Unusual Activity of Rationally Designed Cobalt Phosphide/Oxide Heterostructure Composite for Hydrogen Production in Alkaline Medium
Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active cataly...
Saved in:
| Published in | ACS nano Vol. 16; no. 3; pp. 3906 - 3916 |
|---|---|
| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
22.03.2022
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-Co x O y /CC), with good activity and durability toward HER in alkaline medium (η10 = −43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption–desorption process of water electrolysis, leading to extremely high HER activity. |
|---|---|
| AbstractList | Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-Co
O
/CC), with good activity and durability toward HER in alkaline medium (η
= -43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption-desorption process of water electrolysis, leading to extremely high HER activity. Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-Co x O y /CC), with good activity and durability toward HER in alkaline medium (η 10 = −43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption–desorption process of water electrolysis, leading to extremely high HER activity. Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-Co x O y /CC), with good activity and durability toward HER in alkaline medium (η10 = −43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption–desorption process of water electrolysis, leading to extremely high HER activity. Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-CoxOy/CC), with good activity and durability toward HER in alkaline medium (η10 = -43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption-desorption process of water electrolysis, leading to extremely high HER activity.Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction (HER) in an alkaline medium remain a formidable challenge. At the root of the functional limitation is the inability to tune the active catalytic sites while overcoming the poor reaction kinetics observed under basic conditions. Herein, we report a facile approach to enable the selective design of an electrochemically efficient cobalt phosphide oxide composite catalyst on carbon cloth (CoP-CoxOy/CC), with good activity and durability toward HER in alkaline medium (η10 = -43 mV). Theoretical studies revealed that the redistribution of electrons at laterally dispersed Co phosphide/oxide interfaces gives rise to a synergistic effect in the heterostructured composite, by which various Co oxide phases initiate the dissociation of the alkaline water molecule. Meanwhile, the highly active CoP further facilitates the adsorption-desorption process of water electrolysis, leading to extremely high HER activity. |
| Author | Schwingenschlögl, Udo Eswaran, Mathan Kumar Wahyudi, Wandi Li, Lain-Jong Alsabban, Merfat M Peramaiah, Karthik Yang, Xiulin Huang, Kuo-Wei Ramalingam, Vinoth Miao, Xiaohe Hedhili, Mohamed. N Tung, Vincent |
| AuthorAffiliation | Department of Chemistry University of Jeddah Department of Mechanical Engineering KAUST Catalysis Center Core Laboratories Division of Physical Sciences and Engineering |
