Biomimetic control of crystal assembly by growth in an organic hydrogel network
Calcite aggregates are mineralized in an organic poly-acrylamide hydrogel using a counter diffusion arrangement. The particles obtained show a characteristic pseudo-octahedral morphology, which is unexpected for calcite crystals. Scanning and transmission electron microscopy reveal a microstructure...
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| Published in | The American mineralogist Vol. 88; no. 4; pp. 647 - 652 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington
Mineralogical Society of America
01.04.2003
Walter de Gruyter GmbH |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Calcite aggregates are mineralized in an organic poly-acrylamide hydrogel using a counter diffusion arrangement. The particles obtained show a characteristic pseudo-octahedral morphology, which is unexpected for calcite crystals. Scanning and transmission electron microscopy reveal a microstructure composed of individual highly aligned calcite crystallites. Although the aggregates consist of independent crystallites, the X-ray diffraction patterns suggest calcite single crystals. By analogy with some biominerals, the inorganic assembly is intergrown with an organic hydrogel network. A specific model is proposed for growth of the aggregate. |
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| AbstractList | Calcite aggregates are mineralized in an organic poly-acrylamide hydrogel using a counter diffusion arrangement. The particles obtained show a characteristic pseudo-octahedral morphology, which is unexpected for calcite crystals. Scanning and transmission electron microscopy reveal a microstructure composed of individual highly aligned calcite crystallites. Although the aggregates consist of independent crystallites, the X-ray diffraction patterns suggest calcite single crystals. By analogy with some biominerals, the inorganic assembly is intergrown with an organic hydrogel network. A specific model is proposed for growth of the aggregate. Calcite aggregates are mineralized in an organic poly-acrylamide hydrogel using a counter diffusion arrangement. The particles obtained show a characteristic pseudo-octahedral morphology, which is unexpected for calcite crystals. Scanning and transmission electron microscopy reveal a microstructure composed of individual highly aligned calcite crystallites. Although the aggregates consist of independent crystallites, the X-ray diffraction patterns suggest calcite single crystals. By analogy with some biominerals, the inorganic assembly is intergrown with an organic hydrogel network. A specific model is proposed for growth of the aggregate.[PUBLICATION ABSTRACT] |
| Author | Grassmann, Olaf Löbmann, Peer Neder, Reinhard B Putnis, Andrew |
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| Title | Biomimetic control of crystal assembly by growth in an organic hydrogel network |
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