Printed Electrode for Measuring Phosphate in Environmental Water
Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from agricultural run-off have contributed to the eutrophication of global surface waters. Phosphate environmental dissemination and eutrophication problems...
Saved in:
Published in | ACS omega Vol. 6; no. 17; pp. 11297 - 11306 |
---|---|
Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
04.05.2021
|
Online Access | Get full text |
Cover
Loading…
Abstract | Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from agricultural run-off have contributed to the eutrophication of global surface waters. Phosphate environmental dissemination and eutrophication problems are not yet well understood. Thus, this study aimed to monitor phosphate in the local watershed to help identify potential hot spots in the local community (Mississippi River, Louisiana) that may contribute to nutrient loading downstream (in the Gulf of Mexico). An electrochemical method using a physical vapor deposited cobalt microelectrode was utilized for phosphate detection using cyclic voltammetry and amperometry. The testing results were utilized to evaluate the phosphate distribution in river water and characterize the performance of the microsensor. Various characterizations, including the limit of detection, sensitivity, and reliability, were conducted by measuring the effect of interferences, including dissolved oxygen, pH, and common ions. The electrochemical sensor performance was validated by comparing the results with the standard colorimetry phosphate detection method. X-ray photoelectron spectroscopy (XPS) measurements were performed to understand the phosphate sensing mechanism on the cobalt electrode. This proof-of-concept sensor chip could be utilized for on-field monitoring using a portable, hand-held potentiostat. |
---|---|
AbstractList | Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from agricultural run-off have contributed to the eutrophication of global surface waters. Phosphate environmental dissemination and eutrophication problems are not yet well understood. Thus, this study aimed to monitor phosphate in the local watershed to help identify potential hot spots in the local community (Mississippi River, Louisiana) that may contribute to nutrient loading downstream (in the Gulf of Mexico). An electrochemical method using a physical vapor deposited cobalt microelectrode was utilized for phosphate detection using cyclic voltammetry and amperometry. The testing results were utilized to evaluate the phosphate distribution in river water and characterize the performance of the microsensor. Various characterizations, including the limit of detection, sensitivity, and reliability, were conducted by measuring the effect of interferences, including dissolved oxygen, pH, and common ions. The electrochemical sensor performance was validated by comparing the results with the standard colorimetry phosphate detection method. X-ray photoelectron spectroscopy (XPS) measurements were performed to understand the phosphate sensing mechanism on the cobalt electrode. This proof-of-concept sensor chip could be utilized for on-field monitoring using a portable, hand-held potentiostat. Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from agricultural run-off have contributed to the eutrophication of global surface waters. Phosphate environmental dissemination and eutrophication problems are not yet well understood. Thus, this study aimed to monitor phosphate in the local watershed to help identify potential hot spots in the local community (Mississippi River, Louisiana) that may contribute to nutrient loading downstream (in the Gulf of Mexico). An electrochemical method using a physical vapor deposited cobalt microelectrode was utilized for phosphate detection using cyclic voltammetry and amperometry. The testing results were utilized to evaluate the phosphate distribution in river water and characterize the performance of the microsensor. Various characterizations, including the limit of detection, sensitivity, and reliability, were conducted by measuring the effect of interferences, including dissolved oxygen, pH, and common ions. The electrochemical sensor performance was validated by comparing the results with the standard colorimetry phosphate detection method. X-ray photoelectron spectroscopy (XPS) measurements were performed to understand the phosphate sensing mechanism on the cobalt electrode. This proof-of-concept sensor chip could be utilized for on-field monitoring using a portable, hand-held potentiostat. |
Author | Hasan, Syed Mohammad Abid Prasad, Alisha Gartia, Manas Ranjan Figueiredo Stofela, Sara Karoline Chaichi, Ardalan Liu, Gang Logan Maiti, Kanchan Sahu, Sushant P Bam, Wokil McPeak, Kevin M |
AuthorAffiliation | Department of Electrical and Computer Engineering Department of Chemical Engineering Department of Oceanography and Coastal Sciences Louisiana State University Department of Mechanical and Industrial Engineering |
AuthorAffiliation_xml | – name: Department of Mechanical and Industrial Engineering – name: Department of Oceanography and Coastal Sciences – name: Department of Electrical and Computer Engineering – name: Department of Chemical Engineering – name: Louisiana State University |
Author_xml | – sequence: 1 givenname: Alisha surname: Prasad fullname: Prasad, Alisha organization: Department of Mechanical and Industrial Engineering – sequence: 2 givenname: Sushant P surname: Sahu fullname: Sahu, Sushant P organization: Department of Mechanical and Industrial Engineering – sequence: 3 givenname: Sara Karoline surname: Figueiredo Stofela fullname: Figueiredo Stofela, Sara Karoline organization: Department of Chemical Engineering – sequence: 4 givenname: Ardalan orcidid: 0000-0002-0000-3637 surname: Chaichi fullname: Chaichi, Ardalan organization: Department of Mechanical and Industrial Engineering – sequence: 5 givenname: Syed Mohammad Abid orcidid: 0000-0001-6546-8075 surname: Hasan fullname: Hasan, Syed Mohammad Abid organization: Department of Mechanical and Industrial Engineering – sequence: 