Unravelling the Mechanism of Excited-State Interligand Energy Transfer and the Engineering of Dual Emission in [Ir(C∧N)2(N∧N)]+ Complexes

• Published in: Inorganic chemistry Vol. 59; no. 3; pp. 1785 - 1803
• Main Authors: Scattergood, Paul A, Ranieri, Anna M, Charalambou, Luke, Comia, Adrian, Ross, Daniel A. W, Rice, Craig R, Hardman, Samantha J. O, Heully, Jean-Louis, Dixon, Isabelle M, Massi, Massimiliano, Alary, Fabienne, Elliott, Paul I. P
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 03.02.2020
• Subjects: Chemical Sciences; Coordination chemistry; Inorganic chemistry; or physical chemistry; Theoretical and

Fundamental insights into the mechanism of triplet-excited-state interligand energy transfer dynamics and the origin of dual emission for phosphorescent iridium­(III) complexes are presented. The complexes [Ir­(C∧N)2(N∧N)]+ (HC∧N = 2-phenylpyridine (1a–c), 2-(2,4-difluorophenyl)­pyridine (2a–c), 1-b...