Polymerization-Induced Self-Assembly (PISA) Using ICAR ATRP at Low Catalyst Concentration
Polymerization-induced self-assembly (PISA) was achieved by conducting an initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) at low ppm of copper catalyst concentration. A poly(oligo(ethylene oxide) methyl ether methacrylate)50 (POEOMA50) macroinitiat...
Saved in:
| Published in | Macromolecules Vol. 49; no. 22; pp. 8605 - 8615 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
22.11.2016
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Polymerization-induced self-assembly (PISA) was achieved by conducting an initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) at low ppm of copper catalyst concentration. A poly(oligo(ethylene oxide) methyl ether methacrylate)50 (POEOMA50) macroinitiator and stabilizer was synthesized by an aqueous ICAR ATRP using CuIICl2/tris(pyridin-2-ylmethyl)amine (TPMA) complex. Subsequently, the dispersion polymerization of benzyl methacrylate (BnMA) in ethanol was realized with a CuIIBr2/TPMA complex either at room temperature or at 65 °C using V-70 or AIBN as radical initiators, respectively. The effect of catalyst concentration, radical initiators, targeted degree of polymerization (DP) of PBnMA, solids content, and temperature on the molecular characteristics and self-assembly behavior of block copolymers POEOMA–PBnMA was evaluated by gel permeation chromatography (GPC), transmission electron microscopy (TEM), and dynamic light scattering (DLS). Block copolymers assembled into spheres, wormlike aggregates, and vesicles with diameters ranging from 100 to 600 nm, depending on the temperature, solids content, and the DP of PBnMA. The effect of the temperature on the polymerization behavior and morphological evolution was attributed to the temperature-dependent plasticization of the core-forming PBnMA block above and below its glass transition temperature (T g = 54 °C). |
|---|---|
| AbstractList | Polymerization-induced self-assembly (PISA) was achieved by conducting an initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) at low ppm of copper catalyst concentration. A poly(oligo(ethylene oxide) methyl ether methacrylate)₅₀ (POEOMA₅₀) macroinitiator and stabilizer was synthesized by an aqueous ICAR ATRP using CuᴵᴵCl₂/tris(pyridin-2-ylmethyl)amine (TPMA) complex. Subsequently, the dispersion polymerization of benzyl methacrylate (BnMA) in ethanol was realized with a CuᴵᴵBr₂/TPMA complex either at room temperature or at 65 °C using V-70 or AIBN as radical initiators, respectively. The effect of catalyst concentration, radical initiators, targeted degree of polymerization (DP) of PBnMA, solids content, and temperature on the molecular characteristics and self-assembly behavior of block copolymers POEOMA–PBnMA was evaluated by gel permeation chromatography (GPC), transmission electron microscopy (TEM), and dynamic light scattering (DLS). Block copolymers assembled into spheres, wormlike aggregates, and vesicles with diameters ranging from 100 to 600 nm, depending on the temperature, solids content, and the DP of PBnMA. The effect of the temperature on the polymerization behavior and morphological evolution was attributed to the temperature-dependent plasticization of the core-forming PBnMA block above and below its glass transition temperature (Tg = 54 °C). Polymerization-induced self-assembly (PISA) was achieved by conducting an initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) at