Enantioselective Carbonyl Allylation, Crotylation, and tert-Prenylation of Furan Methanols and Furfurals via Iridium-Catalyzed Transfer Hydrogenation - Bechem, Benjamin; Patman, Ryan L; Hashmi, A. Stephen K; Krische, Michael J (Journal of organic chemistry, 2010)
Keywords: Acetates - chemistry; Allyl Compounds - chemistry; Catalysis; Chemistry; Chemistry, Organic; Exact sciences and technology; Furaldehyde - chemistry; Furans - chemistry; Heterocyclic compounds; Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives; Hydrogenation; Iridium - chemistry; Methanol - chemistry; Molecular Structure; Organic chemistry; Physical Sciences; Preparations and properties; Pyrones - chemistry; Science & Technology; Stereoisomerism; ACTIVATION; REAGENTS; ALCOHOL; LIGANDS; MECHANISM; ALDEHYDE OXIDATION LEVEL; ACETATE; CHIRAL LEWIS-ACID; ASYMMETRIC ALLYLATION; BIS(((S)-BINAPHTHOXY)(ISOPROPOXY)TITANIUM) OXIDE; Chemical rearrangement; Catalytic reaction; Transition element complexes; Enantioselectivity; Furan derivatives; Iridium complex; Transition metal; Modified catalyst; Propanol; Aldehyde; Pyranone derivatives; Oxygen heterocycle; Ketone; Hydrogenation; Allylic compound; Allylation; Furfural derivatives; Chlorides; Enantiomeric excess; Methyl acetate; Platinoid; Methanol