A Mild Photoactivated Hydrophilic/Hydrophobic Switch
Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties of functionalized surfaces. In this paper, we report on systems where soft UV irradiation (λ = 365 nm) converts a “low” activity fluorocarbon to a “high” activity amine-functiona...
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Published in | Langmuir Vol. 21; no. 10; pp. 4554 - 4561 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
10.05.2005
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Abstract | Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties of functionalized surfaces. In this paper, we report on systems where soft UV irradiation (λ = 365 nm) converts a “low” activity fluorocarbon to a “high” activity amine-functionalized surface. An amine-functionalized SAM (self-assembled monolayer) is first masked using a tertiary amine catalyzed reaction with an N-hydroxysuccinimidyl carbonyl reagent. This mild, room-temperature reaction introduces a hydrophobic photocleavable nitrobenzyl “protecting group” terminated with a fluorocarbon end-chain. UV irradiation (λ = 365 nm) of this hydrophobic/fluorocarbon surface cleaves the nitrobenzyl residue, returning the surface to the original hydrophilic/amine-functionalized state. This provides a mild, generic method of producing surfaces with hydrophilic/hydrophobic patterns or patterned with amine functional residues. Two different protecting groups, one terminated with a single and the other with three fluorocarbon end chains, are compared. In the case of the more bulky protecting group, only a small proportion of the amine residues react, but the surface is equally hydrophobic and the amine residues equally well shielded from further reaction. Surfaces are characterized by X-ray photoelectron spectroscopy, ellipsometry, surface potential, and contact angle measurements. Images of the photopatterned SAMs were obtained using scanning electron microscopy. |
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AbstractList | Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties offunctionalized surfaces. In this paper, we report on systems where soft UV irradiation (lambda = 365 nm) converts a "low" activity fluorocarbon to a "high" activity amine-functionalized surface. An amine-functionalized SAM (self-assembled monolayer) is first masked using a tertiary amine catalyzed reaction with an N-hydroxysuccinimidyl carbonyl reagent. This mild, room-temperature reaction introduces a hydrophobic photocleavable nitrobenzyl "protecting group" terminated with a fluorocarbon end-chain. UV irradiation (lambda = 365 nm) of this hydrophobic/fluorocarbon surface cleaves the nitrobenzyl residue, returning the surface to the original hydrophilic/amine-functionalized state. This provides a mild, generic method of producing surfaces with hydrophilic/hydrophobic patterns or patterned with amine functional residues. Two different protecting groups, one terminated with a single and the other with three fluorocarbon end chains, are compared. In the case of the more bulky protecting group, only a small proportion of the amine residues react, but the surface is equally hydrophobic and the amine residues equally well shielded from further reaction. Surfaces are characterized by X-ray photoelectron spectroscopy, ellipsometry, surface potential, and contact angle measurements. Images of the photopatterned SAMs were obtained using scanning electron microscopy. Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties of functionalized surfaces. In this paper, we report on systems where soft UV irradiation (λ = 365 nm) converts a “low” activity fluorocarbon to a “high” activity amine-functionalized surface. An amine-functionalized SAM (self-assembled monolayer) is first masked using a tertiary amine catalyzed reaction with an N-hydroxysuccinimidyl carbonyl reagent. This mild, room-temperature reaction introduces a hydrophobic photocleavable nitrobenzyl “protecting group” terminated with a fluorocarbon end-chain. UV irradiation (λ = 365 nm) of this hydrophobic/fluorocarbon surface cleaves the nitrobenzyl residue, returning the surface to the original hydrophilic/amine-functionalized state. This provides a mild, generic method of producing surfaces with hydrophilic/hydrophobic patterns or patterned with amine functional residues. Two different protecting groups, one terminated with a single and the other with three fluorocarbon end chains, are compared. In the case of the more bulky protecting group, only a small proportion of the amine residues react, but the surface is equally hydrophobic and the amine residues equally well shielded from further reaction. Surfaces are characterized by X-ray photoelectron spectroscopy, ellipsometry, surface potential, and contact angle measurements. Images of the photopatterned SAMs were obtained using scanning electron microscopy. |
Author | Critchley, Kevin Ishida, Masaya Shimoda, Tatsuya Evans, Stephen D Fukushima, Hitoshi Jeyadevan, Jeyaratnam P Bushby, Richard J |
Author_xml | – sequence: 1 givenname: Kevin surname: Critchley fullname: Critchley, Kevin – sequence: 2 givenname: Jeyaratnam P surname: Jeyadevan fullname: Jeyadevan, Jeyaratnam P – sequence: 3 givenname: Hitoshi surname: Fukushima fullname: Fukushima, Hitoshi – sequence: 4 givenname: Masaya surname: Ishida fullname: Ishida, Masaya – sequence: 5 givenname: Tatsuya surname: Shimoda fullname: Shimoda, Tatsuya – sequence: 6 givenname: Richard J surname: Bushby fullname: Bushby, Richard J – sequence: 7 givenname: Stephen D surname: Evans fullname: Evans, Stephen D |
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Keywords | Measurement Self assembly Monolayer Modification X ray Fluorocarbon Hydrophobicity Contact potential Surface properties Photoelectron spectrometry Chemical properties Surface activity Surface potential Protecting group Scanning electron microscopy Catalytic reaction Mask Method Carbonyl Physical properties Contact surface Ellipsometry Halogenated hydrocarbon Ultraviolet irradiation Residue Reagents Potential surface Tertiary amine Room temperature |
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Snippet | Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties of functionalized surfaces. In this... Surface modification using light is one of the most powerful methods for controlling the physical and chemical properties offunctionalized surfaces. In this... |
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SubjectTerms | Catalysis Chemistry Exact sciences and technology General and physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
Title | A Mild Photoactivated Hydrophilic/Hydrophobic Switch |
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