6 givenname: Wokil orcidid: 0000-0002-7320-3496 surname: Bam fullname: Bam, Wokil organization: Louisiana State University – sequence: 7 givenname: Kanchan surname: Maiti fullname: Maiti, Kanchan organization: Louisiana State University – sequence: 8 givenname: Kevin M orcidid: 0000-0002-2766-104X surname: McPeak fullname: McPeak, Kevin M organization: Department of Chemical Engineering – sequence: 9 givenname: Gang Logan surname: Liu fullname: Liu, Gang Logan organization: Department of Electrical and Computer Engineering – sequence: 10 givenname: Manas Ranjan orcidid: 0000-0001-6243-6780 surname: Gartia fullname: Gartia, Manas Ranjan email: mgartia@lsu.edu organization: Department of Mechanical and Industrial Engineering |
BookMark | eNp1kc1v1DAQxS1URD_onWOOHNgy_kjiXBCoWkqlInoAcbTG9mQ3q8Re7KRS_3sMuyB64DSjeW9-lueds5MQAzH2isMVB8Hfostxog1ecQfApXjGzoRqYcWlkif_9KfsMucdFE-jhRbNC3YqFdSN0PUZe3-fhjCTr9YjuTlFT1UfU_WZMC9F2VT325j3W5ypGkK1Dg9DimGiMONYfS_T9JI973HMdHmsF-zbx_XX60-ruy83t9cf7lao2mZe2d56C60FW7etRe40-U726LERvlGuqWvpwKOgTtcaCSx463WHrYJWWS0v2O2B6yPuzD4NE6ZHE3EwvwcxbQymeXAjGdtx6B2BaqRXAoWGrhO99N4pXW5AhfXuwNovdiLvyncSjk-gT5UwbM0mPhjNa9kpVQCvj4AUfyyUZzMN2dE4YqC4ZCNqWXOQWnXFCgerSzHnRP3fZziYXzmaPzmaY45l5c1hpShmF5cUymH_b_8JjeCiig |
CitedBy_id | crossref_primary_10_1007_s44211_022_00228_x crossref_primary_10_1016_j_electacta_2023_142600 crossref_primary_10_1016_j_talanta_2024_125682 |
Cites_doi | 10.1016/S0039-9140(03)00229-7 10.13031/2013.22633 10.1007/s00254-005-0124-x 10.1016/j.talanta.2013.05.004 10.1016/j.talanta.2006.11.003 10.1093/plankt/fbh070 10.1016/j.bios.2006.08.004 10.1088/0022-3727/41/19/195001 10.1016/j.talanta.2018.03.085 10.3390/ijerph110201557 10.1039/C6RA12159D 10.1016/j.talanta.2004.12.064 10.1080/10643389991259182 10.1007/s11426-014-5127-6 10.1021/ac504602a 10.1007/s11783-013-0615-z 10.1016/j.aca.2012.03.060 10.1016/j.chemosphere.2011.03.001 10.1021/acs.est.6b02204 10.1080/07438149109354258 10.1155/2013/104316 10.1016/j.electacta.2018.06.021 10.1016/j.snb.2008.10.032 10.1016/S0003-2670(96)00382-0 10.1039/c0cc05230b 10.1146/annurev.es.13.110182.002025 10.2175/106143004X151662 10.1631/jzus.B0710626 10.1016/S1001-0742(09)60114-5 10.1016/S0003-2670(00)83827-1 10.1007/s11356-016-7321-x 10.1016/j.talanta.2011.09.056 10.1049/iet-nbt.2013.0041 10.1016/j.jhazmat.2007.06.041 10.1016/j.proenv.2011.09.334 10.5268/IW-6.2.938 10.1021/ac00098a009 10.1016/j.aca.2016.02.047 10.3389/fmars.2017.00255 10.1039/B811942B 10.1016/j.coelec.2018.07.008 10.1016/j.electacta.2007.06.058 10.1021/es502852s 10.1021/ac951086v 10.1016/0003-2670(92)80221-R 10.1016/j.aca.2009.10.064 10.3184/095422905782774937 |
ContentType | Journal Article |
Copyright | 2021 The
Authors. Published by American
Chemical Society 2021 The Authors. Published by American Chemical Society 2021 The Authors |
Copyright_xml | – notice: 2021 The Authors. Published by American Chemical Society – notice: 2021 The Authors. Published by American Chemical Society 2021 The Authors |
DBID | N~. AAYXX CITATION 7X8 5PM DOA |
DOI | 10.1021/acsomega.1c00132 |