| AuthorAffiliation_xml | – name: KAUST Catalysis Center – name: Core Laboratories – name: Division of Physical Sciences and Engineering – name: Department of Chemistry – name: Department of Mechanical Engineering – name: University of Jeddah |
| Author_xml | – sequence: 1 givenname: Merfat M surname: Alsabban fullname: Alsabban, Merfat M organization: University of Jeddah – sequence: 2 givenname: Mathan Kumar surname: Eswaran fullname: Eswaran, Mathan Kumar organization: Division of Physical Sciences and Engineering – sequence: 3 givenname: Karthik surname: Peramaiah fullname: Peramaiah, Karthik organization: KAUST Catalysis Center – sequence: 4 givenname: Wandi orcidid: 0000-0002-6224-2414 surname: Wahyudi fullname: Wahyudi, Wandi organization: Division of Physical Sciences and Engineering – sequence: 5 givenname: Xiulin orcidid: 0000-0003-2642-4963 surname: Yang fullname: Yang, Xiulin organization: KAUST Catalysis Center – sequence: 6 givenname: Vinoth surname: Ramalingam fullname: Ramalingam, Vinoth organization: KAUST Catalysis Center – sequence: 7 givenname: Mohamed. N surname: Hedhili fullname: Hedhili, Mohamed. N organization: Core Laboratories – sequence: 8 givenname: Xiaohe surname: Miao fullname: Miao, Xiaohe organization: Core Laboratories – sequence: 9 givenname: Udo orcidid: 0000-0003-4179-7231 surname: Schwingenschlögl fullname: Schwingenschlögl, Udo organization: Division of Physical Sciences and Engineering – sequence: 10 givenname: Lain-Jong orcidid: 0000-0002-4059-7783 surname: Li fullname: Li, Lain-Jong email: lanceli1@hku.hk organization: Department of Mechanical Engineering – sequence: 11 givenname: Vincent surname: Tung fullname: Tung, Vincent email: vincent.tung@kaust.edu.sa organization: KAUST Catalysis Center – sequence: 12 givenname: Kuo-Wei orcidid: 0000-0003-1900-2658 surname: Huang fullname: Huang, Kuo-Wei email: hkw@kaust.edu.sa organization: KAUST Catalysis Center |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35253442$$D View this record in MEDLINE/PubMed |
| BookMark | eNp9kcuPUyEUxokZ4zx07c6wNDGdwuVx792YNPVRkzEzMU7ijlA4bRm5UIE7sWv_cdHWRk10A4Tz-74D5ztHJyEGQOgpJZeUNHSqTQ46xEtqSN8I_gCd0Z7JCenkp5PjWdBTdJ7zHSGi7Vr5CJ0y0QjGeXOGvt2GMY_a45kp7t6VHY4r_EEXF4P2fodfQXbrABbP41L7gm82MW83zsL0-mtd8QIKpJhLGk0ZE1Rs2MbsCuBVTHixsymuIeCbFG0lqit2Ac_8Z-1dAPwerBuHx-jhSvsMTw77Bbp98_rjfDG5un77bj67mmje9GUiNLO8J1SztpGEWsPb-gsNRIDs5VLyegWWddpS2jHGVkB1C1xranpDhWUX6OXedzsuB6hwKEl7tU1u0Gmnonbqz0pwG7WO96rruZB9Ww2eHwxS_DJCLmpw2YD3OkAcs2okk13LJe8r-uz3XscmvyZfgekeMHV8OcHqiFCifmSrDtmqQ7ZVIf5SGFd-JlUf6_x_dC_2ulpQd3FMNdn8T_o7BmS9JQ |
