Regio- and Enantioselective Catalytic Monoepoxidation of Conjugated Dienes: Synthesis of Chiral Allylic cis-Epoxides
Ti(IV)-salan 4 catalyzes the diastereo- and enantioselective monoepoxidation of conjugated dienes using 30% H2O2 at rt or below even in the presence of other olefins and adjacent stereocenters. Its enantiomer, ent-4, provides access to the opposite diastereomer or enantiomer. The resultant chiral a...
Saved in:
Published in | Organic letters Vol. 17; no. 4; pp. 1058 - 1061 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
American Chemical Society
20.02.2015
Amer Chemical Soc |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Be the first to leave a comment!