DatabaseName | American Chemical Society (ACS) Open Access Journals CrossRef MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
DatabaseTitle | CrossRef MEDLINE - Academic |
DatabaseTitleList | |
Database_xml | – sequence: 1 dbid: N~. name: American Chemical Society (ACS) Open Access Journals url: https://pubs.acs.org sourceTypes: Publisher – sequence: 2 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 2470-1343 |
EndPage | 11306 |
ExternalDocumentID | oai_doaj_org_article_b910fce0463d42a280992f3ddc48168e 10_1021_acsomega_1c00132 a148795321 |
GrantInformation_xml | – fundername: ; grantid: 1660233 – fundername: ; grantid: LEQSF(2017-20)-RD-A-04 |
GroupedDBID | 53G ABFRP ABUCX ACS ADACO ADBBV AFEFF ALMA_UNASSIGNED_HOLDINGS BCNDV EBS GGK GROUPED_DOAJ HYE N~. OK1 RPM VF5 AAFWJ AAHBH AAYXX AFPKN AOIJS CITATION M~E 7X8 5PM |
ID | FETCH-LOGICAL-a476t-bfbdb07b0b577ba1c8ed93fada62d64c6553c0da2e9858ae0b0dbd89a74074b83 |
IEDL.DBID | RPM |
ISSN | 2470-1343 |
IngestDate | Mon Aug 19 07:08:02 EDT 2024 Tue Sep 17 21:14:31 EDT 2024 Fri Aug 16 08:37:51 EDT 2024 Fri Aug 23 03:40:00 EDT 2024 Thu May 06 19:56:01 EDT 2021 |
IsDoiOpenAccess | true |
IsOpenAccess | true |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 17 |
Language | English |
License | Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-a476t-bfbdb07b0b577ba1c8ed93fada62d64c6553c0da2e9858ae0b0dbd89a74074b83 |
Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ORCID | 0000-0001-6546-8075 0000-0001-6243-6780 0000-0002-0000-3637 0000-0002-2766-104X 0000-0002-7320-3496 |
OpenAccessLink | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8153944/ |
PMID | 34056285 |
PQID | 2535103849 |
PQPubID | 23479 |
PageCount | 10 |
ParticipantIDs | doaj_primary_oai_doaj_org_article_b910fce0463d42a280992f3ddc48168e pubmedcentral_primary_oai_pubmedcentral_nih_gov_8153944 proquest_miscellaneous_2535103849 crossref_primary_10_1021_acsomega_1c00132 acs_journals_10_1021_acsomega_1c00132 |
ProviderPackageCode | ABFRP ACS AFEFF VF5 ABUCX GGK N~. |
PublicationCentury | 2000 |
PublicationDate | 2021-05-04 |
PublicationDateYYYYMMDD | 2021-05-04 |
PublicationDate_xml | – month: 05 year: 2021 text: 2021-05-04 day: 04 |
PublicationDecade | 2020 |
PublicationTitle | ACS omega |
PublicationTitleAlternate | ACS Omega |
PublicationYear | 2021 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
References | ref9/cit9 ref27/cit27 ref16/cit16 Vollenweider R. A. (ref3/cit3) 1970 ref52/cit52 ref23/cit23 ref8/cit8 ref31/cit31 ref2/cit2 ref34/cit34 ref37/cit37 EPA (ref12/cit12) 2001; 66 ref20/cit20 ref48/cit48 Zimmermann C. F. (ref13/cit13) 1997 ref17/cit17 ref10/cit10 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 Chanysheva A. (ref39/cit39) 2016 ref24/cit24 ref38/cit38 ref50/cit50 ref54/cit54 ref6/cit6 ref11/cit11 ref25/cit25 ref29/cit29 ref32/cit32 Kabir M. F. (ref49/cit49) 2017 ref14/cit14 ref5/cit5 O’Dell J. (ref18/cit18) 1993 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 Ansari A. (ref45/cit45) 2009; 4 ref26/cit26 Sahu S. (ref36/cit36) 2019 ref55/cit55 ref15/cit15 ref41/cit41 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 ref44/cit44 ref7/cit7 |