| CitedBy_id | crossref_primary_10_1016_j_cej_2023_146710 crossref_primary_10_2139_ssrn_4088101 crossref_primary_10_3390_en17071591 crossref_primary_10_1016_j_ijhydene_2025_02_189 crossref_primary_10_1021_acs_inorgchem_3c00876 crossref_primary_10_1016_j_jcis_2025_02_196 crossref_primary_10_1016_j_jallcom_2022_165733 crossref_primary_10_3390_en16031124 crossref_primary_10_1016_j_electacta_2023_142436 crossref_primary_10_1002_cnma_202400066 crossref_primary_10_1002_inf2_12377 crossref_primary_10_1039_D3QI01587D crossref_primary_10_1016_j_apcatb_2024_124444 crossref_primary_10_1039_D4GC00393D crossref_primary_10_1016_j_ensm_2024_103288 crossref_primary_10_1016_j_ijhydene_2024_05_204 crossref_primary_10_1016_j_jcis_2023_11_044 crossref_primary_10_1002_aenm_202303924 crossref_primary_10_1016_j_mcat_2022_112640 crossref_primary_10_1088_1361_6528_acddec crossref_primary_10_1039_D3CC01593A crossref_primary_10_1016_j_ijhydene_2024_11_150 crossref_primary_10_3390_catal13060941 crossref_primary_10_1016_j_jechem_2022_06_047 crossref_primary_10_1039_D2TA04963E crossref_primary_10_1039_D3SE01486J crossref_primary_10_1007_s13369_025_10016_0 crossref_primary_10_1016_j_cej_2022_138628 crossref_primary_10_1016_j_cej_2022_138225 crossref_primary_10_1021_acscatal_2c04936 crossref_primary_10_3390_catal13111426 crossref_primary_10_1002_aenm_202301475 crossref_primary_10_1016_j_ijhydene_2024_03_129 crossref_primary_10_1002_aenm_202303614 crossref_primary_10_1002_smll_202500334 crossref_primary_10_1039_D3DT03088A crossref_primary_10_2139_ssrn_4130782 crossref_primary_10_1021_acsomega_2c04499 crossref_primary_10_1016_j_ijhydene_2023_03_085 crossref_primary_10_1021_acs_energyfuels_4c01477 crossref_primary_10_1002_smll_202302866 crossref_primary_10_1002_smll_202300402 crossref_primary_10_1016_j_jcis_2022_09_126 crossref_primary_10_1016_j_jallcom_2023_170832 crossref_primary_10_1016_j_est_2024_115240 crossref_primary_10_1016_j_jelechem_2023_117216 crossref_primary_10_1007_s12274_024_6433_8 crossref_primary_10_1016_j_apcatb_2022_122324 crossref_primary_10_1016_j_jcrysgro_2023_127430 crossref_primary_10_1002_aenm_202301841 crossref_primary_10_1016_j_jechem_2023_04_014 crossref_primary_10_1016_j_jcis_2022_11_120 crossref_primary_10_1039_D2NR05410H crossref_primary_10_1016_j_electacta_2023_143679 crossref_primary_10_1039_D4DT01713G crossref_primary_10_1016_j_cej_2024_151693 crossref_primary_10_3390_catal14100671 crossref_primary_10_1016_j_matlet_2022_133448 crossref_primary_10_1016_j_ijhydene_2024_01_352 crossref_primary_10_1007_s12274_023_6219_4 crossref_primary_10_1016_j_cej_2023_147092 crossref_primary_10_1002_aenm_202401426 crossref_primary_10_1039_D3SE01379K crossref_primary_10_1016_j_mtchem_2023_101844 crossref_primary_10_1007_s12598_024_02649_1 |
| Cites_doi | 10.1039/c4cp00482e 10.1016/j.ijhydene.2006.08.043 10.1016/j.nanoen.2018.11.047 10.1039/C5TA09125J 10.1038/nmat3385 10.1002/adma.201605502 10.1021/acsomega.9b04143 10.1039/C6CC04141H 10.1021/acscatal.5b02076 10.1039/C8EE01270A 10.3390/catal7040119 10.1021/acsenergylett.8b00514 10.1149/2.0141611jss 10.1039/C5NR02375K 10.1002/adma.201703863 10.1021/acs.chemrev.9b00248 10.1002/anie.201606290 10.1002/advs.201700464 10.1021/acsenergylett.8b00330 10.1016/j.xcrp.2020.100136 10.1039/C8SC04589E 10.1021/acsnano.8b01296 10.1007/BF02841716 10.1039/C6TA00575F 10.1021/acsami.5b04132 10.1021/acs.chemmater.5b01284 10.1038/nature11475 10.1002/anie.201913910 10.1016/j.apsusc.2010.10.051 10.1021/acsami.9b01847 10.1016/j.nanoen.2015.05.026 10.1002/adfm.201503666 10.1039/f19858101841 10.1039/C9EE01202H 10.1038/ncomms4783 10.1038/s41929-018-0195-1 10.1016/j.ijhydene.2020.04.121 |
