Toward Efficient and Metal-Free Emissive Devices: A Solution-Processed Host–Guest Light-Emitting Electrochemical Cell Featuring Thermally Activated Delayed Fluorescence
The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step...
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Published in | ACS applied materials & interfaces Vol. 9; no. 34; pp. 28810 - 28816 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
30.08.2017
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Abstract | The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host–guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m–2 when driven by a constant-current density of 770 A m–2, and 760 cd m–2 during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs. |
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AbstractList | The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m(-2) when driven by a constant-current density of 770 A m(-2), and 760 cd m(-2) during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs. The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host-guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m when driven by a constant-current density of 770 A m , and 760 cd m during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs. |
Author | Lindh, E. Mattias Tang, Shi Lundberg, Petter Edman, Ludvig |
AuthorAffiliation | Umeå University The Organic Photonics and Electronics Group |
AuthorAffiliation_xml | – name: The Organic Photonics and Electronics Group – name: Umeå University |
Author_xml | – sequence: 1 givenname: Petter surname: Lundberg fullname: Lundberg, Petter – sequence: 2 givenname: E. Mattias surname: Lindh fullname: Lindh, E. Mattias – sequence: 3 givenname: Shi surname: Tang fullname: Tang, Shi – sequence: 4 givenname: Ludvig orcidid: 0000-0003-2495-7037 surname: Edman fullname: Edman, Ludvig email: ludvig.edman@umu.se |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28762717$$D View this record in MEDLINE/PubMed https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-140478$$DView record from Swedish Publication Index |
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Title | Toward Efficient and Metal-Free Emissive Devices: A Solution-Processed Host–Guest Light-Emitting Electrochemical Cell Featuring Thermally Activated Delayed Fluorescence |
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