References_xml | – ident: ref27/cit27 doi: 10.1016/S0039-9140(03)00229-7 – volume-title: Electrochemical Sensing System for Detection of Organophosphate Neurotoxins year: 2016 ident: ref39/cit39 contributor: fullname: Chanysheva A. – ident: ref50/cit50 doi: 10.13031/2013.22633 – ident: ref7/cit7 doi: 10.1007/s00254-005-0124-x – volume: 4 start-page: 52 year: 2009 ident: ref45/cit45 publication-title: Pan-Am. J. Aquat. Sci. contributor: fullname: Ansari A. – volume-title: Scientific fundamentals of the eutrophication of lakes and flowing waters, with particular reference to nitrogen and phosphorus as factors in eutrophication year: 1970 ident: ref3/cit3 contributor: fullname: Vollenweider R. A. – ident: ref21/cit21 doi: 10.1016/j.talanta.2013.05.004 – ident: ref24/cit24 doi: 10.1016/j.talanta.2006.11.003 – volume: 66 start-page: 69 year: 2001 ident: ref12/cit12 publication-title: Fed. Regist. contributor: fullname: EPA – ident: ref10/cit10 doi: 10.1093/plankt/fbh070 – ident: ref28/cit28 doi: 10.1016/j.bios.2006.08.004 – year: 1997 ident: ref13/cit13 publication-title: Method 365.5: Determination of orthophosphate in estuarine and coastal waters by automated colorimetric analysis contributor: fullname: Zimmermann C. F. – ident: ref52/cit52 doi: 10.1088/0022-3727/41/19/195001 – ident: ref19/cit19 doi: 10.1016/j.talanta.2018.03.085 – ident: ref40/cit40 doi: 10.3390/ijerph110201557 – ident: ref55/cit55 doi: 10.1039/C6RA12159D – ident: ref15/cit15 doi: 10.1016/j.talanta.2004.12.064 – ident: ref41/cit41 doi: 10.1080/10643389991259182 – ident: ref53/cit53 doi: 10.1007/s11426-014-5127-6 – ident: ref14/cit14 doi: 10.1021/ac504602a – ident: ref30/cit30 doi: 10.1007/s11783-013-0615-z – ident: ref35/cit35 doi: 10.1016/j.aca.2012.03.060 – ident: ref1/cit1 doi: 10.1016/j.chemosphere.2011.03.001 – ident: ref5/cit5 doi: 10.1021/acs.est.6b02204 – ident: ref17/cit17 doi: 10.1080/07438149109354258 – ident: ref43/cit43 doi: 10.1155/2013/104316 – ident: ref31/cit31 doi: 10.1016/j.electacta.2018.06.021 – ident: ref29/cit29 doi: 10.1016/j.snb.2008.10.032 – ident: ref38/cit38 doi: 10.1016/S0003-2670(96)00382-0 – ident: ref54/cit54 doi: 10.1039/c0cc05230b – ident: ref11/cit11 doi: 10.1146/annurev.es.13.110182.002025 – ident: ref46/cit46 doi: 10.2175/106143004X151662 – ident: ref44/cit44 doi: 10.1631/jzus.B0710626 – ident: ref8/cit8 doi: 10.1016/S1001-0742(09)60114-5 – ident: ref23/cit23 doi: 10.1016/S0003-2670(00)83827-1 – ident: ref6/cit6 doi: 10.1007/s11356-016-7321-x – ident: ref26/cit26 doi: 10.1016/j.talanta.2011.09.056 – ident: ref16/cit16 doi: 10.1049/iet-nbt.2013.0041 – ident: ref47/cit47 doi: 10.1016/j.jhazmat.2007.06.041 – ident: ref9/cit9 doi: 10.1016/j.proenv.2011.09.334 – ident: ref4/cit4 doi: 10.5268/IW-6.2.938 – ident: ref37/cit37 doi: 10.1021/ac00098a009 – ident: ref34/cit34 doi: 10.1016/j.aca.2016.02.047 – ident: ref20/cit20 doi: 10.3389/fmars.2017.00255 – ident: ref48/cit48 doi: 10.1039/B811942B – start-page: 1 year: 1993 ident: ref18/cit18 