Toward Efficient and Metal-Free Emissive Devices: A Solution-Processed Host–Guest Light-Emitting Electrochemical Cell Featuring Thermally Activated Delayed Fluorescence

The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step...

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Published inACS applied materials & interfaces Vol. 9; no. 34; pp. 28810 - 28816
Main Authors Lundberg, Petter, Lindh, E. Mattias, Tang, Shi, Edman, Ludvig
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 30.08.2017
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Abstract The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host–guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m–2 when driven by a constant-current density of 770 A m–2, and 760 cd m–2 during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs.
AbstractList The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m(-2) when driven by a constant-current density of 770 A m(-2), and 760 cd m(-2) during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs.
The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host-guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m when driven by a constant-current density of 770 A m , and 760 cd m during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs.
Author Lindh, E. Mattias
Tang, Shi
Lundberg, Petter
Edman, Ludvig
AuthorAffiliation Umeå University
The Organic Photonics and Electronics Group
AuthorAffiliation_xml – name: The Organic Photonics and Electronics Group
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  surname: Lundberg
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  givenname: E. Mattias
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  surname: Edman
  fullname: Edman, Ludvig
  email: ludvig.edman@umu.se
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sustainable illumination technology
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thermally activated delayed fluorescence
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Snippet The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically...
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ECONOMIC GEOLOGY
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JOURNAL OF BIOMEDICAL OPTICS
JOURNAL OF CHEMICAL PHYSICS
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light-emitting electrochemical cell
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P836 erster Theodor
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Title Toward Efficient and Metal-Free Emissive Devices: A Solution-Processed Host–Guest Light-Emitting Electrochemical Cell Featuring Thermally Activated Delayed Fluorescence
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