Biomimetically Inspired Highly Homogeneous Hydrophilization of Graphene with Poly(l‑DOPA): Toward Electroconductive Coatings from Water-Processable Paints
Water-based processing of graphenetypically considered as physicochemically incompatible with water in the macroscaleemerges as the key challenge among the central postulates of green nanotechnology. These problematic concerns are derived from the complex nature of graphene in the family of sp2-ca...
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| Published in | ACS sustainable chemistry & engineering Vol. 10; no. 20; pp. 6596 - 6608 |
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| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
23.05.2022
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Water-based processing of graphenetypically considered as physicochemically incompatible with water in the macroscaleemerges as the key challenge among the central postulates of green nanotechnology. These problematic concerns are derived from the complex nature of graphene in the family of sp2-carbon nanoallotropes. Indeed, nanomaterials hidden under the common “graphene” signboard are very rich in morphological and physicochemical variants. In this work, inspired by the adhesion chemistry of mussel biomaterials, we have synthesized novel, water-processable graphene–polylevodopa (PDOPA) hybrids. Graphene and PDOPA were covalently amalgamated via the “growth-from” polymerization of l-DOPA (l-3,4-dihydroxyphenylalanine) monomer in air, yielding homogeneously PDOPA-coated (23 wt %) (of thickness 10–20 nm) hydrophilic flakes. The hybrids formed >1 year stable and water-processable aqueous dispersions and further conveniently processable paints of viscosity 0.4 Pa·s at 20 s–1 and a low yield stress τ0 up to 0.12 Pa, hence exhibiting long shelf-life stability and lacking sagging after application. Demonstrating their applicability, we have found them as surfactant-like nanoparticles stabilizing the larger, pristine graphene agglomerates in water in the optimized graphene/graphene–PDOPA weight ratio of 9:1. These characteristics enabled the manufacture of conveniently paintable coatings of low surface resistivity of 1.9 kΩ sq–1 (0.21 Ω·m) which, in turn, emerge as potentially applicable in textronics, radar-absorbing materials, or electromagnetic interference shielding. |
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| AbstractList | Water-based processing
of graphene—typically considered
as physicochemically incompatible with water in the macroscale—emerges
as the key challenge among the central postulates of green nanotechnology.
These problematic concerns are derived from the complex nature of
graphene in the family of sp
2
-carbon nanoallotropes. Indeed,
nanomaterials hidden under the common “graphene” signboard
are very rich in morphological and physicochemical variants. In this
work, inspired by the adhesion chemistry of mussel biomaterials, we
have synthesized novel, water-processable graphene–polylevodopa
(PDOPA) hybrids. Graphene and PDOPA were covalently amalgamated via
the “growth-from” polymerization of
l
-DOPA
(
l
-3,4-dihydroxyphenylalanine) monomer in air, yielding homogeneously
PDOPA-coated (23 wt %) (of thickness 10–20 nm) hydrophilic
flakes. The hybrids formed >1 year stable and water-processable
aqueous
dispersions and further conveniently processable paints of viscosity
0.4 Pa·s at 20 s
–1
and a low yield stress τ
0
up to 0.12 Pa, hence exhibiting long shelf-life stability
and lacking sagging after application. Demonstrating their applicability,
we have found them as surfactant-like nanoparticles stabilizing the
larger, pristine graphene agglomerates in water in the optimized graphene/graphene–PDOPA
weight ratio of 9:1. These characteristics enabled the manufacture
of conveniently paintable coatings of low surface resistivity of 1.9
kΩ sq
–1
(0.21 Ω·m) which, in turn,
emerge as potentially applicable in textronics, radar-absorbing materials,
or electromagnetic interference shielding.
