Remote Control of Electron Transfer Reaction by Microwave Irradiation: Kinetic Demonstration of Reduction of Bipyridine Derivatives on Surface of Nickel Particle
Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves witho...
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| Published in | The journal of physical chemistry letters Vol. 10; no. 12; pp. 3390 - 3394 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
20.06.2019
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| Online Access | Get full text |
| ISSN | 1948-7185 1948-7185 |
| DOI | 10.1021/acs.jpclett.9b00629 |
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| Abstract | Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves without an alteration of the reaction temperature. The order of the extent of the microwave acceleration of the electron transfer reaction coincided with the negativity of the redox potential of the bipyridine derivatives, i.e., the electron transfer with smaller ΔG was significantly enhanced by microwave irradiation. By applying Marcus’ electron transfer theory, we propose two mechanisms of the microwave effect on electron transfer reactions, i.e., vibration of the electrons in Ni particles to make the electron transfer easier and rotation of the water molecules to prevent the reorganization of the hydrated systems after the electron transfer reaction. |
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| AbstractList | Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves without an alteration of the reaction temperature. The order of the extent of the microwave acceleration of the electron transfer reaction coincided with the negativity of the redox potential of the bipyridine derivatives, i.e., the electron transfer with smaller ΔG was significantly enhanced by microwave irradiation. By applying Marcus’ electron transfer theory, we propose two mechanisms of the microwave effect on electron transfer reactions, i.e., vibration of the electrons in Ni particles to make the electron transfer easier and rotation of the water molecules to prevent the reorganization of the hydrated systems after the electron transfer reaction. Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves without an alteration of the reaction temperature. The order of the extent of the microwave acceleration of the electron transfer reaction coincided with the negativity of the redox potential of the bipyridine derivatives, i.e., the electron transfer with smaller Δ G was significantly enhanced by microwave irradiation. By applying Marcus' electron transfer theory, we propose two mechanisms of the microwave effect on electron transfer reactions, i.e., vibration of the electrons in Ni particles to make the electron transfer easier and rotation of the water molecules to prevent the reorganization of the hydrated systems after the electron transfer reaction.Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves without an alteration of the reaction temperature. The order of the extent of the microwave acceleration of the electron transfer reaction coincided with the negativity of the redox potential of the bipyridine derivatives, i.e., the electron transfer with smaller Δ G was significantly enhanced by microwave irradiation. By applying Marcus' electron transfer theory, we propose two mechanisms of the microwave effect on electron transfer reactions, i.e., vibration of the electrons in Ni particles to make the electron transfer easier and rotation of the water molecules to prevent the reorganization of the hydrated systems after the electron transfer reaction. Microwave irradiation has great potential to control chemical reactions remotely, particularly reactions that involve electron transfer. In this study, we found that the reduction reaction of bipyridine derivatives on metal nickel particles was accelerated or decelerated by 2.45 GHz microwaves without an alteration of the reaction temperature. The order of the extent of the microwave acceleration of the electron transfer reaction coincided with the negativity of the redox potential of the bipyridine derivatives, i.e., the electron transfer with smaller Δ G was significantly enhanced by microwave irradiation. By applying Marcus' electron transfer theory, we propose two mechanisms of the microwave effect on electron transfer reactions, i.e., vibration of the electrons in Ni particles to make the electron transfer easier and rotation of the water molecules to prevent the reorganization of the hydrated systems after the electron transfer reaction. |
| Author | Suzuki, Eiichi Wada, Yuji Imai, Takashi Kishimoto, Fuminao Mochizuki, Dai Tsubaki, Shuntaro Maitani, Masato M Matsuhisa, Masayuki |
| AuthorAffiliation | Department of Chemical Science and Engineering, School of Materials and Chemical Technology |
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| Author_xml | – sequence: 1 givenname: Fuminao orcidid: 0000-0003-0426-5762 surname: Kishimoto fullname: Kishimoto, Fuminao email: kfuminao@chemsys.t.u-tokyo.ac.jp – sequence: 2 givenname: Masayuki surname: Matsuhisa fullname: Matsuhisa, Masayuki – sequence: 3 givenname: Takashi surname: Imai fullname: Imai, Takashi – sequence: 4 givenname: Dai orcidid: 0000-0002-3547-923X surname: Mochizuki fullname: Mochizuki, Dai – sequence: 5 givenname: Shuntaro orcidid: 0000-0002-9656-4470 surname: Tsubaki fullname: Tsubaki, Shuntaro – sequence: 6 givenname: Masato M orcidid: 0000-0002-5730-0149 surname: Maitani fullname: Maitani, Masato M – sequence: 7 givenname: Eiichi surname: Suzuki fullname: Suzuki, Eiichi – sequence: 8 givenname: Yuji surname: Wada fullname: Wada, Yuji email: yuji-w@apc.titech.ac.jp |
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| Title | Remote Control of Electron Transfer Reaction by Microwave Irradiation: Kinetic Demonstration of Reduction of Bipyridine Derivatives on Surface of Nickel Particle |
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