low ppm of copper catalyst concentration. A poly(oligo(ethylene oxide) methyl ether methacrylate)50 (POEOMA50) macroinitiator and stabilizer was synthesized by an aqueous ICAR ATRP using CuIICl2/tris(pyridin-2-ylmethyl)amine (TPMA) complex. Subsequently, the dispersion polymerization of benzyl methacrylate (BnMA) in ethanol was realized with a CuIIBr2/TPMA complex either at room temperature or at 65 °C using V-70 or AIBN as radical initiators, respectively. The effect of catalyst concentration, radical initiators, targeted degree of polymerization (DP) of PBnMA, solids content, and temperature on the molecular characteristics and self-assembly behavior of block copolymers POEOMA–PBnMA was evaluated by gel permeation chromatography (GPC), transmission electron microscopy (TEM), and dynamic light scattering (DLS). Block copolymers assembled into spheres, wormlike aggregates, and vesicles with diameters ranging from 100 to 600 nm, depending on the temperature, solids content, and the DP of PBnMA. The effect of the temperature on the polymerization behavior and morphological evolution was attributed to the temperature-dependent plasticization of the core-forming PBnMA block above and below its glass transition temperature (T g = 54 °C). |
| Author | Matyjaszewski, Krzysztof Li, Sipei Wang, Guowei Schmitt, Michael Fu, Liye Wang, Zongyu Pan, Xiangcheng Lee, Bongjoon Xie, Guojun Bockstaller, Michael R Yan, Jiajun |
| AuthorAffiliation | Department of Chemistry Carnegie Mellon University Fudan University Department of Materials Science & Engineering State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science |
| AuthorAffiliation_xml | – name: Carnegie Mellon University – name: Fudan University – name: Department of Chemistry – name: State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science – name: Department of Materials Science & Engineering |
| Author_xml | – sequence: 1 givenname: Guowei surname: Wang fullname: Wang, Guowei – sequence: 2 givenname: Michael surname: Schmitt fullname: Schmitt, Michael – sequence: 3 givenname: Zongyu surname: Wang fullname: Wang, Zongyu – sequence: 4 givenname: Bongjoon surname: Lee fullname: Lee, Bongjoon – sequence: 5 givenname: Xiangcheng surname: Pan fullname: Pan, Xiangcheng – sequence: 6 givenname: Liye surname: Fu fullname: Fu, Liye – sequence: 7 givenname: Jiajun surname: Yan fullname: Yan, Jiajun – sequence: 8 givenname: Sipei surname: Li fullname: Li, Sipei – sequence: 9 givenname: Guojun surname: Xie fullname: Xie, Guojun – sequence: 10 givenname: Michael R surname: Bockstaller fullname: Bockstaller, Michael R email: bockstaller@cmu.edu – sequence: 11 givenname: Krzysztof surname: Matyjaszewski fullname: Matyjaszewski, Krzysztof email: km3b@andrew.cmu.edu |
| BookMark | eNqFkDtPwzAUhS1UJNrCP2DwWIaUazvOgy2KeFSqRNXHwBQ5joNSOXaJU6Hw60kfLAww3eGe70jnG6GBsUYhdEtgSoCSeyHdtBaysbXV0yAHEgfBBRoSTsHjEeMDNASgvhfTOLxCI-e2AIRwnw3R28LqrlZN9SXayhpvZoq9VAVeKV16iXOqznWHJ4vZKrnDG1eZdzxLkyVO1ssFFi2e20-cilbozrU4tUYq0zbHqmt0WQrt1M35jtHm6XGdvnjz1-e-Yu4Jn0atxwqSQxxENFJhXgDhjEngStJQAaV5xFRIYgkFIYxEoV8ozgIfCpbzmPplxNgYTU69u8Z-7JVrs7pyUmktjLJ7l1GIfAhjzqGP-qdor8q5RpXZrqlq0XQZgexgMutNZj8ms7PJHnv4hcmqPW7sp1b6PxhO8OG7tfvG9DL-Rr4Be02PDg |