Water-based processing of graphene by
means of a natural
polymer polylevodopa toward stable and functional electroconductive
coatings for textronics was elaborated and cross-verified. Water-based processing of graphenetypically considered as physicochemically incompatible with water in the macroscaleemerges as the key challenge among the central postulates of green nanotechnology. These problematic concerns are derived from the complex nature of graphene in the family of sp2-carbon nanoallotropes. Indeed, nanomaterials hidden under the common “graphene” signboard are very rich in morphological and physicochemical variants. In this work, inspired by the adhesion chemistry of mussel biomaterials, we have synthesized novel, water-processable graphene–polylevodopa (PDOPA) hybrids. Graphene and PDOPA were covalently amalgamated via the “growth-from” polymerization of l-DOPA (l-3,4-dihydroxyphenylalanine) monomer in air, yielding homogeneously PDOPA-coated (23 wt %) (of thickness 10–20 nm) hydrophilic flakes. The hybrids formed >1 year stable and water-processable aqueous dispersions and further conveniently processable paints of viscosity 0.4 Pa·s at 20 s–1 and a low yield stress τ0 up to 0.12 Pa, hence exhibiting long shelf-life stability and lacking sagging after application. Demonstrating their applicability, we have found them as surfactant-like nanoparticles stabilizing the larger, pristine graphene agglomerates in water in the optimized graphene/graphene–PDOPA weight ratio of 9:1. These characteristics enabled the manufacture of conveniently paintable coatings of low surface resistivity of 1.9 kΩ sq–1 (0.21 Ω·m) which, in turn, emerge as potentially applicable in textronics, radar-absorbing materials, or electromagnetic interference shielding. Water-based processing of graphene-typically considered as physicochemically incompatible with water in the macroscale-emerges as the key challenge among the central postulates of green nanotechnology. These problematic concerns are derived from the complex nature of graphene in the family of sp -carbon nanoallotropes. Indeed, nanomaterials hidden under the common "graphene" signboard are very rich in morphological and physicochemical variants. In this work, inspired by the adhesion chemistry of mussel biomaterials, we have synthesized novel, water-processable graphene-polylevodopa (PDOPA) hybrids. Graphene and PDOPA were covalently amalgamated via the "growth-from" polymerization of l-DOPA (l-3,4-dihydroxyphenylalanine) monomer in air, yielding homogeneously PDOPA-coated (23 wt %) (of thickness 10-20 nm) hydrophilic flakes. The hybrids formed >1 year stable and water-processable aqueous dispersions and further conveniently processable paints of viscosity 0.4 Pa·s at 20 s and a low yield stress τ up to 0.12 Pa, hence exhibiting long shelf-life stability and lacking sagging after application. Demonstrating their applicability, we have found them as surfactant-like nanoparticles stabilizing the larger, pristine graphene agglomerates in water in the optimized graphene/graphene-PDOPA weight ratio of 9:1. These characteristics enabled the manufacture of conveniently paintable coatings of low surface resistivity of 1.9 kΩ sq (0.21 Ω·m) which, in turn, emerge as potentially applicable in textronics, radar-absorbing materials, or electromagnetic interference shielding. Water-based processing of graphene-typically considered as physicochemically incompatible with water in the macroscale-emerges as the key challenge among the central postulates of green nanotechnology. These problematic concerns are derived from the complex nature of graphene in the family of sp2-carbon nanoallotropes. Indeed, nanomaterials hidden under the common "graphene" signboard are very rich in morphological and physicochemical variants. In this work, inspired by the adhesion chemistry of mussel biomaterials, we have synthesized novel, water-processable graphene-polylevodopa (PDOPA) hybrids. Graphene and PDOPA were covalently amalgamated via the "growth-from" polymerization of l-DOPA (l-3,4-dihydroxyphenylalanine) monomer in air, yielding homogeneously PDOPA-coated (23 wt %) (of thickness 10-20 nm) hydrophilic flakes. The hybrids formed >1 year stable and water-processable aqueous dispersions and further conveniently processable paints of viscosity 0.4 Pa·s at 20 s-1 and a low yield stress τ0 up to 0.12 Pa, hence exhibiting long shelf-life stability and lacking sagging after application. Demonstrating their applicability, we have found them as surfactant-like nanoparticles stabilizing the larger, pristine graphene agglomerates in water in the optimized graphene/graphene-PDOPA weight ratio of 9:1. These characteristics enabled the manufacture of conveniently paintable coatings of low surface resistivity of 1.9 kΩ sq-1 (0.21 Ω·m) which, in turn, emerge as potentially applicable in textronics, radar-absorbing materials, or electromagnetic interference shielding. |
