Heteropoly Ionic Liquid Functionalized MOF-Fe: Synthesis, Characterization, and Catalytic Application in Selective Acetalization of Glycerol to Solketal as a Fuel Additive at Room Temperature, Solvent-Free Conditions
In this work, we have reported the synthesis of a series of heterogeneous catalysts, viz., [HMIm]3[PW12O40]@MOF-Fe, [HMIm]3[PMo12O40]@MOF-Fe, and [HMIm]4[SiW12O40]@MOF-Fe, by a simple impregnation method. The catalysts were characterized by several techniques, such as FTIR, EDX, XRD, SEM, element...
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| Published in | Precision Chemistry Vol. 1; no. 8; pp. 485 - 496 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
University of Science and Technology of China and American Chemical Society
23.10.2023
American Chemical Society |
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| Online Access | Get full text |
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| Abstract | In this work, we have reported the synthesis of a series of heterogeneous catalysts, viz., [HMIm]3[PW12O40]@MOF-Fe, [HMIm]3[PMo12O40]@MOF-Fe, and [HMIm]4[SiW12O40]@MOF-Fe, by a simple impregnation method. The catalysts were characterized by several techniques, such as FTIR, EDX, XRD, SEM, elemental mapping, and TGA. Among these materials, [HMIm]3[PW12O40]@MOF-Fe had more acidic sites (confirmed by potentiometric titration) and high stability around 598 °C (confirmed by TGA). The catalytic prospect of the materials was examined through selective acetalization of glycerol to solketal as a fuel additive under solvent-free and room-temperature conditions. [HMIm]3[PW12O40]@MOF-Fe exhibited the highest catalytic activity among the three catalysts in terms of glycerol conversion (100%), solketal selectivity (100%), and solketal yield (100%). A recyclability study of [HMIm]3[PW12O40]@MOF-Fe showed that the material could be reused for up to 7 cycles with insignificant loss in its catalytic performance. |
|---|---|
| AbstractList | In this work, we have reported the synthesis of a series
of heterogeneous
catalysts, viz., [HMIm]
3
[PW
12
O
40
]@MOF-Fe,
[HMIm]
3
[PMo
12
O
40
]@MOF-Fe, and
[HMIm]
4
[SiW
12
O
40
]@MOF-Fe, by
a simple impregnation method. The catalysts were characterized by
several techniques, such as FTIR, EDX, XRD, SEM, elemental mapping,
and TGA. Among these materials, [HMIm]
3
[PW
12
O
40
]@MOF-Fe had more acidic sites (confirmed by
potentiometric titration) and high stability around 598 °C (confirmed
by TGA). The catalytic prospect of the materials was examined through
selective acetalization of glycerol to solketal as a fuel additive
under solvent-free and room-temperature conditions. [HMIm]
3
[PW
12
O
40
]@MOF-Fe exhibited the highest
catalytic activity among the three catalysts in terms of glycerol
conversion (100%), solketal selectivity (100%), and solketal yield
(100%). A recyclability study of [HMIm]
3
[PW
12
O
40
]@MOF-Fe showed that the material could be reused
for up to 7 cycles with insignificant loss in its catalytic performance. In this work, we have reported the synthesis of a series of heterogeneous catalysts, viz., [HMIm]3[PW12O40]@MOF-Fe, [HMIm]3[PMo12O40]@MOF-Fe, and [HMIm]4[SiW12O40]@MOF-Fe, by a simple impregnation method. The catalysts were characterized by several techniques, such as FTIR, EDX, XRD, SEM, elemental mapping, and TGA. Among these materials, [HMIm]3[PW12O40]@MOF-Fe had more acidic sites (confirmed by potentiometric titration) and high stability around 598 °C (confirmed by TGA). The catalytic prospect of the materials was examined through selective acetalization of glycerol to solketal as a fuel additive under solvent-free and room-temperature conditions. [HMIm]3[PW12O40]@MOF-Fe exhibited the highest catalytic activity among the three catalysts in terms of glycerol conversion (100%), solketal selectivity (100%), and solketal yield (100%). A recyclability study of [HMIm]3[PW12O40]@MOF-Fe showed that the material could be reused for up to 7 cycles with insignificant loss in its catalytic performance. |
| Author | Siddiqui, Zeba N. Ali, Abdulaziz Abdullah Qasem |
| AuthorAffiliation | Green Chemistry Laboratory, Organic Chemistry Division, Department of Chemistry |
| AuthorAffiliation_xml | – name: Green Chemistry Laboratory, Organic Chemistry Division, Department of Chemistry |
| Author_xml | – sequence: 1 givenname: Abdulaziz Abdullah Qasem surname: Ali fullname: Ali, Abdulaziz Abdullah Qasem – sequence: 2 givenname: Zeba N. orcidid: 0000-0002-0952-8608 surname: Siddiqui fullname: Siddiqui, Zeba N. email: zeba.ch@amu.ac.in, siddiqui_zeba@yahoo.co.in, zns.siddiqui@gmail.com |
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| Keywords | [HMIm]3[PW12O40]@MOF-Fe heterogeneous catalysis MOF-Fe selective acetalization heteropoly ionic liquids solketal glycerol |
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| Snippet | In this work, we have reported the synthesis of a series of heterogeneous catalysts, viz., [HMIm]3[PW12O40]@MOF-Fe, [HMIm]3[PMo12O40]@MOF-Fe, and... In this work, we have reported the synthesis of a series of heterogeneous catalysts, viz., [HMIm] 3 [PW 12 O 40 ]@MOF-Fe, [HMIm] 3 [PMo 12 O 40 ]@MOF-Fe, and... |
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| Title | Heteropoly Ionic Liquid Functionalized MOF-Fe: Synthesis, Characterization, and Catalytic Application in Selective Acetalization of Glycerol to Solketal as a Fuel Additive at Room Temperature, Solvent-Free Conditions |
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