Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks
We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3(im)6(Him)2], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase tr...
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| Published in | Journal of the American Chemical Society Vol. 145; no. 20; pp. 11258 - 11264 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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American Chemical Society
24.05.2023
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| Abstract | We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3(im)6(Him)2], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal–organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young’s modulus, in agreement with stiffening upon vitrification. |
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| AbstractList | We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe₃(im)₆(Him)₂], which yields Fe(im)₂ upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal–organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young’s modulus, in agreement with stiffening upon vitrification. We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted . This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe (im) (Him) ], which yields Fe(im) upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal-organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young's modulus, in agreement with stiffening upon vitrification. We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3(im)6(Him)2], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal-organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young's modulus, in agreement with stiffening upon vitrification.We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3(im)6(Him)2], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal-organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young's modulus, in agreement with stiffening upon vitrification. We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe3(im)6(Him)2], which yields Fe(im)2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal–organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young’s modulus, in agreement with stiffening upon vitrification. We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24 . This material, elusive from direct synthesis, is obtained from the thermal treatment of [Fe 3 (im) 6 (Him) 2 ], which yields Fe(im) 2 upon loss of the neutral imidazole molecules. Different crystalline phase transformations are observed upon further heating, until the material melts at 482 °C. Vitrification upon cooling of the liquid phase gives rise to the first Fe-metal–organic framework glass. X-ray total scattering experiments show that the tetrahedral environment of the crystalline solids is maintained in the glass, whereas nanoindentation measurements reveal an increase in Young’s modulus, in agreement with stiffening upon vitrification. |
| Author | León-Alcaide, Luis Keen, David A. Forment-Aliaga, Alicia Christensen, Rasmus S. Jordá, José L. Brotons-Alcázar, Isaac Mínguez Espallargas, Guillermo |
| AuthorAffiliation | Instituto de Ciencia Molecular (ICMol) Universitat Politècnica de València−Consejo Superior de Investigaciones Científicas Rutherford Appleton Laboratory Center for Integrated Materials Research, Department of Chemistry and iNANO ISIS Facility Instituto de Tecnología Química (UPV-CSIC) |
| AuthorAffiliation_xml | – name: ISIS Facility – name: Center for Integrated Materials Research, Department of Chemistry and iNANO – name: Universitat Politècnica de València−Consejo Superior de Investigaciones Científicas – name: Rutherford Appleton Laboratory – name: Instituto de Ciencia Molecular (ICMol) – name: Instituto de Tecnología Química (UPV-CSIC) |
| Author_xml | – sequence: 1 givenname: Luis surname: León-Alcaide fullname: León-Alcaide, Luis organization: Instituto de Ciencia Molecular (ICMol) – sequence: 2 givenname: Rasmus S. orcidid: 0000-0003-1296-1151 surname: Christensen fullname: Christensen, Rasmus S. organization: Center for Integrated Materials Research, Department of Chemistry and iNANO – sequence: 3 givenname: David A. orcidid: 0000-0003-0376-2767 surname: Keen fullname: Keen, David A. organization: Rutherford Appleton Laboratory – sequence: 4 givenname: José L. orcidid: 0000-0002-0304-5680 surname: Jordá fullname: Jordá, José L. organization: Universitat Politècnica de València−Consejo Superior de Investigaciones Científicas – sequence: 5 givenname: Isaac orcidid: 0000-0002-1787-3348 surname: Brotons-Alcázar fullname: Brotons-Alcázar, Isaac organization: Instituto de Ciencia Molecular (ICMol) – sequence: 6 givenname: Alicia orcidid: 0000-0003-0742-0457 surname: Forment-Aliaga fullname: Forment-Aliaga, Alicia organization: Instituto de Ciencia Molecular (ICMol) – sequence: 7 givenname: Guillermo orcidid: 0000-0001-7855-1003 surname: Mínguez Espallargas fullname: Mínguez Espallargas, Guillermo email: guillermo.minguez@uv.es organization: Instituto de Ciencia Molecular (ICMol) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/37158707$$D View this record in MEDLINE/PubMed |
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| Snippet | We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24. This material, elusive from direct synthesis, is obtained from... We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted . This material, elusive from direct synthesis, is obtained from the... We describe the first meltable iron-based zeolitic imidazolate framework (ZIF), denoted MUV-24 . This material, elusive from direct synthesis, is obtained from... |
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| SubjectTerms | glass heat heat treatment imidazole liquids vitrification X-radiation |
| Title | Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks |
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