publication-title: EPA—U. S. Environ. Prot Agency contributor: fullname: O’Dell J. – ident: ref33/cit33 doi: 10.1016/j.coelec.2018.07.008 – volume-title: Development of Electrochemical Sensor for Phosphate Ion Determination in Environmental Water year: 2019 ident: ref36/cit36 contributor: fullname: Sahu S. – ident: ref22/cit22 doi: 10.1016/j.electacta.2007.06.058 – ident: ref2/cit2 doi: 10.1021/es502852s – ident: ref51/cit51 doi: 10.1021/ac951086v – ident: ref32/cit32 doi: 10.1016/0003-2670(92)80221-R – volume-title: Electrochemical Sensor for Metal Ions and Phosphate Ion Detection for Biomedical and Agriculture Application year: 2017 ident: ref49/cit49 contributor: fullname: Kabir M. F. – ident: ref25/cit25 doi: 10.1016/j.aca.2009.10.064 – ident: ref42/cit42 doi: 10.3184/095422905782774937 |
SSID | ssj0001682826 |
Score | 2.2327642 |
Snippet | Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from... Phosphate is a major nonpoint source pollutant in both the Louisiana local streams as well as in the Gulf of Mexico coastal waters. Phosphates from... |
SourceID | doaj pubmedcentral proquest crossref acs |
SourceType | Open Website Open Access Repository Aggregation Database Publisher |
StartPage | 11297 |
SummonAdditionalLinks | – databaseName: American Chemical Society (ACS) Open Access Journals dbid: N~. link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV07T8MwELZ4DLAgnqK8FCQYGFIS-xI7Gw8VIaRWHajoZtmxSzuQVk1Z-e2c3ZQShBCrYznKd7bvs-_yHSEX1jChNagwtsyGuBJVKHSWhgZ0poBnRvsL_XYnfezBUz_pL2VyfkbwaXyt8nL8Zl9VM859YGCVrFMex25Odz6ay_uUFM8OvroaBR6FMQNWRSV_G8T5orys-SIv2V_jmfUsyW9u52GbbFV8MbidG3iHrNhil2zcL8q07ZGb7tRJPpigNS9oY2yAPDRo-7s_9EtBdzguJ0OklMGoCFrL_9pw1Bdsne6T3kPr-f4xrMoihAheOgv1QCOCXEc64VyrOBfWZGygjEqpSSFPk4TlkVHUZiIRykY6MtqITHE8vIEW7ICsFePCHpKA4hZjgeOitRwUjQQg30kUngqpBpNAg1wiTLKa1qX0EWsaywWcsoKzQa4WQMrJXCXjj753Dumvfk7f2jeg0WW1XKRGFjPIrZMzM0AVFUhk6YAZk4MrFGIb5HxhJ4l4uyCHKuz4vZQ0YU4kUEDWILxmwNob60-K0dArawvc_zOAo39-9jHZpC7FxeU_wglZm03f7SlylJk-85PzE7094-U priority: 102 providerName: American Chemical Society – databaseName: DOAJ Directory of Open Access Journals dbid: DOA link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV07T8MwELZQF1gQT1FeChIMDKGJc06cDahaVUhFHajoZtmxSzuQVk37_zk7CTQLLKyOlVjf2b5nviPk1uiIKwXSD01kfDyJ0ucqjX0NKpWQpFq5gP7wNR6M4WXCJlutvmxNWEkPXALXUajPppmxxFYaqKQcTRo6jbTOwLaMMO72DdmWM-WiKzF6ErTOS6Ie68isWHyaD_kQZi6_YLVRVjS0kSPtb1iazTrJLcXTPyD7lcXoPZUrPSQ7Jj8iu926UdsxeRytLOmD9nplSxttPLREvaGL_qFm8kazRbGcoVHpzXOv9_NnG771HUdXJ2Tc7711B37VGMFH-OK1r6YKMUxUoFiSKBlm3Og0mkotY6pjyGLGoizQkpqUMy5NoAKtNE9lgu4bKB6dkla-yM0Z8SheMgYSPLYmAUkDDmjxMIl-IVWgGbTJHcIkqo1dCJezpqGo4RQVnG1yXwMpliVPxi9zny3S3_Msw7UbQLmLSu7iL7m3yU0tJ4F42zSHzM1iUwjKIksTyCFtk6QhwMYXm0_y-cxxa3PUACnA-X8s8YLsUVsBY8sj4ZK01quNuUITZq2u3W79AiLm8Lc priority: 102 providerName: Directory of Open Access Journals |
Title | Printed Electrode for Measuring Phosphate in Environmental Water |
URI | http://dx.doi.org/10.1021/acsomega.1c00132 https://search.proquest.com/docview/2535103849 https://pubmed.ncbi.nlm.nih.gov/PMC8153944 https://doaj.org/article/b910fce0463d42a280992f3ddc48168e |
