Self-Assembly Fabrication of Hollow Mesoporous Silica@Co–Al Layered Double Hydroxide@Graphene and Application in Toxic Effluents Elimination

Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and...

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Published inACS applied materials & interfaces Vol. 7; no. 16; pp. 8506 - 8514
Main Authors Jiang, Shu-Dong, Song, Lei, Zeng, Wen-Ru, Huang, Zheng-Qi, Zhan, Jing, Stec, Anna A, Hull, T. Richard, Hu, Yuan, Hu, Wei-Zhao
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 29.04.2015
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Abstract Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co–Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co–Al LDH and graphene. Subsequently, the HM-SiO2@Co–Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co–Al LDH@graphene hybrids, implying a reduced toxicity.
AbstractList Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity.
Here, we propose a self-assembly process to prepare hierarchical HM-SiO₂@Co–Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO₂, Co–Al LDH, and graphene oxide, the HM-SiO₂ spheres were coated by Co–Al LDH and graphene. Subsequently, the HM-SiO₂@Co–Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO₂@Co–Al LDH@graphene hybrids, implying a reduced toxicity.
Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity.Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance. Hollow mesoporous silica was first synthesized as the core, using a novel sonochemical method, followed by a controlled shell coating process and chemical reduction. As a result of the electrostatic potential difference among HM-SiO2, Co-Al LDH, and graphene oxide, the HM-SiO2 spheres were coated by Co-Al LDH and graphene. Subsequently, the HM-SiO2@Co-Al LDH@graphene spheres were introduced into an epoxy resin (EP) matrix for investigation of their toxic effluents capture and elimination effectiveness during combustion. The amount of toxic CO and volatile organic compounds from the epoxy resin decomposition significantly suppressed after incorporating the HM-SiO2@Co-Al LDH@graphene hybrids, implying a reduced toxicity.
Author Zeng, Wen-Ru
Huang, Zheng-Qi
Stec, Anna A
Song, Lei
Hu, Wei-Zhao
Hu, Yuan
Jiang, Shu-Dong
Hull, T. Richard
Zhan, Jing
AuthorAffiliation University of Science and Technology of China
Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study
University of Central Lancashire
State Key Laboratory of Fire Science
Centre for Fire and Hazards Science
AuthorAffiliation_xml – name: University of Science and Technology of China
– name: Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study
– name: Centre for Fire and Hazards Science
– name: State Key Laboratory of Fire Science
– name: University of Central Lancashire
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fire effluents elimination
mechanism
HM-SiO2@Co−Al LDH@graphene
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Snippet Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co–Al LDH@graphene, with the purpose of combining their outstanding performance....
Here, we propose a self-assembly process to prepare hierarchical HM-SiO2@Co-Al LDH@graphene, with the purpose of combining their outstanding performance....
Here, we propose a self-assembly process to prepare hierarchical HM-SiO₂@Co–Al LDH@graphene, with the purpose of combining their outstanding performance....
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SubjectTerms chemical reduction
coatings
combustion
effluents
epoxides
graphene
graphene oxide
porous media
silica
toxicity
volatile organic compounds
Title Self-Assembly Fabrication of Hollow Mesoporous Silica@Co–Al Layered Double Hydroxide@Graphene and Application in Toxic Effluents Elimination
URI http://dx.doi.org/10.1021/acsami.5b00176
https://www.ncbi.nlm.nih.gov/pubmed/25853838
https://www.proquest.com/docview/1677379298
https://www.proquest.com/docview/2000286798
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