Bendable, Free-Standing Calcite Thin Films
Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO3 thin films. However, the fabrication of such films has so far been quite limited, to the e...
Saved in:
| Published in | Langmuir Vol. 31; no. 6; pp. 2014 - 2018 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
17.02.2015
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO3 thin films. However, the fabrication of such films has so far been quite limited, to the extent that their mechanical properties have not been reported. To address this, free-standing calcite thin films were prepared through repeated cycles of layer-by-layer deposition of vaterite precursor composite particles with organic polymers, followed by a phase transition to calcite. In this way, two distinct calcite thin film types were produced based on either 3.2 or 1.0 wt % organic material, with subsequent three-point bending tests revealing that both exhibit elastic bending prior to fracture. More importantly, by increasing the organic content from 1.0 to 3.2 wt %, the bending strength increased from 0.95 ± 0.26 MPa to 1.90 ± 0.21 MPa. |
|---|---|
| AbstractList | Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO3 thin films. However, the fabrication of such films has so far been quite limited, to the extent that their mechanical properties have not been reported. To address this, free-standing calcite thin films were prepared through repeated cycles of layer-by-layer deposition of vaterite precursor composite particles with organic polymers, followed by a phase transition to calcite. In this way, two distinct calcite thin film types were produced based on either 3.2 or 1.0 wt % organic material, with subsequent three-point bending tests revealing that both exhibit elastic bending prior to fracture. More importantly, by increasing the organic content from 1.0 to 3.2 wt %, the bending strength increased from 0.95 ± 0.26 MPa to 1.90 ± 0.21 MPa. Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO3 thin films. However, the fabrication of such films has so far been quite limited, to the extent that their mechanical properties have not been reported. To address this, free-standing calcite thin films were prepared through repeated cycles of layer-by-layer deposition of vaterite precursor composite particles with organic polymers, followed by a phase transition to calcite. In this way, two distinct calcite thin film types were produced based on either 3.2 or 1.0 wt % organic material, with subsequent three-point bending tests revealing that both exhibit elastic bending prior to fracture. More importantly, by increasing the organic content from 1.0 to 3.2 wt %, the bending strength increased from 0.95 ± 0.26 MPa to 1.90 ± 0.21 MPa.Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO3 thin films. However, the fabrication of such films has so far been quite limited, to the extent that their mechanical properties have not been reported. To address this, free-standing calcite thin films were prepared through repeated cycles of layer-by-layer deposition of vaterite precursor composite particles with organic polymers, followed by a phase transition to calcite. In this way, two distinct calcite thin film types were produced based on either 3.2 or 1.0 wt % organic material, with subsequent three-point bending tests revealing that both exhibit elastic bending prior to fracture. More importantly, by increasing the organic content from 1.0 to 3.2 wt %, the bending strength increased from 0.95 ± 0.26 MPa to 1.90 ± 0.21 MPa. Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the microstructures of artificial free-standing CaCO₃ thin films. However, the fabrication of such films has so far been quite limited, to the extent that their mechanical properties have not been reported. To address this, free-standing calcite thin films were prepared through repeated cycles of layer-by-layer deposition of vaterite precursor composite particles with organic polymers, followed by a phase transition to calcite. In this way, two distinct calcite thin film types were produced based on either 3.2 or 1.0 wt % organic material, with subsequent three-point bending tests revealing that both exhibit elastic bending prior to fracture. More importantly, by increasing the organic content from 1.0 to 3.2 wt %, the bending strength increased from 0.95 ± 0.26 MPa to 1.90 ± 0.21 MPa. |
| Author | Nakamura, Shiho Naka, Kensuke |
| AuthorAffiliation | Kyoto Institute of Technology Department of Chemistry and Materials Technology, Graduate School of Science and Technology |
| AuthorAffiliation_xml | – name: Kyoto Institute of Technology – name: Department of Chemistry and Materials Technology, Graduate School of Science and Technology |
| Author_xml | – sequence: 1 givenname: Shiho surname: Nakamura fullname: Nakamura, Shiho – sequence: 2 givenname: Kensuke surname: Naka fullname: Naka, Kensuke email: kenaka@kit.ac.jp |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25621634$$D View this record in MEDLINE/PubMed |
| BookMark | eNqF0EtLw0AUBeBBFPvQhX9AshFUjJ33NEstVoWCC-t6mMzc6JRkUjPJwn9vpK0LKbi6m-8eOGeEDkMdAKEzgm8JpmRSGoE5VmJ9gIZEUJyKKVWHaIgVZ6nikg3QKMYVxjhjPDtGAyokJZLxIbq-h-BMXsJNMm8A0tfWBOfDezIzpfUtJMsPH5K5L6t4go4KU0Y43d4xeps_LGdP6eLl8Xl2t0gNF6RNqXF2SqdTQQtpQDia86zgRDnJC6UMz6kExoRwTgqGC2wtc1lOeK4YWHDAxuhyk7tu6s8OYqsrHy2UpQlQd1HTvockRBH-LyVSSMwF46Sn51va5RU4vW58ZZovvZuiB5MNsE0dYwOF7vub1tehbYwvNcH6Z2z9O3b_cfXnYxe6z15srLFRr-quCf2Ee9w3NXOHkw |
| CitedBy_id | crossref_primary_10_1016_j_jhazmat_2024_136667 crossref_primary_10_1038_pj_2016_69 crossref_primary_10_1002_adfm_201704956 crossref_primary_10_1016_j_jcis_2021_06_171 crossref_primary_10_1038_s41598_018_27746_x |
| Cites_doi | 10.1002/adma.201100010 10.1002/1521-4095(20020618)14:12<869::AID-ADMA869>3.0.CO;2-E 10.1007/s10853-007-2414-z 10.1021/cm010110k 10.1021/cg200947c 10.1073/pnas.0631609100 10.1021/la403193e 10.1016/j.jcrysgro.2012.01.037 10.1039/c0cs00121j 10.1098/rspb.1988.0056 10.1111/j.1151-2916.1968.tb11899.x 10.1039/B315478E 10.1073/pnas.84.9.2732 10.1007/s00402-010-1118-z 10.1002/adma.201303470 10.1021/cr078270o 10.1002/anie.201103407 10.1002/anie.200200562 10.1246/bcsj.79.1834 10.1021/cm011035g 10.1111/j.1551-2916.2007.02118.x 10.1021/cr8002856 10.1021/cr800443h 10.1021/la7013286 |