| ContentType | Journal Article |
| Copyright | 2022 The Authors. Published by American Chemical Society 2022 The Authors. Published by American Chemical Society 2022 The Authors |
| Copyright_xml | – notice: 2022 The Authors. Published by American Chemical Society – notice: 2022 The Authors. Published by American Chemical Society 2022 The Authors |
| DBID | AAYXX CITATION NPM 7X8 5PM |
| DOI | 10.1021/acsnano.1c09254 |
| DatabaseName | CrossRef PubMed MEDLINE - Academic PubMed Central (Full Participant titles) |
| DatabaseTitle | CrossRef PubMed MEDLINE - Academic |
| DatabaseTitleList | PubMed MEDLINE - Academic |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1936-086X |
| EndPage | 3916 |
| ExternalDocumentID | PMC8945697 35253442 10_1021_acsnano_1c09254 a554067447 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: ; grantid: OSR-2018-CARF/CCF-3079 |
| GroupedDBID | - 23M 4.4 55A 5GY 5VS 7~N AABXI ABFRP ABMVS ABUCX ACGFS ACS AEESW AENEX AFEFF AHGAQ ALMA_UNASSIGNED_HOLDINGS AQSVZ CS3 EBS ED F5P GGK GNL IH9 IHE JG K2 P2P RNS ROL UI2 VF5 VG9 W1F XKZ YZZ --- .K2 6J9 AAHBH AAYXX ABBLG ABJNI ABLBI ABQRX ACBEA ACGFO ADHGD ADHLV BAANH CITATION CUPRZ ED~ JG~ NPM 7X8 5PM |
| ID | FETCH-LOGICAL-a429t-5a3d4901a372601dc47253ae05e696b641dced38ad118333fe1a7e4aa1c9c15d3 |
| IEDL.DBID | ACS |
| ISSN | 1936-0851 1936-086X |
| IngestDate | Thu Aug 21 18:17:25 EDT 2025 Fri Jul 11 11:24:48 EDT 2025 Thu Jan 02 22:55:04 EST 2025 Tue Jul 01 03:37:24 EDT 2025 Thu Apr 24 23:01:46 EDT 2025 Thu Mar 24 03:15:54 EDT 2022 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 3 |
| Keywords | electrochemical catalyst cobalt phosphide hydrogen evolution reaction (HER) cobalt mixed oxides phosphatization |
| Language | English |
| License | https://creativecommons.org/licenses/by/4.0 Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a429t-5a3d4901a372601dc47253ae05e696b641dced38ad118333fe1a7e4aa1c9c15d3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0003-4179-7231 0000-0002-6224-2414 0000-0003-1900-2658 0000-0003-2642-4963 0000-0002-4059-7783 |
| OpenAccessLink | https://pubmed.ncbi.nlm.nih.gov/PMC8945697 |
| PMID | 35253442 |
| PQID | 2636874649 |
| PQPubID | 23479 |
| PageCount | 11 |
| ParticipantIDs | pubmedcentral_primary_oai_pubmedcentral_nih_gov_8945697 proquest_miscellaneous_2636874649 pubmed_primary_35253442 crossref_primary_10_1021_acsnano_1c09254 crossref_citationtrail_10_1021_acsnano_1c09254 acs_journals_10_1021_acsnano_1c09254 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2022-03-22 |
| PublicationDateYYYYMMDD | 2022-03-22 |
| PublicationDate_xml | – month: 03 year: 2022 text: 2022-03-22 day: 22 |
| PublicationDecade | 2020 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | ACS nano |
| PublicationTitleAlternate | ACS Nano |
