Polymeric Nanomaterials Based on the Buckybowl Motif: Synthesis through Ring-Opening Metathesis Polymerization and Energy Storage Applications
Ring-opening metathesis polymerization (ROMP) of buckybowl corannulene-based oxa-norbornadiene monomer is shown to give rise to polymeric nanomaterials with an average pore size of about 1.4 nm and a surface area of 49.2 m2/g. Application in supercapacitor devices show that the corannulene-based nan...
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| Published in | ACS macro letters Vol. 6; no. 11; pp. 1212 - 1216 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
21.11.2017
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| Abstract | Ring-opening metathesis polymerization (ROMP) of buckybowl corannulene-based oxa-norbornadiene monomer is shown to give rise to polymeric nanomaterials with an average pore size of about 1.4 nm and a surface area of 49.2 m2/g. Application in supercapacitor devices show that the corannulene-based nanomaterials exhibit a specific capacitance of 134 F·g–1 (1.0 V voltage window) in a three-electrode cell configuration. Moreover, the electrode assembled from these materials in a symmetric configuration (1.6 V voltage window) exhibits long-term cyclability of 90% capacitance retention after undergoing 10000 cycles. This work demonstrates that ROMP is a valuable method in synthesizing nanostructured corannulene polymers, and that materials based on the nonplanar polycyclic aromatic motif represents an attractive active component for fabrication of devices targeted at electrochemical energy storage applications. |
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| AbstractList | Ring-opening metathesis polymerization (ROMP) of buckybowl corannulene-based oxa-norbornadiene monomer is shown to give rise to polymeric nanomaterials with an average pore size of about 1.4 nm and a surface area of 49.2 m2/g. Application in supercapacitor devices show that the corannulene-based nanomaterials exhibit a specific capacitance of 134 F·g–1 (1.0 V voltage window) in a three-electrode cell configuration. Moreover, the electrode assembled from these materials in a symmetric configuration (1.6 V voltage window) exhibits long-term cyclability of 90% capacitance retention after undergoing 10000 cycles. This work demonstrates that ROMP is a valuable method in synthesizing nanostructured corannulene polymers, and that materials based on the nonplanar polycyclic aromatic motif represents an attractive active component for fabrication of devices targeted at electrochemical energy storage applications. Ring-opening metathesis polymerization (ROMP) of buckybowl corannulene-based oxa-norbornadiene monomer is shown to give rise to polymeric nanomaterials with an average pore size of about 1.4 nm and a surface area of 49.2 m /g. Application in supercapacitor devices show that the corannulene-based nanomaterials exhibit a specific capacitance of 134 F·g (1.0 V voltage window) in a three-electrode cell configuration. Moreover, the electrode assembled from these materials in a symmetric configuration (1.6 V voltage window) exhibits long-term cyclability of 90% capacitance retention after undergoing 10000 cycles. This work demonstrates that ROMP is a valuable method in synthesizing nanostructured corannulene polymers, and that materials based on the nonplanar polycyclic aromatic motif represents an attractive active component for fabrication of devices targeted at electrochemical energy storage applications. |
| Author | Mishra, Amita Sreejith, Sivaramapanicker Edison, Eldho Stuparu, Mihaiela C Borah, Parijat Ulaganathan, Mani Madhavi, Srinivasan Mishra, Abhinay |
| AuthorAffiliation | School of Materials Science and Engineering Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences School of Mechanical and Aerospace Engineering Department of Chemistry, School of Science University of Tokyo Nanyang Technological University |
| AuthorAffiliation_xml | – name: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences – name: School of Mechanical and Aerospace Engineering – name: Department of Chemistry, School of Science – name: University of Tokyo – name: School of Materials Science and Engineering – name: Nanyang Technological University |
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