Rare-Earth Doping in Nanostructured Inorganic Materials
Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter th...
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| Published in | Chemical reviews Vol. 122; no. 6; pp. 5519 - 5603 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
23.03.2022
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications. |
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| AbstractList | Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications. Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications.Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties, rare-earth ions have been extensively explored as active dopants in inorganic crystal lattices since the 18th century. Rare-earth doping can alter the crystallographic phase, morphology, and size, leading to tunable optical responses of doped nanomaterials. Moreover, rare-earth doping can control the ultimate electronic and catalytic performance of doped nanomaterials in a tunable and scalable manner, enabling significant improvements in energy harvesting and conversion. A better understanding of the critical role of rare-earth doping is a prerequisite for the development of an extensive repertoire of functional nanomaterials for practical applications. In this review, we highlight recent advances in rare-earth doping in inorganic nanomaterials and the associated applications in many fields. This review covers the key criteria for rare-earth doping, including basic electronic structures, lattice environments, and doping strategies, as well as fundamental design principles that enhance the electrical, optical, catalytic, and magnetic properties of the material. We also discuss future research directions and challenges in controlling rare-earth doping for new applications. |
| Author | Fan, Jingyue Liu, Xiaogang Chen, Bing Deng, Renren Zheng, Bingzhu Qin, Xian Wang, Juan Wang, Feng |
| AuthorAffiliation | Department of Chemistry National University of Singapore Department of Materials Science and Engineering State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering Zhejiang University Institute of Environmental Health, MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental & Resource Sciences |
| AuthorAffiliation_xml | – name: Institute of Environmental Health, MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environmental & Resource Sciences – name: Department of Chemistry – name: Zhejiang University – name: National University of Singapore – name: State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering – name: Department of Materials Science and Engineering |
| Author_xml | – sequence: 1 givenname: Bingzhu surname: Zheng fullname: Zheng, Bingzhu organization: State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering – sequence: 2 givenname: Jingyue orcidid: 0000-0003-4987-7025 surname: Fan fullname: Fan, Jingyue organization: Department of Chemistry – sequence: 3 givenname: Bing orcidid: 0000-0002-0663-1343 surname: Chen fullname: Chen, Bing organization: Department of Materials Science and Engineering – sequence: 4 givenname: Xian surname: Qin fullname: Qin, Xian organization: National University of Singapore – sequence: 5 givenname: Juan orcidid: 0000-0002-1340-9011 surname: Wang fullname: Wang, Juan email: wjuan@zju.edu.cn organization: Zhejiang University – sequence: 6 givenname: Feng orcidid: 0000-0001-9471-4386 surname: Wang fullname: Wang, Feng email: fwang24@cityu.edu.hk organization: Department of Materials Science and Engineering – sequence: 7 givenname: Renren orcidid: 0000-0001-8213-6304 surname: Deng fullname: Deng, Renren email: rdeng@zju.edu.cn organization: State Key Laboratory of Silicon Materials, Institute for Composites Science Innovation, School of Materials Science and Engineering – sequence: 8 givenname: Xiaogang orcidid: 0000-0003-2517-5790 surname: Liu fullname: Liu, Xiaogang email: chmlx@nus.edu.sg organization: Department of Chemistry |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/34989556$$D View this record in MEDLINE/PubMed |
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| Snippet | Impurity doping is a promising method to impart new properties to various materials. Due to their unique optical, magnetic, and electrical properties,... |
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| SubjectTerms | catalytic activity Crystal lattices crystallization Crystallography Doping Earth Electrical properties energy Energy harvesting Functional materials Inorganic materials Magnetic properties magnetism Metal ions Metals, Rare Earth - chemistry Nanomaterials Nanostructures - chemistry Nanotechnology Optical properties Rare earth elements |
| Title | Rare-Earth Doping in Nanostructured Inorganic Materials |
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