Self-Assembly Fabrication of Hollow Mesoporous Silica@Co–Al Layered Double Hydroxide@Graphene and Application in Toxic Effluents Elimination
Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and...
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Published in | ACS applied materials & interfaces Vol. 7; no. 16; pp. 8506 - 8514 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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United States
American Chemical Society
29.04.2015
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Abstract | Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co–Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co–Al LDH and graphene. Subsequently, the HM-SiO2@Co–Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co–Al LDH@graphene hybrids, implying a reduced toxicity. |
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AbstractList | Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity. Here, we propose a self-assembly process to prepare hierarchical HM-SiO₂@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO₂, Co–Al LDH, and graphene oxide, the HM-SiO₂ spheres were coated by Co–Al LDH and graphene. Subsequently, the HM-SiO₂@Co–Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO₂@Co–Al LDH@graphene hybrids, implying a reduced toxicity. Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity.Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity. |
Author | Zeng, Wen-Ru Huang, Zheng-Qi Stec, Anna A Song, Lei Hu, Wei-Zhao Hu, Yuan Jiang, Shu-Dong Hull, T. Richard Zhan, Jing |
AuthorAffiliation | University of Science and Technology of China Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study University of Central Lancashire State Key Laboratory of Fire Science Centre for Fire and Hazards Science |
AuthorAffiliation_xml | – name: University of Science and Technology of China – name: Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study – name: Centre for Fire and Hazards Science – name: State Key Laboratory of Fire Science – name: University of Central Lancashire |
Author_xml | – sequence: 1 givenname: Shu-Dong surname: Jiang fullname: Jiang, Shu-Dong – sequence: 2 givenname: Lei surname: Song fullname: Song, Lei – sequence: 3 givenname: Wen-Ru surname: Zeng fullname: Zeng, Wen-Ru – sequence: 4 givenname: Zheng-Qi surname: Huang fullname: Huang, Zheng-Qi – sequence: 5 givenname: Jing surname: Zhan fullname: Zhan, Jing – sequence: 6 givenname: Anna A surname: Stec fullname: Stec, Anna A – sequence: 7 givenname: T. Richard surname: Hull fullname: Hull, T. Richard – sequence: 8 givenname: Yuan surname: Hu fullname: Hu, Yuan email: yuanhu@ustc.edu.cn – sequence: 9 givenname: Wei-Zhao surname: Hu fullname: Hu, Wei-Zhao |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25853838$$D View this record in MEDLINE/PubMed |
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Snippet | Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance.... Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance.... Here, we propose a self-assembly process to prepare hierarchical HM-SiO₂@Co–Al LDH@graphene, with the purpose of combining their outstanding performance.... |
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SubjectTerms | chemical reduction coatings combustion effluents epoxides graphene graphene oxide porous media silica toxicity volatile organic compounds |
Title | Self-Assembly Fabrication of Hollow Mesoporous Silica@Co–Al Layered Double Hydroxide@Graphene and Application in Toxic Effluents Elimination |
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