| CitedBy_id | crossref_primary_10_1039_D4PY00073K crossref_primary_10_1039_D0PY00627K crossref_primary_10_1002_adma_201706441 crossref_primary_10_1002_marc_201800332 crossref_primary_10_1021_acs_macromol_8b02491 crossref_primary_10_1039_D4PY00263F crossref_primary_10_1002_advs_201700137 crossref_primary_10_1016_j_polymer_2019_121852 crossref_primary_10_1002_marc_201800331 crossref_primary_10_1021_acs_iecr_7b03065 crossref_primary_10_1002_marc_201800327 crossref_primary_10_1038_s41467_019_09324_5 crossref_primary_10_1021_acsmacrolett_7b00069 crossref_primary_10_34133_research_0113 crossref_primary_10_1039_D1PY01108A crossref_primary_10_1039_C8CS00259B crossref_primary_10_1002_marc_202000209 crossref_primary_10_1039_C8PY01117F crossref_primary_10_1039_C9PY01462D crossref_primary_10_1016_j_cej_2020_127663 crossref_primary_10_1002_pi_6562 crossref_primary_10_1039_D3PY01318A crossref_primary_10_1039_D2PY01086K crossref_primary_10_1021_acs_macromol_8b02081 crossref_primary_10_1002_marc_201800346 crossref_primary_10_1039_D0PY01498B crossref_primary_10_1039_D2PY00935H crossref_primary_10_1021_acs_macromol_1c01528 crossref_primary_10_1039_C8PY00775F crossref_primary_10_1016_j_biomaterials_2018_10_044 crossref_primary_10_1016_j_fuel_2024_134164 crossref_primary_10_1002_slct_202402040 crossref_primary_10_1021_acs_chemmater_1c04151 crossref_primary_10_1021_acsmaterialslett_1c00145 crossref_primary_10_3390_ma13071717 crossref_primary_10_1016_j_jelechem_2023_117804 crossref_primary_10_1039_D4PY01008F crossref_primary_10_1021_acs_macromol_8b00690 crossref_primary_10_1021_acsmacrolett_8b00815 crossref_primary_10_1021_acs_macromol_6b02651 crossref_primary_10_1002_marc_201800279 crossref_primary_10_1039_D1PY00239B crossref_primary_10_1016_j_polymer_2024_127474 crossref_primary_10_1021_acs_macromol_0c00371 crossref_primary_10_1039_D1PY01178B crossref_primary_10_1016_j_progpolymsci_2019_101180 crossref_primary_10_1039_C9PY00166B crossref_primary_10_3390_polym12112599 crossref_primary_10_1021_acsmacrolett_9b00464 crossref_primary_10_1021_acs_macromol_2c00475 crossref_primary_10_1039_D2PY01148D crossref_primary_10_1021_acs_macromol_7b01644 crossref_primary_10_1021_acsmacrolett_8b00378 crossref_primary_10_1016_j_eurpolymj_2024_113666 crossref_primary_10_1002_marc_202100566 crossref_primary_10_1021_acs_jcim_3c00460 crossref_primary_10_1002_pol_20190256 crossref_primary_10_1002_ange_202308372 crossref_primary_10_1016_j_progpolymsci_2018_05_003 crossref_primary_10_1016_j_polymer_2017_09_029 crossref_primary_10_1016_j_giant_2022_100114 crossref_primary_10_1021_acsmacrolett_9b00117 crossref_primary_10_1021_acsmacrolett_7b00099 crossref_primary_10_1039_C9NJ05638F crossref_primary_10_1021_acsmacrolett_9b00870 crossref_primary_10_1016_j_carbpol_2020_116224 crossref_primary_10_1021_acs_macromol_1c02431 crossref_primary_10_1016_j_polymer_2023_125913 crossref_primary_10_1002_marc_202100498 crossref_primary_10_1002_agt2_418 crossref_primary_10_1002_anie_201911758 crossref_primary_10_1016_j_polymer_2024_126686 crossref_primary_10_1039_C7PY00442G crossref_primary_10_1246_cl_200957 crossref_primary_10_1039_C9PY01144G crossref_primary_10_1021_acsmacrolett_9b00606 crossref_primary_10_1039_D0PY01425G crossref_primary_10_1021_acs_biomac_4c00552 crossref_primary_10_3390_polym16101408 crossref_primary_10_1002_pol_20220614 crossref_primary_10_1021_acs_biomac_8b01326 crossref_primary_10_1007_s10118_021_2616_x crossref_primary_10_1002_marc_201900547 crossref_primary_10_1021_acsami_9b22386 crossref_primary_10_1016_j_jconrel_2021_11_010 crossref_primary_10_1021_acs_macromol_4c01334 crossref_primary_10_1016_j_polymer_2023_125804 crossref_primary_10_1021_acs_macromol_7b01440 