| Author | Dzido, Grzegorz Zięba, Monika Yahya, Noorhana Kuziel, Anna Kolanowska, Anna Koziol, Krzysztof K. Jóźwiak, Bertrand Beunat, Juliette Thakur, Vijay Kumar Korczeniewski, Emil Terzyk, Artur P. Boncel, Sławomir Jędrysiak, Rafał G. |
| AuthorAffiliation | Cambridge Graphene Centre, Engineering Department Spin Eight Nanotechnologies Sdn. Bhd. 28 Cranfield University Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology University of Petroleum & Energy Studies (UPES) Enhanced Composites and Structures Centre, School of Aerospace, Transport and Manufacturing Nicolaus Copernicus University in Toruń Department of Fundamental and Applied Sciences School of Engineering Department of Chemical Engineering and Process Design Biorefining and Advanced Materials Research Center, SRUC Faculty of Chemistry, Physicochemistry of Carbon Materials Research Group |
| AuthorAffiliation_xml | – name: Faculty of Chemistry, Physicochemistry of Carbon Materials Research Group – name: Department of Fundamental and Applied Sciences – name: Cranfield University – name: Nicolaus Copernicus University in Toruń – name: Spin Eight Nanotechnologies Sdn. Bhd. 28 – name: Biorefining and Advanced Materials Research Center, SRUC – name: School of Engineering – name: Enhanced Composites and Structures Centre, School of Aerospace, Transport and Manufacturing – name: Department of Chemical Engineering and Process Design – name: Cambridge Graphene Centre, Engineering Department – name: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology – name: University of Petroleum & Energy Studies (UPES) |
| Author_xml | – sequence: 1 givenname: Anna surname: Kuziel fullname: Kuziel, Anna organization: Cranfield University – sequence: 2 givenname: Grzegorz surname: Dzido fullname: Dzido, Grzegorz organization: Department of Chemical Engineering and Process Design – sequence: 3 givenname: Rafał G. surname: Jędrysiak fullname: Jędrysiak, Rafał G. organization: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology – sequence: 4 givenname: Anna orcidid: 0000-0002-2073-4808 surname: Kolanowska fullname: Kolanowska, Anna organization: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology – sequence: 5 givenname: Bertrand orcidid: 0000-0003-2977-5670 surname: Jóźwiak fullname: Jóźwiak, Bertrand organization: Department of Chemical Engineering and Process Design – sequence: 6 givenname: Juliette surname: Beunat fullname: Beunat, Juliette organization: Cambridge Graphene Centre, Engineering Department – sequence: 7 givenname: Emil orcidid: 0000-0001-6086-4458 surname: Korczeniewski fullname: Korczeniewski, Emil organization: Nicolaus Copernicus University in Toruń – sequence: 8 givenname: Monika surname: Zięba fullname: Zięba, Monika organization: Nicolaus Copernicus University in Toruń – sequence: 9 givenname: Artur P. surname: Terzyk fullname: Terzyk, Artur P. organization: Nicolaus Copernicus University in Toruń – sequence: 10 givenname: Noorhana surname: Yahya fullname: Yahya, Noorhana organization: Spin Eight Nanotechnologies Sdn. Bhd. 28 – sequence: 11 givenname: Vijay Kumar orcidid: 0000-0002-0790-2264 surname: Thakur fullname: Thakur, Vijay Kumar organization: University of Petroleum & Energy Studies (UPES) – sequence: 12 givenname: Krzysztof K. surname: Koziol fullname: Koziol, Krzysztof K. email: K.Koziol@cranfield.ac.uk organization: Cranfield University – sequence: 13 givenname: Sławomir orcidid: 0000-0002-0787-5243 surname: Boncel fullname: Boncel, Sławomir email: slawomir.boncel@polsl.pl organization: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35634268$$D View this record in MEDLINE/PubMed |
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| Keywords | hydrophilization covalent functionalization water-processing poly(l-DOPA) electroconductive coatings graphene |
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| Snippet | Water-based processing of graphenetypically considered as physicochemically incompatible with water in the macroscaleemerges as the key challenge among the... Water-based processing of graphene-typically considered as physicochemically incompatible with water in the macroscale-emerges as the key challenge among the... Water-based processing of graphene—typically considered as physicochemically incompatible with water in the macroscale—emerges as the key challenge among the... |
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| Title | Biomimetically Inspired Highly Homogeneous Hydrophilization of Graphene with Poly(l‑DOPA): Toward Electroconductive Coatings from Water-Processable Paints |
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