Ionic Highways from Covalent Assembly in Highly Conducting and Stable Anion Exchange Membrane Fuel Cells
A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we presen...
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| Published in | Journal of the American Chemical Society Vol. 141; no. 45; pp. 18152 - 18159 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
13.11.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing ionic highways along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm–1 at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g–1 ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm–2 (0.45 W cm–2 from a silver-based cathode) and stable performance throughout 400 h tests. |
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| AbstractList | A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing
along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm
at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g
ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm
(0.45 W cm
from a silver-based cathode) and stable performance throughout 400 h tests. A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing ionic highways along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm-1 at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g-1 ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm-2 (0.45 W cm-2 from a silver-based cathode) and stable performance throughout 400 h tests.A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing ionic highways along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm-1 at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g-1 ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm-2 (0.45 W cm-2 from a silver-based cathode) and stable performance throughout 400 h tests. A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing ionic highways along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm–¹ at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g–¹ ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm–² (0.45 W cm–² from a silver-based cathode) and stable performance throughout 400 h tests. A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. Herein, we present a design using cross-linked polymer membranes containing ionic highways along charge-delocalized pyrazolium cations and homoconjugated triptycenes. These ionic highway membranes show improved performance. Specifically, a conductivity of 111.6 mS cm–1 at 80 °C was obtained with a low 7.9% water uptake and 0.91 mmol g–1 ion exchange capacity. In contrast to existing materials, ionic highways produce higher conductivities at reduced hydration and ionic exchange capacities. The membranes retain more than 75% of their initial conductivity after 30 days of an alkaline stability test. The formation of ionic highways for ion transport is confirmed by density functional theory and Monte Carlo studies. A single cell with platinum metal catalysts at 80 °C showed a high peak density of 0.73 W cm–2 (0.45 W cm–2 from a silver-based cathode) and stable performance throughout 400 h tests. |
| Author | France-Lanord, Arthur Wang, Yichong Lin, Sibo Li, Yifan Wang, Yanming Kim, Yoonseob Wu, You-Chi Mason Grossman, Jeffrey C Swager, Timothy M |
| AuthorAffiliation | Department of Chemistry Department of Chemical and Biological Engineering Department of Materials Science and Engineering Hong Kong University of Science and Technology |
| AuthorAffiliation_xml | – name: Department of Chemistry – name: Department of Chemical and Biological Engineering – name: Hong Kong University of Science and Technology – name: Department of Materials Science and Engineering |
| Author_xml | – sequence: 1 givenname: Yoonseob orcidid: 0000-0002-6892-8281 surname: Kim fullname: Kim, Yoonseob organization: Hong Kong University of Science and Technology – sequence: 2 givenname: Yanming orcidid: 0000-0002-0912-681X surname: Wang fullname: Wang, Yanming organization: Department of Materials Science and Engineering – sequence: 3 givenname: Arthur orcidid: 0000-0003-0586-1945 surname: France-Lanord fullname: France-Lanord, Arthur organization: Department of Materials Science and Engineering – sequence: 4 givenname: Yichong surname: Wang fullname: Wang, Yichong organization: Department of Chemistry – sequence: 5 givenname: You-Chi Mason orcidid: 0000-0002-6585-7908 surname: Wu fullname: Wu, You-Chi Mason organization: Department of Chemistry – sequence: 6 givenname: Sibo orcidid: 0000-0001-5922-6694 surname: Lin fullname: Lin, Sibo organization: Department of Chemistry – sequence: 7 givenname: Yifan surname: Li fullname: Li, Yifan organization: Department of Chemistry – sequence: 8 givenname: Jeffrey C orcidid: 0000-0003-1281-2359 surname: Grossman fullname: Grossman, Jeffrey C email: jcg@mit.edu organization: Department of Materials Science and Engineering – sequence: 9 givenname: Timothy M orcidid: 0000-0002-3577-0510 surname: Swager fullname: Swager, Timothy M email: tswager@mit.edu organization: Department of Chemistry |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31682441$$D View this record in MEDLINE/PubMed |
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| SubjectTerms | anion-exchange membranes catalysts cathodes cations crosslinking density functional theory fuel cells hydroxides ion exchange capacity Monte Carlo method platinum polymers water uptake |
| Title | Ionic Highways from Covalent Assembly in Highly Conducting and Stable Anion Exchange Membrane Fuel Cells |
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