| ContentType | Journal Article |
| DBID | AAYXX CITATION CGR CUY CVF ECM EIF NPM 7X8 7S9 L.6 |
| DOI | 10.1021/la504075p |
| DatabaseName | CrossRef Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | MEDLINE MEDLINE - Academic AGRICOLA |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: EIF name: MEDLINE url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/medline/basic-search sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5827 |
| EndPage | 2018 |
| ExternalDocumentID | 25621634 10_1021_la504075p b102902713 |
| Genre | Research Support, Non-U.S. Gov't Journal Article |
| GroupedDBID | - .K2 02 4.4 53G 55A 5GY 5VS 7~N AABXI ABFLS ABMVS ABPTK ABUCX ACGFS ACJ ACNCT ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CS3 DU5 EBS ED ED~ EJD F5P GNL IH9 IHE JG JG~ K2 LG6 RNS ROL TN5 UI2 UPT VF5 VG9 W1F X --- -~X AAHBH AAYXX ABBLG ABJNI ABLBI ABQRX ADHLV AGXLV AHGAQ CITATION CUPRZ GGK YQT ~02 CGR CUY CVF ECM EIF NPM 7X8 7S9 L.6 |
| ID | FETCH-LOGICAL-a451t-2adc828852f6ae5d2b49f417d64f77a4b26e3355dd6530f0cc3d9b14b73ecede3 |
| IEDL.DBID | ACS |
| ISSN | 0743-7463 1520-5827 |
| IngestDate | Fri Jul 11 07:27:55 EDT 2025 Fri Jul 11 11:38:19 EDT 2025 Thu Jan 02 22:16:26 EST 2025 Tue Jul 01 02:30:35 EDT 2025 Thu Apr 24 23:09:02 EDT 2025 Thu Aug 27 13:41:57 EDT 2020 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 6 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a451t-2adc828852f6ae5d2b49f417d64f77a4b26e3355dd6530f0cc3d9b14b73ecede3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PMID | 25621634 |
| PQID | 1656045341 |
| PQPubID | 23479 |
| PageCount | 5 |
| ParticipantIDs | proquest_miscellaneous_2000611714 proquest_miscellaneous_1656045341 pubmed_primary_25621634 crossref_citationtrail_10_1021_la504075p crossref_primary_10_1021_la504075p acs_journals_10_1021_la504075p |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2015-02-17 |
| PublicationDateYYYYMMDD | 2015-02-17 |
| PublicationDate_xml | – month: 02 year: 2015 text: 2015-02-17 day: 17 |
| PublicationDecade | 2010 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | Langmuir |
| PublicationTitleAlternate | Langmuir |
| PublicationYear | 2015 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | Naka K. (ref12/cit12) 2001; 13 Yao H.-B. (ref11/cit11) 2011; 40 Naka K. (ref19/cit19) 2007; 23 Okumura T. (ref3/cit3) 2011; 12 Cusack M. (ref4/cit4) 2008; 108 Sun J. M. (ref22/cit22) 2010; 53 Devries R. C. (ref23/cit23) 1968; 51 Estroff L. A. (ref8/cit8) 2001; 13 Takahashi K. (ref1/cit1) 2004 Kim S. (ref13/cit13) 2011; 23 Nakamura S. (ref18/cit18) 2013; 29 Cölfen H. (ref15/cit15) 2003; 42 Jackson A. P. (ref21/cit21) 1988; 234 Sato I. (ref25/cit25) 2008; 91 Zhang T. (ref6/cit6) 2011; 50 Doncieux A. (ref24/cit24) 2008; 43 Kato T. (ref2/cit2) 2002; 14 Imai H. (ref10/cit10) 2006; 79 Addadi L. (ref16/cit16) 1987; 84 Meldrum F. C. (ref9/cit9) 2008; 108 Yao H.-B. (ref7/cit7) 2014; 26 Dong L. (ref14/cit14) 2012; 343 Richter B. I. (ref20/cit20) 2011; 131 Gower L. B. (ref17/cit17) 2008; 108 Gao H. (ref5/cit5) 2003; 100 |
