A Self-Assembled Organic/Metal Junction for Water Photo-Oxidation

We report the in situ self-assembly of TTF, TTF•+, and BF4 – or PF6 – into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O2 and H+, with an efficiency of...

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Published inJournal of the American Chemical Society Vol. 141; no. 16; pp. 6765 - 6774
Main Authors Olaya, Astrid J, Omatsu, Terumasa, Hidalgo-Acosta, Jonnathan C, Riva, Julieta S, Bassetto, Victor Costa, Gasilova, Natalia, Girault, Hubert H
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 24.04.2019
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Abstract We report the in situ self-assembly of TTF, TTF•+, and BF4 – or PF6 – into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O2 and H+, with an efficiency of 100% with respect to the initial concentration of TTF•+. TTF•+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF•+, and HTTF+, which furthermore showed no signs of decomposition in solution.
AbstractList We report the in situ self-assembly of TTF, TTF , and BF or PF into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O and H , with an efficiency of 100% with respect to the initial concentration of TTF . TTF is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF , and HTTF , which furthermore showed no signs of decomposition in solution.
We report the in situ self-assembly of TTF, TTF•+, and BF4 – or PF6 – into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile mixtures. The visible light photoactivation of these self-assemblies leads to water oxidation forming O2 and H+, with an efficiency of 100% with respect to the initial concentration of TTF•+. TTF•+ is then completely reduced to TTF upon photoreduction with water. The Pt microparticles act as floating microelectrodes whose Fermi level is imposed by the different redox species in solution; here predominantly TTF, TTF•+, and HTTF+, which furthermore showed no signs of decomposition in solution.
Author Omatsu, Terumasa
Riva, Julieta S
Bassetto, Victor Costa
Hidalgo-Acosta, Jonnathan C
Girault, Hubert H
Gasilova, Natalia
Olaya, Astrid J
AuthorAffiliation Faculty of Molecular Chemistry and Engineering
Kyoto Institute of Technology
Laboratory of Physical and Analytical Electrochemistry, EPFL Valais Wallis
École Polytechnique Fédérale de Lausanne
Universidad Nacional de Córdoba
Consejo Nacional de Investigaciones Científicas y Técnicas, CONICET, Facultad de Matemática, Astronomía, Física y Computación
AuthorAffiliation_xml – name: Faculty of Molecular Chemistry and Engineering
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– name: École Polytechnique Fédérale de Lausanne
– name: Kyoto Institute of Technology
– name: Universidad Nacional de Córdoba
– name: Laboratory of Physical and Analytical Electrochemistry, EPFL Valais Wallis
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  orcidid: 0000-0002-9770-130X
  surname: Olaya
  fullname: Olaya, Astrid J
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Snippet We report the in situ self-assembly of TTF, TTF•+, and BF4 – or PF6 – into p-type semiconductors on the surface of Pt microparticles dispersed in...
We report the in situ self-assembly of TTF, TTF , and BF or PF into p-type semiconductors on the surface of Pt microparticles dispersed in water/acetonitrile...
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Title A Self-Assembled Organic/Metal Junction for Water Photo-Oxidation
URI http://dx.doi.org/10.1021/jacs.9b02693
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