Redox state of iron during high-pressure serpentinite dehydration

The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions durin...

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Published inContributions to mineralogy and petrology Vol. 169; no. 4; p. 1
Main Authors Debret, Baptiste, Bolfan-Casanova, Nathalie, Padrón-Navarta, José Alberto, Martin-Hernandez, Fatima, Andreani, Muriel, Garrido, Carlos J., López Sánchez-Vizcaíno, Vicente, Gómez-Pugnaire, María Teresa, Muñoz, Manuel, Trcera, Nicolas
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer Berlin Heidelberg 01.04.2015
Springer Nature B.V
Springer Verlag
Springer Verlag (Germany)
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Abstract The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe 3+ /Fe Total(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe 3+ /Fe Total ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe 3+ -rich antigorite (Fe 3+ /Fe Total  = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe 3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe 3+ /Fe Total(BR) (=0.34–0.41), the crystallization of Fe 2+ -rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe 3+ -rich hematite and ilmenite intergrowths suggests that the O 2 released by the crystallization of Fe 2+ -rich phases could promote hematite crystallization and a subsequent increase in f o 2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
AbstractList The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe3+/FeTotal(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe3+/FeTotal ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe3+-rich antigorite (Fe3+/FeTotal = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe3+/FeTotal(BR) (=0.34–0.41), the crystallization of Fe2+-rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe3+-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe2+-rich phases could promote hematite crystallization and a subsequent increase in fo2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe 3+ /Fe Total(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe 3+ /Fe Total ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe 3+ -rich antigorite (Fe 3+ /Fe Total  = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe 3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe 3+ /Fe Total(BR) (=0.34–0.41), the crystallization of Fe 2+ -rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe 3+ -rich hematite and ilmenite intergrowths suggests that the O 2 released by the crystallization of Fe 2+ -rich phases could promote hematite crystallization and a subsequent increase in f o 2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite-olivine-orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe^sup 3+^/Fe^sub Total(BR)^ (=0.55) and magnetite modal content (=2.8-4.3 wt%). Micro-X-ray absorption near-edge structure ([mu]-XANES) spectroscopy measurements of serpentines at the Fe-K edge show that antigorite has a lower Fe^sup 3+^/Fe^sub Total^ ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe^sup 3+^-rich antigorite (Fe^sup 3+^/Fe^sub Total^ = 0.6-0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6-2.2 wt%). This suggests a preferential partitioning of Fe^sup 3+^ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe^sup 3+^/Fe^sub Total(BR)^ (=0.34-0.41), the crystallization of Fe^sup 2+^-rich phases and the quasi-disappearance of magnetite (=0.6-1.4 wt.%). The observation of Fe^sup 3+^-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe^sup 2+^-rich phases could promote hematite crystallization and a subsequent increase in fO2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
ArticleNumber 36
Author Bolfan-Casanova, Nathalie
Padrón-Navarta, José Alberto
Debret, Baptiste
Gómez-Pugnaire, María Teresa
Trcera, Nicolas
López Sánchez-Vizcaíno, Vicente
Martin-Hernandez, Fatima
Andreani, Muriel
Garrido, Carlos J.
Muñoz, Manuel
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  givenname: Baptiste
  surname: Debret
  fullname: Debret, Baptiste
  email: baptiste.debret@durham.ac.uk
  organization: Department of Earth Sciences, Durham University, Laboratoire Magmas et Volcans, Clermont Université, Université Blaise Pascal, UMR6524 - IRD, R163, LMV, CNRS
– sequence: 2
  givenname: Nathalie
  surname: Bolfan-Casanova
  fullname: Bolfan-Casanova, Nathalie
  organization: Laboratoire Magmas et Volcans, Clermont Université, Université Blaise Pascal, UMR6524 - IRD, R163, LMV, CNRS
– sequence: 3
  givenname: José Alberto
  surname: Padrón-Navarta
  fullname: Padrón-Navarta, José Alberto
  organization: Géosciences Montpellier, Université Montpellier 2
– sequence: 4
  givenname: Fatima
  surname: Martin-Hernandez
  fullname: Martin-Hernandez, Fatima
  organization: Departamento de Física de la Tierra, Astronomía y Astrofísica I, Fac. Physics, Universidad Complutense de Madrid, Dpto. de Física de la Tierra, Instituto de Geociencias (UCM,CSIC)
– sequence: 5
  givenname: Muriel
  surname: Andreani
  fullname: Andreani, Muriel
  organization: Laboratoire de Géologie de Lyon, UMR5276, ENS — Université Lyon 1
– sequence: 6
  givenname: Carlos J.
  surname: Garrido
  fullname: Garrido, Carlos J.
  organization: Instituto Andaluz de Ciencias de la Tierra (IACT), CSIC-UGR
– sequence: 7
  givenname: Vicente
  surname: López Sánchez-Vizcaíno
  fullname: López Sánchez-Vizcaíno, Vicente
  organization: Departamento de Geología, Escuela Politécnica Superior, Universidad de Jaén (Unidad Asociada al CSIC-IACT Granada)
– sequence: 8
  givenname: María Teresa
  surname: Gómez-Pugnaire
  fullname: Gómez-Pugnaire, María Teresa
  organization: Departamento de Mineralogía y Petrología, Facultad de Ciencias, Universidad de Granada
– sequence: 9
  givenname: Manuel
  surname: Muñoz
  fullname: Muñoz, Manuel
  organization: Institut des Sciences de la Terre, Université Grenoble I
– sequence: 10
  givenname: Nicolas
  surname: Trcera
  fullname: Trcera, Nicolas
  organization: Synchrotron SOLEIL
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ID FETCH-LOGICAL-a439t-6630f0b7a189afb7aa5ba54b2e8a15cacb438a2bcb2c32dc6e046590060bab153
IEDL.DBID BENPR
ISSN 0010-7999
IngestDate Tue Oct 15 15:16:00 EDT 2024
Thu Oct 10 20:57:01 EDT 2024
Thu Sep 26 15:54:05 EDT 2024
Sat Dec 16 12:20:43 EST 2023
IsPeerReviewed true
IsScholarly true
Issue 4
Keywords Redox
Iron
Antigorite breakdown
XANES
Subduction
Language English
License Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a439t-6630f0b7a189afb7aa5ba54b2e8a15cacb438a2bcb2c32dc6e046590060bab153
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0000-0001-8043-0905
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PQPubID 48463
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crossref_primary_10_1007_s00410_015_1130_y
springer_journals_10_1007_s00410_015_1130_y
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PublicationDate 2015-04-01
PublicationDateYYYYMMDD 2015-04-01
PublicationDate_xml – month: 04
  year: 2015
  text: 2015-04-01
  day: 01
PublicationDecade 2010
PublicationPlace Berlin/Heidelberg
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PublicationTitle Contributions to mineralogy and petrology
PublicationTitleAbbrev Contrib Mineral Petrol
PublicationYear 2015
Publisher Springer Berlin Heidelberg
Springer Nature B.V
Springer Verlag
Springer Verlag (Germany)
Publisher_xml – name: Springer Berlin Heidelberg
– name: Springer Nature B.V
– name: Springer Verlag (Germany)
– name: Springer Verlag
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Snippet The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite...
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SubjectTerms Crystallization
Dehydration
Earth and Environmental Science
Earth Sciences
Geochemistry
Geology
Iron
Lithosphere
Mineral Resources
Mineralogy
Minerals
Original Paper
Petrology
Pressure
Sciences of the Universe
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Title Redox state of iron during high-pressure serpentinite dehydration
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