Enhanced Proton Conductivity of Sulfonated Hybrid Poly(arylene ether ketone) Membranes by Incorporating an Amino–Sulfo Bifunctionalized Metal–Organic Framework for Direct Methanol Fuel Cells
Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino–sulfo-bifunctionalized metal–organic framework (MNS, short for MIL-101-NH2-SO3H) was synthesized via a hydrothermal techno...
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| Published in | ACS applied materials & interfaces Vol. 10; no. 9; pp. 7963 - 7973 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
07.03.2018
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| Subjects | |
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| Abstract | Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino–sulfo-bifunctionalized metal–organic framework (MNS, short for MIL-101-NH2-SO3H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic–inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between −NH2 of MNS and −SO3H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm–1, which was much higher than those of the pristine membrane (0.145 S·cm–1) and recast Nafion (0.134 S·cm–1) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm2 at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane. |
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| AbstractList | Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino–sulfo-bifunctionalized metal–organic framework (MNS, short for MIL-101-NH₂-SO₃H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic–inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between −NH₂ of MNS and −SO₃H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm–¹, which was much higher than those of the pristine membrane (0.145 S·cm–¹) and recast Nafion (0.134 S·cm–¹) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm² at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane. Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino-sulfo-bifunctionalized metal-organic framework (MNS, short for MIL-101-NH -SO H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic-inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between -NH of MNS and -SO H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm , which was much higher than those of the pristine membrane (0.145 S·cm ) and recast Nafion (0.134 S·cm ) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane. Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino–sulfo-bifunctionalized metal–organic framework (MNS, short for MIL-101-NH2-SO3H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic–inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between −NH2 of MNS and −SO3H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm–1, which was much higher than those of the pristine membrane (0.145 S·cm–1) and recast Nafion (0.134 S·cm–1) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm2 at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane. Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino-sulfo-bifunctionalized metal-organic framework (MNS, short for MIL-101-NH2-SO3H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic-inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between -NH2 of MNS and -SO3H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm-1, which was much higher than those of the pristine membrane (0.145 S·cm-1) and recast Nafion (0.134 S·cm-1) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm2 at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane.Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this work, and a new amino-sulfo-bifunctionalized metal-organic framework (MNS, short for MIL-101-NH2-SO3H) was synthesized via a hydrothermal technology and postmodification. Then, MNS was incorporated into a SNF-PAEK matrix as an inorganic nanofiller to prepare a series of organic-inorganic hybrid membranes (MNS@SNF-PAEK-XX). The mechanical property, methanol resistance, electrochemistry, and other properties of MNS@SNF-PAEK-XX hybrid membranes were characterized in detail. We found that the mechanical strength and methanol resistances of these hybrid membranes were improved by the formation of an ionic cross-linking structure between -NH2 of MNS and -SO3H on the side chain of SNF-PAEK. Particularly, the proton conductivity of these hybrid membranes increased obviously after the addition of MNS. MNS@SNF-PAEK-3% exhibited the proton conductivity of 0.192 S·cm-1, which was much higher than those of the pristine membrane (0.145 S·cm-1) and recast Nafion (0.134 S·cm-1) at 80 °C. This result indicated that bifunctionalized MNS rearranged the microstructure of hybrid membranes, which could accelerate the transfer of protons. The hybrid membrane (MNS@SNF-PAEK-3%) showed a better direct methanol fuel cell performance with a higher peak power density of 125.7 mW/cm2 at 80 °C and a higher open-circuit voltage (0.839 V) than the pristine membrane. |
| Author | Na, Hui Li, Zhenhua Bu, Fanzhe Zhao, Chengji Zhuang, Zhuang Ru, Chunyu Duan, Yuting |
| AuthorAffiliation | Jilin University Key Laboratory of Advanced Batteries Physics and Technology (Ministry of Education) State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry Alan G. MacDiarmid Institute, College of Chemistry |
| AuthorAffiliation_xml | – name: Alan G. MacDiarmid Institute, College of Chemistry – name: Key Laboratory of Advanced Batteries Physics and Technology (Ministry of Education) – name: Jilin University – name: State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry |
| Author_xml | – sequence: 1 givenname: Chunyu surname: Ru fullname: Ru, Chunyu – sequence: 2 givenname: Zhenhua surname: Li fullname: Li, Zhenhua – sequence: 3 givenname: Chengji orcidid: 0000-0003-3949-8638 surname: Zhao fullname: Zhao, Chengji – sequence: 4 givenname: Yuting surname: Duan fullname: Duan, Yuting – sequence: 5 givenname: Zhuang surname: Zhuang fullname: Zhuang, Zhuang – sequence: 6 givenname: Fanzhe surname: Bu fullname: Bu, Fanzhe – sequence: 7 givenname: Hui orcidid: 0000-0002-5709-2538 surname: Na fullname: Na, Hui email: huina@jlu.edu.cn |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29439561$$D View this record in MEDLINE/PubMed |
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| Keywords | direct methanol fuel cells proton conductivity sulfonated poly(arylene ether ketone) bifunctionalized metal−organic framework polymer electrolyte membranes |
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| Snippet | Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this... Novel side-chain-type sulfonated poly(arylene ether ketone) (SNF-PAEK) containing naphthalene and fluorine moieties on the main chain was prepared in this... |
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| StartPage | 7963 |
| SubjectTerms | coordination polymers crosslinking electric power electrochemistry fluorine fuel cells methanol microstructure moieties naphthalene protons strength (mechanics) |
| Title | Enhanced Proton Conductivity of Sulfonated Hybrid Poly(arylene ether ketone) Membranes by Incorporating an Amino–Sulfo Bifunctionalized Metal–Organic Framework for Direct Methanol Fuel Cells |
| URI | http://dx.doi.org/10.1021/acsami.7b17299 https://www.ncbi.nlm.nih.gov/pubmed/29439561 https://www.proquest.com/docview/2002218707 https://www.proquest.com/docview/2067294791 |
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