Metal–Organic Framework MIL-101(Cr) for High-Performance Liquid Chromatographic Separation of Substituted Aromatics

• Published in: Analytical chemistry (Washington) Vol. 83; no. 18; pp. 7144 - 7150
• Main Authors: Yang, Cheng-Xiong, Yan, Xiu-Ping
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 15.09.2011
• Subjects: Analytical chemistry; Benzene Derivatives - chemistry; Benzene Derivatives - isolation & purification; Chemistry; Chlorobenzenes - chemistry; Chlorobenzenes - isolation & purification; Chromatographic methods and physical methods associated with chromatography; Chromatography; Chromatography, High Pressure Liquid - methods; Dichlorobenzene; Exact sciences and technology; Isomerism; Metals; Metals - chemistry; Organic Chemicals - chemistry; Other chromatographic methods; Retention time; Slurries; Styrene; Styrene - chemistry; Styrene - isolation & purification; Temperature; Thermodynamics; Toluene; Toluene - chemistry; Toluene - isolation & purification; Xylene; Xylenes - chemistry; Xylenes - isolation & purification; High resolution; Peak resolution; Temperature; Cage; Impurity; Enthalpy; HPLC chromatography; Entropy; Metal; Replica method; Retention time; Mixture; Isomer; Ethylbenzene; Efficiency; Xylene; Standard deviation; Phase composition; Pore structure; Sample; Toluene; Plate; Styrene; Dichloromethane; Affinity; Surface area; Slurries; Packed column

The diverse structures and pore topologies, accessible cages and tunnels, and high surface areas make metal–organic frameworks attractive as novel media in separation sciences. Here we report the slurry-packed MIL-101(Cr) column for high-performance liquid chromatographic separation of substituted a...