Longitudinal Splitting of Boron Nitride Nanotubes for the Facile Synthesis of High Quality Boron Nitride Nanoribbons

Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and magnetic properties. We report the synthesis of BNNRs through the potassium-intercalation-induced longitudinal splitting of boron nitride nanotube...

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Published inNano letters Vol. 11; no. 8; pp. 3221 - 3226
Main Authors Erickson, Kris J, Gibb, Ashley L, Sinitskii, Alexander, Rousseas, Michael, Alem, Nasim, Tour, James M, Zettl, Alex K
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 10.08.2011
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Abstract Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and magnetic properties. We report the synthesis of BNNRs through the potassium-intercalation-induced longitudinal splitting of boron nitride nanotubes (BNNTs). This facile, scalable synthesis results in narrow (down to 20 nm), few sheet (typically 2–10), high crystallinity BNNRs with very uniform widths. The BNNRs are at least 1 μm in length with minimal defects within the ribbon plane and along the ribbon edges.
AbstractList Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and magnetic properties. We report the synthesis of BNNRs through the potassium-intercalation-induced longitudinal splitting of boron nitride nanotubes (BNNTs). This facile, scalable synthesis results in narrow (down to 20 nm), few sheet (typically 2–10), high crystallinity BNNRs with very uniform widths. The BNNRs are at least 1 μm in length with minimal defects within the ribbon plane and along the ribbon edges.
Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and magnetic properties. We report the synthesis of BNNRs through the potassium-intercalation-induced longitudinal splitting of boron nitride nanotubes (BNNTs). This facile, scalable synthesis results in narrow (down to 20 nm), few sheet (typically 2-10), high crystallinity BNNRs with very uniform widths. The BNNRs are at least 1 mu m in length with minimal defects within the ribbon plane and along the ribbon edges.
Author Gibb, Ashley L
Rousseas, Michael
Sinitskii, Alexander
Zettl, Alex K
Erickson, Kris J
Alem, Nasim
Tour, James M
AuthorAffiliation Department of Chemistry
Lawrence Berkeley National Laboratory
University of California at Berkeley
Rice University
Department of Physics
AuthorAffiliation_xml – name: University of California at Berkeley
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  givenname: Kris J
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  givenname: Ashley L
  surname: Gibb
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https://www.ncbi.nlm.nih.gov/pubmed/21608991$$D View this record in MEDLINE/PubMed
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Keywords nanoribbons
splitting
Boron nitride
nanotubes
nanomaterials
Electronic properties
Graphene
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Nanotape
Crystallinity
Potassium
Magnetic properties
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Snippet Boron nitride nanoribbons (BNNRs), the boron nitride structural equivalent of graphene nanoribbons (GNRs), are predicted to possess unique electronic and...
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SubjectTerms Boron nitride
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science; rheology
Crystal defects
Crystallinity
Electron states and collective excitations in thin films, multilayers, quantum wells, mesoscopic and nanoscale systems
Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures
Exact sciences and technology
Fullerenes and related materials; diamonds, graphite
Graphene
Magnetic properties and materials
Magnetic properties of nanostructures
Materials science
Nanoscale materials and structures: fabrication and characterization
Nanostructure
Nanotubes
Physics
Ribbons
Specific materials
Splitting
Synthesis
Title Longitudinal Splitting of Boron Nitride Nanotubes for the Facile Synthesis of High Quality Boron Nitride Nanoribbons
URI http://dx.doi.org/10.1021/nl2014857
https://www.ncbi.nlm.nih.gov/pubmed/21608991
https://search.proquest.com/docview/1762053012
https://search.proquest.com/docview/883007202
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