| PublicationYear | 2022 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref9/cit9 ref6/cit6 ref36/cit36 ref3/cit3 ref27/cit27 ref18/cit18 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 ref32/cit32 ref23/cit23 ref14/cit14 ref8/cit8 ref5/cit5 ref31/cit31 ref2/cit2 ref34/cit34 ref37/cit37 ref28/cit28 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref35/cit35 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref22/cit22 ref13/cit13 ref33/cit33 ref4/cit4 ref30/cit30 ref1/cit1 ref24/cit24 ref7/cit7 |
| References_xml | – ident: ref18/cit18 doi: 10.1039/c4cp00482e – ident: ref35/cit35 doi: 10.1016/j.ijhydene.2006.08.043 – ident: ref33/cit33 doi: 10.1016/j.nanoen.2018.11.047 – ident: ref36/cit36 doi: 10.1039/C5TA09125J – ident: ref30/cit30 doi: 10.1038/nmat3385 – ident: ref20/cit20 doi: 10.1002/adma.201605502 – ident: ref22/cit22 doi: 10.1021/acsomega.9b04143 – ident: ref15/cit15 doi: 10.1039/C6CC04141H – ident: ref31/cit31 doi: 10.1021/acscatal.5b02076 – ident: ref14/cit14 doi: 10.1039/C8EE01270A – ident: ref29/cit29 doi: 10.3390/catal7040119 – ident: ref13/cit13 doi: 10.1021/acsenergylett.8b00514 – ident: ref25/cit25 doi: 10.1149/2.0141611jss – ident: ref16/cit16 doi: 10.1039/C5NR02375K – ident: ref19/cit19 doi: 10.1002/adma.201703863 – ident: ref6/cit6 doi: 10.1021/acs.chemrev.9b00248 – ident: ref8/cit8 doi: 10.1002/anie.201606290 – ident: ref4/cit4 doi: 10.1002/advs.201700464 – ident: ref9/cit9 doi: 10.1021/acsenergylett.8b00330 – ident: ref5/cit5 doi: 10.1016/j.xcrp.2020.100136 – ident: ref21/cit21 doi: 10.1039/C8SC04589E – ident: ref37/cit37 doi: 10.1021/acsnano.8b01296 – ident: ref24/cit24 doi: 10.1007/BF02841716 – ident: ref11/cit11 doi: 10.1039/C6TA00575F – ident: ref28/cit28 doi: 10.1021/acsami.5b04132 – ident: ref27/cit27 doi: 10.1021/acs.chemmater.5b01284 – ident: ref1/cit1 doi: 10.1038/nature11475 – ident: ref2/cit2 doi: 10.1002/anie.201913910 – ident: ref26/cit26 doi: 10.1016/j.apsusc.2010.10.051 – ident: ref12/cit12 doi: 10.1021/acsami.9b01847 – ident: ref17/cit17 doi: 10.1016/j.nanoen.2015.05.026 – ident: ref23/cit23 doi: 10.1002/adfm.201503666 – ident: ref34/cit34 doi: 10.1039/f19858101841 – ident: ref3/cit3 doi: 10.1039/C9EE01202H – ident: ref10/cit10 doi: 10.1038/ncomms4783 – ident: ref7/cit7 doi: 10.1038/s41929-018-0195-1 – ident: ref32/cit32 doi: 10.1016/j.ijhydene.2020.04.121 |
| SSID | ssj0057876 |
| Score | 2.6185334 |
| Snippet | Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction... Design and development of an efficient, nonprecious catalyst with structural features and functionality necessary for driving the hydrogen evolution reaction... |
| SourceID | pubmedcentral proquest pubmed crossref acs |
| SourceType | Open Access Repository Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 3906 |
| Title | Unusual Activity of Rationally Designed Cobalt Phosphide/Oxide Heterostructure Composite for Hydrogen Production in Alkaline Medium |
| URI | http://dx.doi.org/10.1021/acsnano.1c09254 https://www.ncbi.nlm.nih.gov/pubmed/35253442 https://www.proquest.com/docview/2636874649 https://pubmed.ncbi.nlm.nih.gov/PMC8945697 |
