Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting
Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new...
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| Published in | Journal of the American Chemical Society Vol. 140; no. 6; pp. 2085 - 2092 |
|---|---|
| Main Authors | , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
14.02.2018
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which π-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking. |
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| AbstractList | Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which π-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking.Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which π-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking. Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which π-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking. Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which π-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking. |
| Author | Hufnagel, Alexander G Kampmann, Jonathan Rotter, Julian M Peters, Kristina Böhm, Daniel Sick, Torben Herbert, Simon Bein, Thomas Döblinger, Markus Evans, Austin Calik, Mona Fattakhova-Rohlfing, Dina Medina, Dana D Kondofersky, Ilina Knochel, Paul |
| AuthorAffiliation | University of Munich (LMU) Forschungszentrum Jülich GmbH University of Duisburg-Essen Faculty of Engineering and Center for Nanointegration Duisburg-Essen (CENIDE) Department of Chemistry and Center for NanoScience (CeNS) Institute of Energy and Climate Research (IEK-1) Materials Synthesis and Processing |
| AuthorAffiliation_xml | – name: University of Duisburg-Essen – name: Faculty of Engineering and Center for Nanointegration Duisburg-Essen (CENIDE) – name: Institute of Energy and Climate Research (IEK-1) Materials Synthesis and Processing – name: Forschungszentrum Jülich GmbH – name: Department of Chemistry and Center for NanoScience (CeNS) – name: University of Munich (LMU) |
| Author_xml | – sequence: 1 givenname: Torben orcidid: 0000-0003-4684-7971 surname: Sick fullname: Sick, Torben organization: University of Munich (LMU) – sequence: 2 givenname: Alexander G orcidid: 0000-0003-4088-937X surname: Hufnagel fullname: Hufnagel, Alexander G organization: University of Munich (LMU) – sequence: 3 givenname: Jonathan surname: Kampmann fullname: Kampmann, Jonathan organization: University of Munich (LMU) – sequence: 4 givenname: Ilina surname: Kondofersky fullname: Kondofersky, Ilina organization: University of Munich (LMU) – sequence: 5 givenname: Mona surname: Calik fullname: Calik, Mona organization: University of Munich (LMU) – sequence: 6 givenname: Julian M surname: Rotter fullname: Rotter, Julian M organization: University of Munich (LMU) – sequence: 7 givenname: Austin surname: Evans fullname: Evans, Austin organization: University of Munich (LMU) – sequence: 8 givenname: Markus surname: Döblinger fullname: Döblinger, Markus organization: University of Munich (LMU) – sequence: 9 givenname: Simon surname: Herbert fullname: Herbert, Simon organization: University of Munich (LMU) – sequence: 10 givenname: Kristina surname: Peters fullname: Peters, Kristina organization: University of Munich (LMU) – sequence: 11 givenname: Daniel surname: Böhm fullname: Böhm, Daniel organization: University of Munich (LMU) – sequence: 12 givenname: Paul orcidid: 0000-0001-7913-4332 surname: Knochel fullname: Knochel, Paul organization: University of Munich (LMU) – sequence: 13 givenname: Dana D orcidid: 0000-0003-4759-8612 surname: Medina fullname: Medina, Dana D organization: University of Munich (LMU) – sequence: 14 givenname: Dina orcidid: 0000-0003-2008-0151 surname: Fattakhova-Rohlfing fullname: Fattakhova-Rohlfing, Dina email: d.fattakhova@fz-juelich.de organization: University of Duisburg-Essen – sequence: 15 givenname: Thomas orcidid: 0000-0001-7248-5906 surname: Bein fullname: Bein, Thomas email: bein@lmu.de organization: University of Munich (LMU) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29249151$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/ja510895m 10.1038/ncomms9508 10.1002/anie.201206817 10.1039/C4CP03946G 10.1002/anie.201406811 10.1021/jacs.5b04147 10.1021/ja511802c 10.1021/ja206846p 10.1002/chem.201504151 10.1039/C7CC01827D 10.1039/C6CE00193A 10.1038/nmat2317 10.1021/acs.chemmater.5b04388 10.1021/jacs.5b10708 10.1039/C4EE01019A 10.1039/C5EE02574E 10.1039/C7FD00051K 10.1021/ja409033p 10.1021/ja4103293 10.1021/ja3100319 10.1039/C3CC48813F 10.1021/ja411321s 10.1021/cm703099j 10.1021/ja805064f 10.1002/anie.201209513 10.1021/ja9015765 10.1039/C4SC00016A 10.1126/science.1120411 10.1021/ja409421d 10.1021/jacs.7b07489 10.1039/c3cc45217d 10.1021/ja5092936 10.1039/c0cc04057f 10.1038/ncomms5503 10.1021/ja8096256 10.1021/ja204728y 10.1021/la103541n 10.1039/C1EE02717D 10.1002/anie.201208514 10.1002/anie.201307443 10.1002/anie.200903886 10.1039/B719545C 10.1021/acsnano.6b07692 10.1021/jz502646d 10.1039/b718969a 10.1039/c2cc33583b 10.1021/ja509551m 10.1002/cssc.201000416 10.1021/ja509602c 10.1038/nchem.548 10.1021/ja502212v 10.1002/marc.201500270 10.1039/C7CC04515H 10.1021/nn5000223 10.1126/science.1251428 10.1007/s10008-012-1957-3 10.1126/science.1209816 10.1038/nchem.2444 |
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| Snippet | Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is... Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is... |
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| Title | Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting |
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