Distribution of heavy metals and radionuclides in the sediments and their environmental impacts in Nansha Sea area, South China Sea
Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and induc...
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Published in | Marine pollution bulletin Vol. 166; p. 112192 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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England
Elsevier Ltd
01.05.2021
Elsevier BV |
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Abstract | Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, 232Th was positively correlated with As and Pb. 238U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. 40K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities.
The geo-accumulation index (Igeo) of heavy metals in the sediment profiles was used to study the quantitative index of heavy metal pollution in sediments. [Display omitted]
•A total of 121 samples from two long sediment cores with depths of 773 cm and 420 cm were analyzed.•Four radionuclides and eight heavy metals in sediments were studied at the same time.•232Th was positively correlated with Pb. 238U showed significant positive correlation with Co, Ni, Cu, Zn and Cd.•The high concentration of As in the core was related to the environment and climate change of the Last Glacial Period. |
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AbstractList | Activity concentrations of radionuclides (²³⁸U, ²²⁶Ra, ²³²Th, and ⁴⁰K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, ²³²Th was positively correlated with As and Pb. ²³⁸U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. ⁴⁰K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities. Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, 232Th was positively correlated with As and Pb. 238U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. 40K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities. The geo-accumulation index (Igeo) of heavy metals in the sediment profiles was used to study the quantitative index of heavy metal pollution in sediments. [Display omitted] •A total of 121 samples from two long sediment cores with depths of 773 cm and 420 cm were analyzed.•Four radionuclides and eight heavy metals in sediments were studied at the same time.•232Th was positively correlated with Pb. 238U showed significant positive correlation with Co, Ni, Cu, Zn and Cd.•The high concentration of As in the core was related to the environment and climate change of the Last Glacial Period. Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, 232Th was positively correlated with As and Pb. 238U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. 40K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities. Activity concentrations of radionuclides ( U, Ra, Th, and K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, Th was positively correlated with As and Pb. U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities. Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, 232Th was positively correlated with As and Pb. 238U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. 40K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities.Activity concentrations of radionuclides (238U, 226Ra, 232Th, and 40K) in the sediments of eight sampling stations and heavy metal concentrations (Cr, Co, Ni, Cu, Zn, As, Cd, and Pb) in the sediments of two long cores from Nansha Sea area were obtained by high-purity germanium spectroscopy and inductively coupled plasma atomic emission spectrometry. In a correlation analysis between the radionuclides and heavy metals, 232Th was positively correlated with As and Pb. 238U demonstrated a significant positive correlation with Co, Ni, Cu, Zn, and Cd. 40K was positively correlated with Co, Ni, and Cu. The geo-accumulation index, pollution load index, potential ecological risk index, and multivariate statistical techniques were used to evaluate the pollution degree and possible sources of heavy metals in the sediments. An ecological risk assessment suggested that Cr, Co, Ni, Cu, Zn, Cd, and Pb were primarily derived from natural processes, while the source of As may be related to natural processes and human activities. |
ArticleNumber | 112192 |
Author | Liu, Guangshan Li, Chao Liu, Jing Liu, Min Peng, Anguo Deng, Shuang |
Author_xml | – sequence: 1 givenname: Jing surname: Liu fullname: Liu, Jing organization: School of Nuclear Science and Technology, University of South China, Hengyang 421001, China – sequence: 2 givenname: Anguo surname: Peng fullname: Peng, Anguo email: 1964849898@qq.com organization: School of Nuclear Science and Technology, University of South China, Hengyang 421001, China – sequence: 3 givenname: Shuang surname: Deng fullname: Deng, Shuang organization: School of Nuclear Science and Technology, University of South China, Hengyang 421001, China – sequence: 4 givenname: Min surname: Liu fullname: Liu, Min organization: School of Nuclear Science and Technology, University of South China, Hengyang 421001, China – sequence: 5 givenname: Guangshan surname: Liu fullname: Liu, Guangshan organization: College of the Environment and Ecology, Xiamen University, Xiamen 361005, China – sequence: 6 givenname: Chao surname: Li fullname: Li, Chao organization: College of the Environment and Ecology, Xiamen University, Xiamen 361005, China |
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SubjectTerms | Analytical methods atomic absorption spectrometry Cadmium China Chromium Cobalt Contamination assessment Copper Cores Correlation analysis Ecological risk assessment Emission analysis Environment environmental assessment Environmental impact Environmental Monitoring Geologic Sediments Germanium Heavy metal Heavy metals Humans Inductively coupled plasma Lead marine pollution Metal concentrations Metals Metals, Heavy - analysis Nansha Sea area Nickel Pollutant load Pollution index Pollution load Radioisotopes Radionuclide Radionuclide kinetics Radium 226 Radium isotopes Radium radioisotopes risk Risk Assessment Sediment Sediment samples Sediments South China Sea Spectrometry Spectroscopy Statistical analysis Water Pollutants, Chemical - analysis Zinc |
Title | Distribution of heavy metals and radionuclides in the sediments and their environmental impacts in Nansha Sea area, South China Sea |
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