| Volume | 16 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3Nb9MwFLdgXOAwvlmBISNx4JIu_ojjHKuyqUICJqDSbpG_qlYrzrQ0EuPKP857SVrWVRNcckhsS7Z_9vu9vOefCXlnUu05-MmJF84mknObFJq5xKciOBN04TmeRv70WU2m8uNZdvZXLPpmBJ-zI-PqaGI1ZC4twJu5S-5xpXP0s0bjb-tNF3GnugAyOMjAIjYqPjsNoBly9bYZ2uGWN1Mkr9mck4ddtlbdShViqsn5sFnZofu1K-T47-48Ivs986SjDiqPyZ0Qn5AH1_QIn5Lf09jUDRZy3aUStJrRr_3vwuUV_dCmewRPx6gisqKn86q-mC98OPryE550grk1VSdJ21wGipsNJoUFCtSYTq78ZQV4paedyiy0SheRjpbnBrkuxZhR8-MZmZ4cfx9Pkv6WhsSALVslmRFeAqswIkd5Mu9kzjNhQpoFVSirJLwKXmjjwZcRQswCM3mQxjBXOJZ58ZzsxSqGA0Kdd5rPuGZGaemFtTOV2lwLo4ssWMsGgC1Xl_0qq8s2gM5Z2Y9p2Y_pgAzXc1u6XukcL9xY3l7h_abCRSfycXvRt2uwlLAQMbpiYqiauuRKAC6lksWAvOjAs2kMNWeFlHxA8i1YbQqgyPf2l7iYt2LfugCKW-Qv_6_rr8h9juczUpFw_prswYSHQ2BNK_umXS9_AHvYF8k |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV1Lb9QwELZKOQCHljdLeRgJJC7ZJrbjOAcOqy1VSh9U0JV6S_1a7arbpGo2guXaP9K_wj9jnGRDt1UlLpW45ODYI8fz8Exm_Bmh99IXhkCc7BmqlccIUV4sAu0Zn1otrYgNcaeRd_d4MmBfDsPDJXQxPwsDkyiAUlEl8f-iCwTr0JbJLO8G2o8hqGnKKLft7AcEacWnrQ3g6AdCNj8f9BOvuUfAk2Btp14oqWGw70kaOQAto1lEQiqtH1oec8UZNFlDhTTgbVNKhzaQkWVSBjrWQWgo0L2D7oLrQ1x41-t_n9t6J-68zltDXA7OSwsedG3CbvfTxeLud82lvVqZeWmr21xFv9tFqipcjrvlVHX1ryv4kf_zKj5EK42fjXu1YjxCSzZ7jB5cQl98gs4HWVmUrpOur9DA-RB_a36OTmZ4oypusQb3HWbKFO-P8uJ0NDZ2_etPeOLEVRLlNQBveWaxM62uBM5iCARwMjNnOWgn3q8xdYEqHme4NzmWzrPHLkNWnjxFg1tZhWdoOcsz-wJhbbQgQyICyQUzVKkh91UkqBRxaJUKOqBJukgbm1KkVbkACdKGh2nDww7qzkUq1Q2uu7teZHLzgI_tgNMa0uTmru_mMpqC2XG5JJnZvCxSwikXEeMs7qDntcy2xBzCLmWMdFC0IM1tBwdpvvgmG48qaHMRg0MfRy__7dPfonvJwe5OurO1t72G7hN3MsWnHiGv0DIw374Gf3Gq3lQqi9HRbUv3H92Bebo |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV3Nb9MwFLfGkBAcxjeUTyOBxCVdYjuOc-BQtVQdg1EBlXbL_BW1WpdUSyMoV_4V_hX-L56TNFo3TeIyiUsOjv3k-H34vbznnxF6LX1hCMTJnqFaeYwQ5cUi0J7xqdXSitgQdxr50wEfTdiHw_BwC_1en4WBSRRAqaiS-E6rFyZtEAaCXWjPZJZ3A-3HENg0pZT7dvUdArXi3d4AuPqGkOH7b_2R19wl4EmwuEsvlNQw2PskjRyIltEsIiGV1g8tj7niDJqsoUIa8LgppakNZGSZlIGOdRAaCnSvoesuSehCvF7_69reO5Hnde4aYnNwYFoAoQsTdjugLjZ3wAtu7fnqzDPb3fA2-tMuVFXlctwtl6qrf57DkPzfV_IO2mn8bdyrFeQu2rLZPXTrDArjffRrkpVF6Trp-ioNnKf4S_OTdL7Cg6rIxRrcd9gpSzye5sViOjN29_MPeOKRqyjKayDe8tRiZ2JdKZzFEBDg0cqc5qCleFxj6wJVPMtwb34snYePXaasPHmAJleyCg_RdpZn9jHC2mhBUiICyQUzVKmU-yoSVIo4tEoFHdAoXSSNbSmSqmyABEnDw6ThYQd112KV6Abf3V0zMr98wNt2wKKGNrm866u1nCZgflxOSWY2L4uEcMpFxDiLO-hRLbctMYe0SxkjHRRtSHTbwUGbb77JZtMK4lzE4NjH0ZN_-_SX6MZ4MEw-7h3sP0U3iTug4lOPkGdoG3hvn4PbuFQvKq3F6OiqhfsvDvt8PQ |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Unusual+Activity+of+Rationally+Designed+Cobalt+Phosphide%2FOxide+Heterostructure+Composite+for+Hydrogen+Production+in+Alkaline+Medium&rft.jtitle=ACS+nano&rft.au=Alsabban%2C+Merfat+M.&rft.au=Eswaran%2C+Mathan+Kumar&rft.au=Peramaiah%2C+Karthik&rft.au=Wahyudi%2C+Wandi&rft.date=2022-03-22&rft.issn=1936-0851&rft.eissn=1936-086X&rft.volume=16&rft.issue=3&rft.spage=3906&rft.epage=3916&rft_id=info:doi/10.1021%2Facsnano.1c09254&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_acsnano_1c09254 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1936-0851&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1936-0851&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1936-0851&client=summon |