Silver-Loaded Aluminosilicate Aerogels As Iodine Sorbents
In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na–Al–Si−O and Al–Si–O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3...
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| Published in | ACS applied materials & interfaces Vol. 9; no. 38; pp. 32907 - 32919 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
27.09.2017
American Chemical Society (ACS) |
| Subjects | |
| Online Access | Get full text |
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| Abstract | In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na–Al–Si−O and Al–Si–O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3 solutions followed by drying and Ag+ reduction under H2/Ar to form Ag0 crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag+. During the Ag+-impregnation steps, for the Na–Al–Si−O aerogels, Na was replaced with Ag, and for the Al–Si–O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na–Al–Si–O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al–Si–O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag0-functionalized Na–Al–Si–O aerogels were >0.5 m I m s –1 (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag0-functionalized Al–Si–O aerogel was 0.31 m I m s –1. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. |
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| AbstractList | In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na–Al–Si−O and Al–Si–O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3 solutions followed by drying and Ag+ reduction under H2/Ar to form Ag0 crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag+. During the Ag+-impregnation steps, for the Na–Al–Si−O aerogels, Na was replaced with Ag, and for the Al–Si–O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na–Al–Si–O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al–Si–O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag0-functionalized Na–Al–Si–O aerogels were >0.5 m I m s –1 (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag0-functionalized Al–Si–O aerogel was 0.31 m I m s –1. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I (g). The starting materials for these scaffolds included Na-Al-Si-O and Al-Si-O aerogels, both synthesized from metal alkoxides. The Ag particles were added by soaking the aerogels in aqueous AgNO solutions followed by drying and Ag reduction under H /Ar to form Ag crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag . During the Ag -impregnation steps, for the Na-Al-Si-O aerogels, Na was replaced with Ag, and for the Al-Si-O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na-Al-Si-O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al-Si-O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag -functionalized Na-Al-Si-O aerogels were >0.5 m m (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag -functionalized Al-Si-O aerogel was 0.31 m m . The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na-Al-Si-O and Al-Si-O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3 solutions followed by drying and Ag+ reduction under H2/Ar to form Ag0 crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag+. During the Ag+-impregnation steps, for the Na-Al-Si-O aerogels, Na was replaced with Ag, and for the Al-Si-O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na-Al-Si-O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al-Si-O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag0-functionalized Na-Al-Si-O aerogels were >0.5 mI ms-1 (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag0-functionalized Al-Si-O aerogel was 0.31 mI ms-1. