The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification

The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure–function correlation in the field of catalysis. Here, we significantly expand upon the number of...

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Published inJournal of the American Chemical Society Vol. 142; no. 1; pp. 242 - 250
Main Authors Kim, In Soo, Ahn, Sol, Vermeulen, Nicolaas A, Webber, Thomas E, Gallington, Leighanne C, Chapman, Karena W, Penn, R. Lee, Hupp, Joseph T, Farha, Omar K, Notestein, Justin M, Martinson, Alex B. F
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 08.01.2020
American Chemical Society (ACS)
Subjects
atomic layer deposition
Catalysis
catalytic activity
coordination polymers
functionalization
Gases - chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ligands
metal organic frameworks
Metal-Organic Frameworks - chemistry
metals
oxides
post-synthetic modification
precursors
screening
Structure-Activity Relationship
surface area
vapor phase
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Abstract The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure–function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
AbstractList The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. Furthermore, with a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure-function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. With a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.
Author Ahn, Sol
Vermeulen, Nicolaas A
Chapman, Karena W
Penn, R. Lee
Kim, In Soo
Gallington, Leighanne C
Hupp, Joseph T
Webber, Thomas E
Farha, Omar K
Notestein, Justin M
Martinson, Alex B. F
AuthorAffiliation Department of Chemistry
Department of Chemical and Biological Engineering
Materials Science Division
X-ray Science Division, Advanced Photon Source
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Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC)
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Snippet The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which...
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SubjectTerms atomic layer deposition
Catalysis
catalytic activity
coordination polymers
functionalization
Gases - chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ligands
metal organic frameworks
Metal-Organic Frameworks - chemistry
metals
oxides
post-synthetic modification
precursors
screening
Structure-Activity Relationship
surface area
vapor phase
Title The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification
URI http://dx.doi.org/10.1021/jacs.9b10034
https://www.ncbi.nlm.nih.gov/pubmed/31851505
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https://www.osti.gov/servlets/purl/1595952
Volume 142
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