Revisiting the Morphology Development of Solvent-Swollen Composite Polymer Particles at Thermodynamic Equilibrium

Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was examined. It changed from ex-centered PS-core/PMMA-shell to hemisphere with increasing SDS concentration. At low polymer weight fraction (w p),...

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Published inLangmuir Vol. 23; no. 11; pp. 5914 - 5919
Main Authors Saito, Naohiko, Kagari, Yoshimi, Okubo, Masayoshi
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 22.05.2007
Subjects
Chemistry
Exact sciences and technology
General and physical chemistry
Dispersed phase
Hydrocarbon
Interface tension
Toluene
Methyl methacrylate polymer
Polymer
Droplet
Free energy
Thermodynamic equilibrium
Composite material
Lauryl sulfate
Drop
Particle
Morphology
Phase separation
Benzenic compound
Styrene polymer
Calculation
Aqueous solution
Thermodynamic properties
Physicochemical properties
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Abstract Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was examined. It changed from ex-centered PS-core/PMMA-shell to hemisphere with increasing SDS concentration. At low polymer weight fraction (w p), PS and PMMA phases contained non-negligible amount of PMMA and PS, respectively. The small amount of PS and PMMA in PMMA and PS phases, respectively, affected significantly the interfacial tension between polymer/toluene and aqueous solutions. Interfacial tension between PS and PMMA phases at low w p was measured by the spinning drop method, showing a quite low value (≈10-2 mN/m). Predicted morphology obtained from calculation of minimum total interfacial free energy of the droplets using the interfacial tensions agreed well with the experimental observation.
AbstractList Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was examined. It changed from ex-centered PS-core/PMMA-shell to hemisphere with increasing SDS concentration. At low polymer weight fraction (wp), PS and PMMA phases contained non-negligible amount of PMMA and PS, respectively. The small amount of PS and PMMA in PMMA and PS phases, respectively, affected significantly the interfacial tension between polymer/toluene and aqueous solutions. Interfacial tension between PS and PMMA phases at low wp was measured by the spinning drop method, showing a quite low value ( approximately 10-2 mN/m). Predicted morphology obtained from calculation of minimum total interfacial free energy of the droplets using the interfacial tensions agreed well with the experimental observation.
Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was examined. It changed from ex-centered PS-core/PMMA-shell to hemisphere with increasing SDS concentration. At low polymer weight fraction (w p), PS and PMMA phases contained non-negligible amount of PMMA and PS, respectively. The small amount of PS and PMMA in PMMA and PS phases, respectively, affected significantly the interfacial tension between polymer/toluene and aqueous solutions. Interfacial tension between PS and PMMA phases at low w p was measured by the spinning drop method, showing a quite low value (≈10-2 mN/m). Predicted morphology obtained from calculation of minimum total interfacial free energy of the droplets using the interfacial tensions agreed well with the experimental observation.
Author Kagari, Yoshimi
Saito, Naohiko
Okubo, Masayoshi
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Issue 11
Keywords Dispersed phase
Hydrocarbon
Interface tension
Toluene
Methyl methacrylate polymer
Polymer
Droplet
Free energy
Thermodynamic equilibrium
Composite material
Lauryl sulfate
Drop
Particle
Morphology
Phase separation
Benzenic compound
Styrene polymer
Calculation
Aqueous solution
Thermodynamic properties
Physicochemical properties
Language English
License CC BY 4.0
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Part CCXCII of the series “Studies on Suspension and Emulsion”.
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Snippet Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was...
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SubjectTerms Chemistry
Exact sciences and technology
General and physical chemistry
Title Revisiting the Morphology Development of Solvent-Swollen Composite Polymer Particles at Thermodynamic Equilibrium
URI http://dx.doi.org/10.1021/la063653n
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