| References_xml | – volume: 23 start-page: 2009 year: 2011 ident: ref13/cit13 publication-title: Adv. Mater. doi: 10.1002/adma.201100010 – volume: 14 start-page: 869 year: 2002 ident: ref2/cit2 publication-title: Adv. Mater. doi: 10.1002/1521-4095(20020618)14:12<869::AID-ADMA869>3.0.CO;2-E – volume: 43 start-page: 4167 year: 2008 ident: ref24/cit24 publication-title: J. Mater. Sci. doi: 10.1007/s10853-007-2414-z – volume: 13 start-page: 3227 year: 2001 ident: ref8/cit8 publication-title: Chem. Mater. doi: 10.1021/cm010110k – volume: 12 start-page: 224 year: 2011 ident: ref3/cit3 publication-title: Cryst. Growth Design doi: 10.1021/cg200947c – volume: 100 start-page: 5597 year: 2003 ident: ref5/cit5 publication-title: Proc. Natl. Acad. Sci. U. S. A. doi: 10.1073/pnas.0631609100 – volume: 29 start-page: 15888 year: 2013 ident: ref18/cit18 publication-title: Langmuir doi: 10.1021/la403193e – volume: 343 start-page: 86 year: 2012 ident: ref14/cit14 publication-title: J. Cryst. Growth doi: 10.1016/j.jcrysgro.2012.01.037 – volume: 40 start-page: 3764 year: 2011 ident: ref11/cit11 publication-title: Chem. Soc. Rev. doi: 10.1039/c0cs00121j – volume: 234 start-page: 415 year: 1988 ident: ref21/cit21 publication-title: Proc. R. Soc. London B doi: 10.1098/rspb.1988.0056 – volume: 51 start-page: 387 year: 1968 ident: ref23/cit23 publication-title: J. Am. Ceram. Soc. doi: 10.1111/j.1151-2916.1968.tb11899.x – start-page: 996 year: 2004 ident: ref1/cit1 publication-title: Chem. Commun. doi: 10.1039/B315478E – volume: 84 start-page: 2732 year: 1987 ident: ref16/cit16 publication-title: Proc. Natl. Acad. Sci. U. S. A. doi: 10.1073/pnas.84.9.2732 – volume: 131 start-page: 191 year: 2011 ident: ref20/cit20 publication-title: Arch. Orthop. Trauma. Surg. doi: 10.1007/s00402-010-1118-z – volume: 26 start-page: 163 year: 2014 ident: ref7/cit7 publication-title: Adv. Mater. doi: 10.1002/adma.201303470 – volume: 53 start-page: 380 year: 2010 ident: ref22/cit22 publication-title: Sci. China: Phys., Mech. Astron. – volume: 108 start-page: 4433 year: 2008 ident: ref4/cit4 publication-title: Chem. Rev. doi: 10.1021/cr078270o – volume: 50 start-page: 10361 year: 2011 ident: ref6/cit6 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201103407 – volume: 42 start-page: 2350 year: 2003 ident: ref15/cit15 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200200562 – volume: 79 start-page: 1834 year: 2006 ident: ref10/cit10 publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.79.1834 – volume: 13 start-page: 3245 year: 2001 ident: ref12/cit12 publication-title: Chem. Mater. doi: 10.1021/cm011035g – volume: 91 start-page: 607 year: 2008 ident: ref25/cit25 publication-title: J. Am. Ceram. Soc. doi: 10.1111/j.1551-2916.2007.02118.x – volume: 108 start-page: 4332 year: 2008 ident: ref9/cit9 publication-title: Chem. Rev. doi: 10.1021/cr8002856 – volume: 108 start-page: 4551 year: 2008 ident: ref17/cit17 publication-title: Chem. Rev. doi: 10.1021/cr800443h – volume: 23 start-page: 9057 year: 2007 ident: ref19/cit19 publication-title: Langmuir doi: 10.1021/la7013286 |
| SSID | ssj0009349 |
| Score | 2.1726885 |
| Snippet | Since the hardness and toughness of natural nacre are determined by hierarchical microstructures with organic matters, it is of great importance to control the... |