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine.In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na-Al-Si-O and Al-Si-O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3 solutions followed by drying and Ag+ reduction under H2/Ar to form Ag0 crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag+. During the Ag+-impregnation steps, for the Na-Al-Si-O aerogels, Na was replaced with Ag, and for the Al-Si-O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na-Al-Si-O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al-Si-O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag0-functionalized Na-Al-Si-O aerogels were >0.5 mI ms-1 (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag0-functionalized Al-Si-O aerogel was 0.31 mI ms-1. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. Here, in this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included Na–Al–Si-O and Al–Si–O aerogels, both synthesized from metal alkoxides. The Ag0 particles were added by soaking the aerogels in aqueous AgNO3 solutions followed by drying and Ag+ reduction under H2/Ar to form Ag0 crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag+. During the Ag+-impregnation steps, for the Na–Al–Si-O aerogels, Na was replaced with Ag, and for the Al–Si–O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na–Al–Si–O aerogels was comparable at ~35 atomic %, whereas the Ag-loading in unthiolated Al–Si–O aerogels was significantly lower at ~7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag0-functionalized Na–Al–Si–O aerogels were >0.5 mIms–1 (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag0-functionalized Al–Si–O aerogel was 0.31 mIms–1. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I₂(g). The starting materials for these scaffolds included Na–Al–Si−O and Al–Si–O aerogels, both synthesized from metal alkoxides. The Ag⁰ particles were added by soaking the aerogels in aqueous AgNO₃ solutions followed by drying and Ag⁺ reduction under H₂/Ar to form Ag⁰ crystallites within the aerogel matrix. In some cases, aerogels were thiolated with 3-(mercaptopropyl)trimethoxysilane as an alternative method for binding Ag⁺. During the Ag⁺-impregnation steps, for the Na–Al–Si−O aerogels, Na was replaced with Ag, and for the Al–Si–O aerogels, Si was replaced with Ag. The Ag-loading of thiolated versus nonthiolated Na–Al–Si–O aerogels was comparable at ∼35 atomic %, whereas the Ag-loading in unthiolated Al–Si–O aerogels was significantly lower at ∼7 atomic % after identical treatment. Iodine loadings in both thiolated and unthiolated Ag⁰-functionalized Na–Al–Si–O aerogels were >0.5 mI mₛ–¹ (denoting the mass of iodine captured per starting mass of the sorbent) showing almost complete utilization of the Ag through chemisorption to form AgI. Iodine loading in the thiolated and Ag⁰-functionalized Al–Si–O aerogel was 0.31 mI mₛ–¹. The control of Ag uptake over solution residence time and [Ag] demonstrates the ability to customize the Ag-loading in the base sorbent to regulate the loading capacity of iodine. |
| Author | Matyáš, Josef Li, Xiaohong Olszta, Matthew J Vienna, John D Peterson, Jacob A Riley, Brian J Kroll, Jared O |
| AuthorAffiliation | Pacific Northwest National Laboratory |
| AuthorAffiliation_xml | – name: Pacific Northwest National Laboratory |
| Author_xml | – sequence: 1 givenname: Brian J orcidid: 0000-0002-7745-6730 surname: Riley fullname: Riley, Brian J email: brian.riley@pnnl.gov – sequence: 2 givenname: Jared O surname: Kroll fullname: Kroll, Jared O – sequence: 3 givenname: Jacob A surname: Peterson fullname: Peterson, Jacob A – sequence: 4 givenname: Josef surname: Matyáš fullname: Matyáš, Josef – sequence: 5 givenname: Matthew J surname: Olszta fullname: Olszta, Matthew J – sequence: 6 givenname: Xiaohong surname: Li fullname: Li, Xiaohong – sequence: 7 givenname: John D surname: Vienna fullname: Vienna, John D |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28910079$$D View this record in MEDLINE/PubMed https://www.osti.gov/servlets/purl/1398211$$D View this record in Osti.gov |
