Asymmetric Total Synthesis of Cladosporin and Isocladosporin
The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield, respectively. The relative configuration of isocladosporin was determined via this total synthesis.
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| Published in | Journal of organic chemistry Vol. 77; no. 13; pp. 5656 - 5663 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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WASHINGTON
American Chemical Society
06.07.2012
Amer Chemical Soc |
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| Abstract | The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield, respectively. The relative configuration of isocladosporin was determined via this total synthesis. |
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| AbstractList | The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield, respectively. The relative configuration of isocladosporin was determined via this total synthesis. The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield, respectively. The relative configuration of isocladosporin was determined via this total synthesis.The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield, respectively. The relative configuration of isocladosporin was determined via this total synthesis. |
| Author | Zhao, Changgui Jing, Peng Yang, Juan Xie, Xingang Fang, Bowen Zheng, Huaiji She, Xuegong |
| AuthorAffiliation | Lanzhou University Lanzhou Institute of Chemical Physics |
| AuthorAffiliation_xml | – name: Lanzhou University – name: Lanzhou Institute of Chemical Physics |
| Author_xml | – sequence: 1 givenname: Huaiji surname: Zheng fullname: Zheng, Huaiji – sequence: 2 givenname: Changgui surname: Zhao fullname: Zhao, Changgui – sequence: 3 givenname: Bowen surname: Fang fullname: Fang, Bowen – sequence: 4 givenname: Peng surname: Jing fullname: Jing, Peng – sequence: 5 givenname: Juan surname: Yang fullname: Yang, Juan – sequence: 6 givenname: Xingang surname: Xie fullname: Xie, Xingang – sequence: 7 givenname: Xuegong surname: She fullname: She, Xuegong email: shexg@lzu.edu.cn |
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| Snippet | The first asymmetric total syntheses of cladosporin and isocladosporin were accomplished in 8 steps with 8% overall yield and 10 steps with 26% overall yield,... |
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| SubjectTerms | antibiotics chemical reactions Chemistry Chemistry, Organic Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Isocoumarins - chemical synthesis Isocoumarins - chemistry Molecular Structure Organic chemistry Physical Sciences Preparations and properties research methods Science & Technology Stereoisomerism |
| Title | Asymmetric Total Synthesis of Cladosporin and Isocladosporin |
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