Scalable and Template-Free Aqueous Synthesis of Zirconium-Based Metal–Organic Framework Coating on Textile Fiber
Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that Zr-based metal–organic frameworks (Zr-MOFs) can effectively catalyze the hydrolysis of these toxic chemicals for diminishing their toxicity. On...
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| Published in | Journal of the American Chemical Society Vol. 141; no. 39; pp. 15626 - 15633 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
02.10.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that Zr-based metal–organic frameworks (Zr-MOFs) can effectively catalyze the hydrolysis of these toxic chemicals for diminishing their toxicity. On the other hand, utilizing these materials in powder form is not practical, and developing scalable and economical processes for integrating these materials onto fibers is crucial for protective gear. Herein, we report a scalable, template-free, and aqueous solution-based synthesis strategy for the production of Zr-MOF-coated textiles. Among all MOF/fiber composites reported to date, the MOF-808/polyester fibers exhibit the highest rates of nerve agent hydrolysis. Moreover, such highly porous fiber composites display significantly higher protection time compared to that of its parent fabric for a mustard gas simulant, 2-chloroethyl ethyl sulfide (CEES). A decreased diffusion rate of toxic chemicals through the MOF layer can provide time needed for the destruction of the harmful species. |
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| AbstractList | Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that Zr-based metal–organic frameworks (Zr-MOFs) can effectively catalyze the hydrolysis of these toxic chemicals for diminishing their toxicity. On the other hand, utilizing these materials in powder form is not practical, and developing scalable and economical processes for integrating these materials onto fibers is crucial for protective gear. Herein, we report a scalable, template-free, and aqueous solution-based synthesis strategy for the production of Zr-MOF-coated textiles. Among all MOF/fiber composites reported to date, the MOF-808/polyester fibers exhibit the highest rates of nerve agent hydrolysis. Moreover, such highly porous fiber composites display significantly higher protection time compared to that of its parent fabric for a mustard gas simulant, 2-chloroethyl ethyl sulfide (CEES). A decreased diffusion rate of toxic chemicals through the MOF layer can provide time needed for the destruction of the harmful species. Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that Zr-based metal-organic frameworks (Zr-MOFs) can effectively catalyze the hydrolysis of these toxic chemicals for diminishing their toxicity. On the other hand, utilizing these materials in powder form is not practical, and developing scalable and economical processes for integrating these materials onto fibers is crucial for protective gear. Herein, we report a scalable, template-free, and aqueous solution-based synthesis strategy for the production of Zr-MOF-coated textiles. Among all MOF/fiber composites reported to date, the MOF-808/polyester fibers exhibit the highest rates of nerve agent hydrolysis. Moreover, such highly porous fiber composites display significantly higher protection time compared to that of its parent fabric for a mustard gas simulant, 2-chloroethyl ethyl sulfide (CEES). A decreased diffusion rate of toxic chemicals through the MOF layer can provide time needed for the destruction of the harmful species.Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that Zr-based metal-organic frameworks (Zr-MOFs) can effectively catalyze the hydrolysis of these toxic chemicals for diminishing their toxicity. On the other hand, utilizing these materials in powder form is not practical, and developing scalable and economical processes for integrating these materials onto fibers is crucial for protective gear. Herein, we report a scalable, template-free, and aqueous solution-based synthesis strategy for the production of Zr-MOF-coated textiles. Among all MOF/fiber composites reported to date, the MOF-808/polyester fibers exhibit the highest rates of nerve agent hydrolysis. Moreover, such highly porous fiber composites display significantly higher protection time compared to that of its parent fabric for a mustard gas simulant, 2-chloroethyl ethyl sulfide (CEES). A decreased diffusion rate of toxic chemicals through the MOF layer can provide time needed for the destruction of the harmful species. |
| Author | Chen, Yongwei Peterson, Gregory W Wasson, Megan C Xin, John H Farha, Omar K Wang, Yuanfeng Li, Peng Ma, Kaikai Islamoglu, Timur Chen, Zhijie |
| AuthorAffiliation | Research Centre for Smart Wearable Technology, Institute of Textiles and Clothing U.S. Army Combat Capabilities Development Command Chemical Biological Center Chemical and Biological Engineering Department of Chemistry and International Institute of Nanotechnology |
| AuthorAffiliation_xml | – name: Chemical and Biological Engineering – name: Department of Chemistry and International Institute of Nanotechnology – name: U.S. Army Combat Capabilities Development Command Chemical Biological Center – name: Research Centre for Smart Wearable Technology, Institute of Textiles and Clothing |
| Author_xml | – sequence: 1 givenname: Kaikai orcidid: 0000-0003-0414-4397 surname: Ma fullname: Ma, Kaikai organization: Research Centre for Smart Wearable Technology, Institute of Textiles and Clothing – sequence: 2 givenname: Timur orcidid: 0000-0003-3688-9158 surname: Islamoglu fullname: Islamoglu, Timur – sequence: 3 givenname: Zhijie orcidid: 0000-0001-9232-7382 surname: Chen fullname: Chen, Zhijie – sequence: 4 givenname: Peng orcidid: 0000-0002-4273-4577 surname: Li fullname: Li, Peng – sequence: 5 givenname: Megan C orcidid: 0000-0002-9384-2033 surname: Wasson fullname: Wasson, Megan C – sequence: 6 givenname: Yongwei surname: Chen fullname: Chen, Yongwei – sequence: 7 givenname: Yuanfeng surname: Wang fullname: Wang, Yuanfeng organization: Research Centre for Smart Wearable Technology, Institute of Textiles and Clothing – sequence: 8 givenname: Gregory W orcidid: 0000-0003-3467-5295 surname: Peterson fullname: Peterson, Gregory W organization: U.S. Army Combat Capabilities Development Command Chemical Biological Center – sequence: 9 givenname: John H surname: Xin fullname: Xin, John H email: tcxinjh@polyu.edu.hk organization: Research Centre for Smart Wearable Technology, Institute of Textiles and Clothing – sequence: 10 givenname: Omar K orcidid: 0000-0002-9904-9845 surname: Farha fullname: Farha, Omar K email: o-farha@northwestern.edu |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31532665$$D View this record in MEDLINE/PubMed |
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| Snippet | Organophosphonate-based nerve agents, such as VX, Sarin (GB), and Soman (GD), are among the most toxic chemicals to humankind. Recently, we have shown that... |
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| SubjectTerms | coatings coordination polymers fabrics hydrolysis nerve agents organic sulfur compounds polyesters textile fibers toxicity |
| Title | Scalable and Template-Free Aqueous Synthesis of Zirconium-Based Metal–Organic Framework Coating on Textile Fiber |
| URI | http://dx.doi.org/10.1021/jacs.9b07301 https://www.ncbi.nlm.nih.gov/pubmed/31532665 https://www.proquest.com/docview/2293974856 https://www.proquest.com/docview/2327991342 |
| Volume | 141 |
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