Volume | 6 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV07b9swED7EGdosRfpC3aSGCrRDB9kyeRKpra3hIAjgwEAbNBvBl2MDtWTYztrfniMttdHSIYsGknrg41H3He94B_DJOy6NQZ2OPfcprUSdSlMWqUNTahSlM3FDf3ZdXN7g1W1-ewR5exYmBu1bsxpWv9fDarWMsZWbtR21cWKj-WwiaZmWiKMe9ATnj0z0uLFSkBHBWpckqbCRtrt67e_0cGyja-EEnnEMij8UUO5Rb0cnxdT9Hb7ZjZZ8pH4uTuFFwxuTb4fvewlHvnoFzydtubbX8HW-DakfXDI9FLZxPiE-msziHiDpp2S-rHebJVHLZFUl03_n2-ipv6h1-wZuLqY_J5dpUx4hJRCLfWoWhpAUJjO5EEaPrfSu5AvtdMFcgbbIc24zp5kvZS61z0zmjJOlFmTEoZH8LRxXdeXfQcLoV-NR0OL1AjXLJBLvyTVZh8ygy7EPnwkm1Yj3TkXPNRurFlnVINuHLy2QanPIlvGfsd8D0n_HhTzXsaHe3qlmtpUhNrOwPqQ1c8g0k0Ro2YI7ZzEUDPF9-NjOkyK8g7NDV76-3ymW85AsUGLZB9GZwM4buz0kcDHDdiNg75985xmcsBD8EiIj8RyO99t7_4HYy94MiL1Pfgyi7U_X6z_DQZTfB0Le9H8 |
link.rule.ids | 230,315,733,786,790,870,891,2115,2782,27109,27113,27957,27958,53827,53829,57093,57117,57143,57167 |
linkProvider | National Library of Medicine |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LbxMxEB61RaK9UF4VKRQWCQ4cdrPx2mvvjTZKFaCpcmihN8uvNBHNbpTHhV_P2NmFLgckuNr79OfxzHjG3wC8czYTWlMV91zmYpREFQtd5LGlulCUF1aHDf3RZT68pp9v2M0OsOYsTEjaN3qWlHfzpJxNQ27lYm66TZ5YdzzqCxTTgtLuLjxAeSX8npMetlZydCNIE5REJdZVZlXN3a1KeiYEFw7gYUa96vcllHext6WVAnl_y-Js50veU0Dnh_C1-fRt3sn3ZLPWifnxB6vjP__bY3hUm6TR6bb7Cey48ins95tKcM_g43jpWSVsNNjWzLEuQlM3GoXtRVR90XharRZTtFqjWRkNfh-dw6d-w9blc7g-H1z1h3FdeSFGfPJ1rCcaQeI61YxzrXpGOFtkE2VVTmxOTc5YZlKriCsEE8qlOrXaikJx9A-pFtkR7JVV6V5ARHAVc5TjuuA4VSQVFE0qptDxJJpaRjvwHsdf1pKzkiEoTnqygUzWkHXgQ4OQXGyJOP5y7ZmH8Nd1nkI7NFTLW1kPttRoKE2M84xplhJFBNrKZJJZa6ivReI68LaZABLH28dRVOmqzUoSlnkeQkGLDvDWzGi9sd2DeAfy7hrf4_--8w3sD69GF_Li0-WXl3BAfI6NT8Ckr2Bvvdy4EzSS1vp1EImfXWATgA |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3JbtswEB00KZDmknQL6nRTgfbQgxZTlETemro20sWBDw0a9EJwU2w0lgwvl3x9h7TUWj30kCtJbXwczhvOaAbgrTUpU4rKsG9TG6IkypApnoeGKi5pwY3yB_rji_z8kn65yq52Sn35oH2tZlF1M4-q2dTHVi7mOm7jxOLJeMBQTDml8cKU8R7cR5klfMdQ98crOZoSpHVMoiKLpV7Vc3sto772DoZDOEipU_-ujPIe9nY0k0_g32Gd3ZjJHSU0Ooaf7etvY09-RZu1ivTtP5kd7_R9D-GooabB2XbII7hnq8fwYNBWhHsCHyZLl13CBMNt7RxjA6S8wdgfM6IKDCbTerWYInsNZlUw_PsLHd71B7Yun8LlaPh9cB42FRhCxClfh6pUCFahEpUVhZJ9zazhaSmNzInJqc6zLNWJkcRyljFpE5UYZRiXBdqJVLH0BParurLPICC4m1la4P5gCypJwihSq0yiAUoUNRntwTvEQDQStBLeOU76ooVNNLD14H2LklhsE3L8Z-xHB-OfcS6Vtm-ol9eimXChkDCV2rrMaYYSSRhyZlKmxmjqapLYHrxpF4HA-Xb-FFnZerMSJEtdPkJGeQ-KzuroPLHbg5j7JN4Nxqd3vvI1HEw-jcS3zxdfn8MhcaE2Lg6TvoD99XJjXyJXWqtXXip-A_W5FgA |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Printed+Electrode+for+Measuring+Phosphate+in+Environmental+Water&rft.jtitle=ACS+omega&rft.au=Prasad%2C+Alisha&rft.au=Sahu%2C+Sushant+P.&rft.au=Figueiredo+Stofela%2C+Sara+Karoline&rft.au=Chaichi%2C+Ardalan&rft.date=2021-05-04&rft.pub=American+Chemical+Society&rft.eissn=2470-1343&rft.volume=6&rft.issue=17&rft.spage=11297&rft.epage=11306&rft_id=info:doi/10.1021%2Facsomega.1c00132&rft_id=info%3Apmid%2F34056285&rft.externalDBID=PMC8153944 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2470-1343&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2470-1343&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2470-1343&client=summon |