Poly(N-isopropylacrylamide) Brushes Grafted from Cellulose Nanocrystals via Surface-Initiated Single-Electron Transfer Living Radical Polymerization
Cellulose nanocrystals (CNCs) or nanowhiskers produced from sulfuric acid hydrolysis of ramie fibers were used as substrates for surface chemical functionalization with thermoresponsive macromolecules. The CNCs were grafted with poly(N-isopropylacrylamide) brushes via surface-initiated single-electr...
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Published in | Biomacromolecules Vol. 11; no. 10; pp. 2683 - 2691 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
11.10.2010
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Subjects | |
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Abstract | Cellulose nanocrystals (CNCs) or nanowhiskers produced from sulfuric acid hydrolysis of ramie fibers were used as substrates for surface chemical functionalization with thermoresponsive macromolecules. The CNCs were grafted with poly(N-isopropylacrylamide) brushes via surface-initiated single-electron transfer living radical polymerization (SI-SET-LRP) under various conditions at room temperature. The grafting process was confirmed via Fourier transform IR spectroscopy and X-ray photoelectron spectroscopy and the different molecular masses of the grafts were quantified and found to depend on the initiator and monomer concentrations used. No observable damage occurred to the CNCs after grafting, as determined by X-ray diffraction. Size exclusion chromatography analyses of polymer chains cleaved from the cellulose nanocrystals indicated that a higher degree of polymerization was achieved by increasing initiator or monomer loading, most likely caused by local heterogeneities yielding higher rates of polymerization. It is expected that suspension stability, interfacial interactions, friction, and other properties of grafted CNCs can be controlled by changes in temperature and provide a unique platform for further development of stimuli-responsive nanomaterials. |
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AbstractList | Cellulose nanocrystals (CNCs) or nanowhiskers produced from sulfuric acid hydrolysis of ramie fibers were used as substrates for surface chemical functionalization with thermoresponsive macromolecules. The CNCs were grafted with poly(N-isopropylacrylamide) brushes via surface-initiated single-electron transfer living radical polymerization (SI-SET-LRP) under various conditions at room temperature. The grafting process was confirmed via Fourier transform IR spectroscopy and X-ray photoelectron spectroscopy and the different molecular masses of the grafts were quantified and found to depend on the initiator and monomer concentrations used. No observable damage occurred to the CNCs after grafting, as determined by X-ray diffraction. Size exclusion chromatography analyses of polymer chains cleaved from the cellulose nanocrystals indicated that a higher degree of polymerization was achieved by increasing initiator or monomer loading, most likely caused by local heterogeneities yielding higher rates of polymerization. It is expected that suspension stability, interfacial interactions, friction, and other properties of grafted CNCs can be controlled by changes in temperature and provide a unique platform for further development of stimuli-responsive nanomaterials. |
Author | Efimenko, Kirill Habibi, Youssef Rojas, Orlando J Venditti, Richard A Österberg, Monika Zoppe, Justin O Johansson, Leena-Sisko Laine, Janne |
Author_xml | – sequence: 1 givenname: Justin O surname: Zoppe fullname: Zoppe, Justin O – sequence: 2 givenname: Youssef surname: Habibi fullname: Habibi, Youssef – sequence: 3 givenname: Orlando J surname: Rojas fullname: Rojas, Orlando J email: ojrojas@ncsu.edu – sequence: 4 givenname: Richard A surname: Venditti fullname: Venditti, Richard A – sequence: 5 givenname: Leena-Sisko surname: Johansson fullname: Johansson, Leena-Sisko – sequence: 6 givenname: Kirill surname: Efimenko fullname: Efimenko, Kirill – sequence: 7 givenname: Monika surname: Österberg fullname: Österberg, Monika – sequence: 8 givenname: Janne surname: Laine fullname: Laine, Janne |
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Keywords | Surface reaction Graft copolymer Cellulose Electron transfer Acrylamide derivative copolymer Experimental study Grafting Esterification Thermal stability Acyl bromide Chemical modification Free radical polymerization Preparation Living copolymer Liquid solid reaction Cellulose organic ester Nanocrystal |
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Snippet | Cellulose nanocrystals (CNCs) or nanowhiskers produced from sulfuric acid hydrolysis of ramie fibers were used as substrates for surface chemical... |
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SubjectTerms | Acrylamides - chemical synthesis Acrylamides - chemistry Acrylic Resins Applied sciences Boehmeria - chemistry Calorimetry, Differential Scanning Cellulose - chemistry Cellulose and derivatives Chromatography, Gel Electron Transport Exact sciences and technology Nanoparticles - chemistry Natural polymers Photoelectron Spectroscopy Physicochemistry of polymers Polymerization Polymers - chemical synthesis Polymers - chemistry Spectroscopy, Fourier Transform Infrared X-Ray Diffraction |
Title | Poly(N-isopropylacrylamide) Brushes Grafted from Cellulose Nanocrystals via Surface-Initiated Single-Electron Transfer Living Radical Polymerization |
URI | http://dx.doi.org/10.1021/bm100719d https://www.ncbi.nlm.nih.gov/pubmed/20843063 https://search.proquest.com/docview/758832480 |
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