Dialumene as a Dimeric or Monomeric Al Synthon for C–F Activation in Monofluorobenzene

• Published in: Journal of the American Chemical Society Vol. 146; no. 33; pp. 23591 - 23597
• Main Authors: Liu, Xufang, Dong, Shicheng, Zhu, Jun, Inoue, Shigeyoshi
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 21.08.2024
• Subjects: aluminum; chemistry; dissociation; fluorine

The activation of C–F bonds has long been regarded as the subject of research in organometallic chemistry, given their synthetic relevance and the fact that fluorine is the most abundant halogen in the Earth’s crust. However, C–F bond activation remains a largely unsolved challenge due to the high b...