| SourceID | proquest pubmed crossref acs |
| SourceType | Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 2014 |
| SubjectTerms | bending strength calcite calcium carbonate Calcium Carbonate - chemistry Elasticity Glass - chemistry Hardness Materials Testing Mechanical Phenomena microstructure nacre phase transition polymers vaterite |
| Title | Bendable, Free-Standing Calcite Thin Films |
| URI | http://dx.doi.org/10.1021/la504075p https://www.ncbi.nlm.nih.gov/pubmed/25621634 https://www.proquest.com/docview/1656045341 https://www.proquest.com/docview/2000611714 |
| Volume | 31 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV3JTgMxDLVYDnBhX8qmYTkgxMBM1ukRClXFgUupxG2UxSMhhoJoe-HrSWYpIFq4O0riOPKzbD8DnHBLiTRchsxIDJmKVKgpF6HztDQRSktuiyrfe9HpsbtH_jgDx1My-CS-zBV3hib52yzME5FIH2FdtbpfzLq0xLiea1MyQWv6oO9Lvesxg5-uZwqeLPxKexlu6u6cspzk-WI01Bfm4zdZ419HXoGlClcGV6UhrMIM9tdgoVWPc1uHs2t00bfO8TxovyOG3aqhJWip3DjcGfgJnkH7KX8ZbECvffvQ6oTVoIRQMR4PQ6KscZFTwkkmFHJLNGtmLJZWsExKxTQRSB2wsFZwGmWRMdQ2dcy0pGjQIt2Euf5rH7choJYxXxKBJEOWsMShFfdLVdK0xkQY8QYcOE2mlaEP0iKHTeJ0fOUGnNZKTk1FM-6nXeSTRI_Gom8lt8YkocP6pVKnMZ_OUH18HbmtPW8Q484NT5cpGpFiP-S9AVvlM4-3cmCPODTKdv670i4sOphUNLLHcg_mhu8j3HdQZKgPClP8BOhf06M |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV1LT9xADLaAHuBCebSwLY9QgVRVBJJ5ZLIHDnRhtZTHBZC4hcmMIyGWgMiuqvan8Ff4c3iyyVIQiBNS79aM4_HEnzX2Z4BVaTlTRipfGIW-0IH2Uy4jnyItjyOdKmnLKt-jqHMqfp3JsxG4q3thSImCVirKR_xHdoFws6sl-ZuSN1UB5T7--U3pWbG1t0NnucZYe_ek1fGrCQK-FjLs-UxbQylFLFkWaZSWpaKZiVDZSGRKaZGyCDlFXGsjyYMsMIbbZhqKVHE0aJHTuqPwgUAPc4ndduv4kdCXD6C1o_hUIuI1a9G_qrqIZ4qnEe8VGFuGs_ZHuB8aoqxiudzo99IN8_cZR-T_aakpmKxQtLc9cPtpGMF8BsZb9fC6WfjxE3PrusLWvfYton9cte94Ld01hLI9N6_Ua190r4pPcPouqn6Gsfw6x3nwuBXCFYAgy1DEIiZsRv8kHTetMQEGsgFLZOGkutZFUr7YszAZmrgB3-uzTUxFqu5me3RfEv02FL0ZMIm8JLRSO0hCFnOPNzrH6z5t7ViShCTQ8bpM2XYVupH2DZgbeNdwK4K2jLC3-PLWJy3DeOfk8CA52Dva_woTBBDLFv5QLcBY77aPiwTCeulSeRs8OH9vp3oAvMg3pw |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV1fS9xAEB-sQtsXq61_zlaNpQURY5P9k8099MGeBq1FCla4t7jZnUDpGQ9zh-iH8av41ZzNJactSp8E34fdzexM5rfMzG8APknLmTJS-cIo9IUOtJ9xGfkUaXkc6UxJW1X5HkZ7x-J7V3Yn4LrphaFDlLRSWSXxnVf3bV4zDIRfelqSzSnZr4soD_Dygp5o5df9HbrPz4wlu786e349RcDXQoYDn2lr6FkRS5ZHGqVlmWjnIlQ2ErlSWmQsQk5R19pI8iAPjOG2nYUiUxwNWuS07guYculB97jb7hzdkfryEbx2NJ9KRLxhLrp_VBf1TPl31HsEylYhLXkDN2NlVJUsf7aGg2zLXP3DE_l8tTUD0zWa9rZH5j8LE1i8hVedZojdO9j4hoV13WGbXnKO6B_VbTxeR_cMoW3PzS31kt-903IOjp_kqPMwWZwVuAget0K4QhBkOYpYxITR6N-k47Y1JsBAtmCFtJzW7l2mVeaehelYxS1Yb-43NTW5upvx0XtI9ONYtD9iFHlIaK0xkpQ05pI4usCzIW3t2JKEJPDxuEzVfhW60fYtWBhZ2HgrgriMMLhY-t8nrcLLnztJ-mP_8OA9vCacWHXyh-oDTA7Oh7hMWGyQrVQO4cHJU9vULUMZOio |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Bendable%2C+Free-Standing+Calcite+Thin+Films&rft.jtitle=Langmuir&rft.au=Nakamura%2C+Shiho&rft.au=Naka%2C+Kensuke&rft.date=2015-02-17&rft.issn=1520-5827&rft.volume=31&rft.issue=6+p.2014-2018&rft.spage=2014&rft.epage=2018&rft_id=info:doi/10.1021%2Fla504075p&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0743-7463&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0743-7463&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0743-7463&client=summon |