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| Cites_doi | 10.1016/0022-3093(82)90244-7 10.1021/ja00364a005 10.1039/c1ra00351h 10.1155/2013/702496 10.2172/15009659 10.1073/pnas.48.6.982 10.1080/00387019808006772 10.1021/es400595z 10.1007/BF00540646 10.2172/7287743 10.1016/0022-3093(84)90401-0 10.13182/NT89-A34241 10.1080/14786442508634742 10.1016/j.jnucmat.2015.11.038 10.1016/S0022-3093(86)80078-3 10.1021/ie200248g 10.1016/j.jnucmat.2014.09.057 10.1016/0022-3093(88)90005-1 10.1021/ja00905a001 10.2172/911962 10.1021/es405807w 10.2172/5795448 10.1107/S0108768187097532 10.1016/0022-3093(84)90393-4 10.1021/acs.chemmater.5b00413 10.1134/S1066362209040158 10.1016/j.carbon.2015.03.070 10.13182/NT91-A16225 10.4236/jmp.2010.14031 10.1021/cm401762g 10.2172/1111567 10.1021/ja01269a023 10.6028/jres.109.002 10.13182/NT76-A31646 10.1080/18811248.1987.9733524 10.13182/NT92-A34704 10.1081/SS-120020130 10.1016/j.jnucmat.2016.04.047 10.1134/S1066362211020020 |
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| Keywords | iodine silver aerogel thiolation |
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| References | ref9/cit9 ref45/cit45 Frueh A. J. (ref41/cit41) 1957; 10 Ackley R. D. (ref24/cit24) 1973 ref56/cit56 ref16/cit16 Gal I. J. (ref25/cit25) 1974 ref52/cit52 ref59/cit59 Trevorrow L. E. (ref5/cit5) 1983 ref34/cit34 ref20/cit20 ref48/cit48 Iler R. K. (ref31/cit31) 1979 Hebel W. (ref14/cit14) 1982 ref17/cit17 ref10/cit10 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 ref13/cit13 Pence D. T. (ref26/cit26) 1972 ref61/cit61 ref38/cit38 ref50/cit50 ref64/cit64 ref54/cit54 ref6/cit6 ref18/cit18 Jubin R. (ref58/cit58) 2012 ref65/cit65 ref11/cit11 ref29/cit29 ref32/cit32 ref39/cit39 ref57/cit57 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 Khaskin I. G. (ref36/cit36) 1952; 85 Gregg S. (ref63/cit63) 1982 ref55/cit55 Burger L. L. (ref3/cit3) 2004 ref12/cit12 ref15/cit15 Shaw D. (ref37/cit37) 1980 Thomas T. R. (ref27/cit27) 1977 ref62/cit62 ref66/cit66 ref33/cit33 Pence D. T. (ref22/cit22) 1970; 2 Maeck W. J. (ref23/cit23) 1970; 2 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 Vienna J. D. (ref60/cit60) 2015 Haefner D. R. (ref8/cit8) 2007 ref44/cit44 Jubin R. T. (ref2/cit2) 1979 ref7/cit7 |
| References_xml | – ident: ref35/cit35 doi: 10.1016/0022-3093(82)90244-7 – ident: ref20/cit20 – ident: ref44/cit44 doi: 10.1021/ja00364a005 – volume-title: The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica year: 1979 ident: ref31/cit31 – ident: ref11/cit11 doi: 10.1039/c1ra00351h – ident: ref59/cit59 doi: 10.1155/2013/702496 – volume-title: HWVP Iodine Trap Evaluation, PNNL-14860 year: 2004 ident: ref3/cit3 doi: 10.2172/15009659 – ident: ref4/cit4 – ident: ref43/cit43 doi: 10.1073/pnas.48.6.982 – ident: ref64/cit64 doi: 10.1080/00387019808006772 – volume: 2 volume-title: 11th AEC Air Cleaning Conference, CONF 700816 year: 1970 ident: ref22/cit22 – ident: ref50/cit50 – ident: ref47/cit47 – ident: ref9/cit9 doi: 10.1021/es400595z – volume: 85 start-page: 129 year: 1952 ident: ref36/cit36 publication-title: Dokl. Akad. Nauk SSSR – ident: ref61/cit61 – volume: 10 start-page: 764 year: 1957 ident: ref41/cit41 publication-title: Acta Crystallogr. – ident: ref39/cit39 doi: 10.1007/BF00540646 – volume-title: Adsorption, surface area, and porosity year: 1982 ident: ref63/cit63 – ident: ref19/cit19 – volume-title: Closed Fuel Cycle Waste Treatment Strategy year: 2015 ident: ref60/cit60 – volume-title: Airborne Elemental Iodine Loading Capacities of Metal Zeolites and a Method for Recycling Silver Zeolite, ICP-1119 year: 