Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian; Ferrandon, Magali S; Webber, Thomas E; Platero-Prats, Ana E; Duan, Jiaxin; Garcia-Holley, Paula; Camaioni, Donald M; Chapman, Karena W; Delferro, Massimiliano; Farha, Omar K; et al. (Journal of the American Chemical Society, 2018)
Keywords: active sites; alkynes; catalysts; catalytic activity; Chemistry; Chemistry, Multidisciplinary; coordination polymers; hydrogenation; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Physical Sciences; Science & Technology; stereoselectivity; OXIDATION; PALLADIUM; PROPYNE; ETHYLENE; REDUCTION; PARTIAL HYDROGENATION; HETEROGENEOUS CATALYSIS; TRANS-HYDROGENATION; IDENTIFICATION; ATOMIC LAYER DEPOSITION