Vibrational Strong Coupling with Surface Plasmons and the Presence of Surface Plasmon Stop Bands
We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We cho...
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| Published in | ACS photonics Vol. 6; no. 8; pp. 2110 - 2116 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
21.08.2019
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| Abstract | We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We choose the period of the grating so that we may observe strong coupling between the surface plasmon mode associated with a patterned gold film and the CO vibrational resonance in an overlying polymer film. We present results from experiments and numerical simulations to show that surface plasmon modes provide convenient open cavities for vibrational strong coupling experiments. In addition to providing momentum matching between surface plasmon modes and incident light, gratings may also produce a modification of the surface plasmon properties, notably their dispersion. We further show that for the parameters used in our experiment surface plasmon stop bands are formed, and we find that both stop-band edges undergo strong coupling. |
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| AbstractList | We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We choose the period of the grating so that we may observe strong coupling between the surface plasmon mode associated with a patterned gold film and the CO vibrational resonance in an overlying polymer film. We present results from experiments and numerical simulations to show that surface plasmon modes provide convenient open cavities for vibrational strong coupling experiments. In addition to providing momentum matching between surface plasmon modes and incident light, gratings may also produce a modification of the surface plasmon properties, notably their dispersion. We further show that for the parameters used in our experiment surface plasmon stop bands are formed, and we find that both stop-band edges undergo strong coupling. We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We choose the period of the grating so that we may observe strong coupling between the surface plasmon mode associated with a patterned gold film and the C=O vibrational resonance in an overlying polymer film. We present results from experiments and numerical simulations to show that surface plasmon modes provide convenient open cavities for vibrational strong coupling experiments. In addition to providing momentum matching between surface plasmon modes and incident light, gratings may also produce a modification of the surface plasmon properties, notably their dispersion. We further show that for the parameters used in our experiment surface plasmon stop bands are formed, and we find that both stop-band edges undergo strong coupling. We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We choose the period of the grating so that we may observe strong coupling between the surface plasmon mode associated with a patterned gold film and the C=O vibrational resonance in an overlying polymer film. We present results from experiments and numerical simulations to show that surface plasmon modes provide convenient open cavities for vibrational strong coupling experiments. In addition to providing momentum matching between surface plasmon modes and incident light, gratings may also produce a modification of the surface plasmon properties, notably their dispersion. We further show that for the parameters used in our experiment surface plasmon stop bands are formed, and we find that both stop-band edges undergo strong coupling. |
| Author | Menghrajani, Kishan S Barnes, William L Nash, Geoffrey R |
| AuthorAffiliation | College of Engineering, Mathematics and Physical Sciences |
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| Author_xml | – sequence: 1 givenname: Kishan S orcidid: 0000-0002-9282-9689 surname: Menghrajani fullname: Menghrajani, Kishan S email: km508@exeter.ac.uk – sequence: 2 givenname: Geoffrey R surname: Nash fullname: Nash, Geoffrey R – sequence: 3 givenname: William L surname: Barnes fullname: Barnes, William L email: w.l.barnes@exeter.ac.uk |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31475218$$D View this record in MEDLINE/PubMed |
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| Keywords | vibrational resonance Rabi splitting strong coupling hybrid polariton surface plasmon |
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| Snippet | We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the... We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the... We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the... |
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| Title | Vibrational Strong Coupling with Surface Plasmons and the Presence of Surface Plasmon Stop Bands |
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