Solvothermal Synthesis and Characterization of Two High-Nuclearity Mixed-Valent Manganese Phosphonate Clusters
Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn19 cluster with a cylindrical...
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| Published in | Inorganic chemistry Vol. 47; no. 9; pp. 3489 - 3491 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
05.05.2008
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| Abstract | Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn19 cluster with a cylindrical core structure. Compound 2 possess a Mn16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. |
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| AbstractList | Two novel mixed-valent manganese (Mn(II)/Mn(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn 19 cluster with a cylindrical core structure. Compound 2 possess a Mn 16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. Two novel mixed-valent manganese (Mn(II)/Mn(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn 19 cluster with a cylindrical core structure. Compound 2 possess a Mn 16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers.Two novel mixed-valent manganese (Mn(II)/Mn(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn 19 cluster with a cylindrical core structure. Compound 2 possess a Mn 16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn19 cluster with a cylindrical core structure. Compound 2 possess a Mn16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. Two novel mixed-valent manganese (Mn super(II)/Mn super(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn sub(19) cluster with a cylindrical core structure. Compound 2 possess a Mn sub(16) core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers. |
| Author | Konar, Sanjit Clearfield, Abraham |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/18376822$$D View this record in MEDLINE/PubMed |
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| Notes | Syntheses, BVS calculations, selected bond distances, and magnetization curves for 1 and 2, χ′′M vs T and χ′M vs T plots for 1, and X-ray crystallographic data in CIF format. This material is available free of charge via the Internet at http://pubs.acs.org. istex:A98549ABEEC5039F3C0D8F50AC956D6B27D13B6C ark:/67375/TPS-8159BW9N-9 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| Snippet | Two novel mixed-valent manganese (MnII/MnIII) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray... Two novel mixed-valent manganese (Mn(II)/Mn(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray... Two novel mixed-valent manganese (Mn super(II)/Mn super(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal... |
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| SubjectTerms | Bonding Clusters Diffraction Infrared spectroscopy Magnetic measurement Manganese Mathematical analysis X-rays |
| Title | Solvothermal Synthesis and Characterization of Two High-Nuclearity Mixed-Valent Manganese Phosphonate Clusters |
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