1977 ident: ref27/cit27 doi: 10.2172/7287743 – ident: ref34/cit34 doi: 10.1016/0022-3093(84)90401-0 – ident: ref54/cit54 doi: 10.13182/NT89-A34241 – volume-title: Introduction to Colloid and Surface Chemistry year: 1980 ident: ref37/cit37 – volume-title: A Literature Survey of Methods to Remove Iodine from Off-Gas Streams using Solid Sorbents, ORNL/TM-6607 year: 1979 ident: ref2/cit2 – ident: ref51/cit51 – ident: ref40/cit40 doi: 10.1080/14786442508634742 – ident: ref1/cit1 doi: 10.1016/j.jnucmat.2015.11.038 – ident: ref29/cit29 doi: 10.1016/S0022-3093(86)80078-3 – ident: ref12/cit12 doi: 10.1021/ie200248g – ident: ref17/cit17 doi: 10.1016/j.jnucmat.2014.09.057 – ident: ref30/cit30 doi: 10.1016/0022-3093(88)90005-1 – ident: ref45/cit45 doi: 10.1021/ja00905a001 – ident: ref49/cit49 – volume-title: Methods of Gas Phase Capture of Iodine from Fuel Reprocessing Off-Gas: A Literature Survey, INL/EXT-07-12299 year: 2007 ident: ref8/cit8 doi: 10.2172/911962 – ident: ref10/cit10 doi: 10.1021/es405807w – volume-title: Radioactive Waste Management Vol. 7: Management Modes for Iodine-129 year: 1982 ident: ref14/cit14 – volume-title: Compatibility of Technologies with Regulations in the Waste Management of H-3, I-129, C-14, and Kr-85. Part I. Initial Information Base, ANL-83-57 year: 1983 ident: ref5/cit5 doi: 10.2172/5795448 – volume-title: Applicability of Inorganic Sorbents for Trapping Radioiodine from LMFBR Fuel Reprocessing Off-Gas, ORNL/TM-4227 year: 1973 ident: ref24/cit24 – ident: ref42/cit42 doi: 10.1107/S0108768187097532 – ident: ref53/cit53 – ident: ref33/cit33 doi: 10.1016/0022-3093(84)90393-4 – ident: ref28/cit28 doi: 10.1021/acs.chemmater.5b00413 – ident: ref48/cit48 – ident: ref16/cit16 doi: 10.1134/S1066362209040158 – volume: 2 volume-title: 11th AEC Air Cleaning Conference, CONF 700816 year: 1970 ident: ref23/cit23 – ident: ref15/cit15 doi: 10.1016/j.carbon.2015.03.070 – ident: ref57/cit57 doi: 10.13182/NT91-A16225 – volume-title: 12th AEC Air Cleaning Conference, CONF 720823 year: 1972 ident: ref26/cit26 – ident: ref65/cit65 doi: 10.4236/jmp.2010.14031 – ident: ref13/cit13 doi: 10.1021/cm401762g – volume-title: 13th AEC Air Cleaning Conference, CONF 740807 year: 1974 ident: ref25/cit25 – ident: ref32/cit32 – volume-title: Fuel Age Impacts on Gaseous Fission Product Capture during Separations year: 2012 ident: ref58/cit58 doi: 10.2172/1111567 – ident: ref18/cit18 – ident: ref46/cit46 – ident: ref62/cit62 doi: 10.1021/ja01269a023 – ident: ref66/cit66 doi: 10.6028/jres.109.002 – ident: ref6/cit6 doi: 10.13182/NT76-A31646 – ident: ref52/cit52 doi: 10.1080/18811248.1987.9733524 – ident: ref55/cit55 doi: 10.13182/NT92-A34704 – ident: ref21/cit21 doi: 10.1081/SS-120020130 – ident: ref7/cit7 – ident: ref38/cit38 doi: 10.1016/j.jnucmat.2016.04.047 – ident: ref56/cit56 doi: 10.1134/S1066362211020020 |
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| Snippet | In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds included... In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I (g). The starting materials for these scaffolds included... In this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I₂(g). The starting materials for these scaffolds included... Here, in this paper, aluminosilicate aerogels were used as scaffolds for silver nanoparticles to capture I2(g). The starting materials for these scaffolds... |
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| SubjectTerms | aerogel aluminosilicate aerogel crystallites drying iodine iodine capture Iodine Capture: Iodine immobilization MATERIALS SCIENCE nanosilver silicon silver silver nitrate soaking sodium sorbents |
| Title | Silver-Loaded Aluminosilicate Aerogels As Iodine Sorbents |
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