crossref_primary_10_1002_marc_201800140 crossref_primary_10_1016_j_eurpolymj_2021_110631 crossref_primary_10_1016_j_eurpolymj_2025_113906 crossref_primary_10_3390_polym12020330 crossref_primary_10_1016_j_progpolymsci_2020_101209 crossref_primary_10_1039_C9PY00498J crossref_primary_10_1021_acs_macromol_3c00406 crossref_primary_10_1016_j_cis_2018_08_002 crossref_primary_10_1002_anie_202308372 crossref_primary_10_1039_D0PY00296H crossref_primary_10_1021_acs_macromol_9b01695 crossref_primary_10_1088_1742_6596_2229_1_012010 crossref_primary_10_1021_acs_macromol_0c02106 crossref_primary_10_1039_C9CC04445K crossref_primary_10_1039_D0PY01713B crossref_primary_10_1039_C8PY01799A crossref_primary_10_1021_acs_macromol_9b02008 crossref_primary_10_1039_D2PY00180B crossref_primary_10_1002_anbr_202100087 crossref_primary_10_1139_cjc_2016_0591 crossref_primary_10_1002_ijch_201900039 crossref_primary_10_1016_j_eurpolymj_2022_111234 crossref_primary_10_1039_C9SC03056E crossref_primary_10_1007_s10965_022_02979_7 crossref_primary_10_1039_D0PY00455C crossref_primary_10_1002_marc_201800510 crossref_primary_10_3390_polym14235331 crossref_primary_10_1016_j_pmatsci_2024_101248 crossref_primary_10_1039_D3PY01361H crossref_primary_10_1039_C8PY00649K crossref_primary_10_1002_ange_201911758 crossref_primary_10_1039_D1QM00307K crossref_primary_10_1021_acs_macromol_0c00616 crossref_primary_10_1021_acs_macromol_8b00246 crossref_primary_10_1039_C7RA09154K crossref_primary_10_1016_j_apsusc_2022_156288 crossref_primary_10_1039_C7PY01618B crossref_primary_10_1002_pola_29439 crossref_primary_10_1016_j_rinma_2022_100313 crossref_primary_10_1002_marc_202100921 crossref_primary_10_1002_marc_201900296 crossref_primary_10_1002_slct_202004194 crossref_primary_10_1016_j_progpolymsci_2017_07_005 crossref_primary_10_1021_acs_macromol_1c02636 crossref_primary_10_1039_D2PY00937D crossref_primary_10_1016_j_polymer_2022_125160 crossref_primary_10_1002_smll_201802734 crossref_primary_10_1063_5_0083099 crossref_primary_10_1021_acs_macromol_8b00994 |
| Cites_doi | 10.1021/jacs.5b11599 10.1039/c2sm27602j 10.1039/b805764h 10.1021/ma5019473 10.1016/j.jorganchem.2007.01.051 10.1007/s00396-014-3216-x 10.1021/la100840a 10.1021/ma300816m 10.1038/nchem.257 10.1021/acs.macromol.5b02602 10.1021/ja407033x 10.1021/ja0429364 10.1021/ma047389l 10.1021/ma300713f 10.1126/science.1202357 10.1021/ja00060a017 10.1021/ja502843f 10.1039/C1SM06035J 10.1016/j.physb.2006.06.049 10.1039/C2PY20612A 10.1021/ma101136v 10.1039/c1sm05771e 10.1016/j.progpolymsci.2010.05.001 10.1016/j.progpolymsci.2015.10.002 10.1021/ja305150c 10.1021/ma011651y 10.1021/acs.macromol.5b00021 10.1002/poc.610080414 10.1002/poc.610080403 10.1021/acs.macromol.5b02789 10.1007/s00396-013-3154-z 10.1021/mz200020c 10.1021/ja303841f 10.1021/ma201865s 10.1021/mz500195u 10.1021/acsmacrolett.6b00235 10.1039/b515267d 10.1021/mz200035b 10.1021/ja3024059 10.1021/ja501756h 10.1021/cr050947p 10.1002/marc.200800713 10.1039/c2sm25537e 10.1021/ja100685s 10.1021/ma010864k 10.2478/s11532-009-0092-1 10.1021/acsmacrolett.5b00523 10.1021/ma5002386 10.1016/j.jcis.2014.11.058 10.1002/anie.201105317 10.1002/marc.200700230 10.1002/marc.201500122 10.1021/ma4022983 10.1002/anie.201410598 10.1021/ma800892e 10.1021/ma4003159 10.1002/anie.201308686 10.1007/s00396-013-3056-0 10.1021/ma502230h 10.1016/S0079-6700(03)00015-7 10.1021/acsmacrolett.5b00748 10.1039/c2sm25375e 10.1039/c1cc13955j 10.1002/anie.201000095 10.1021/ja410593n 10.1039/c0sm00284d 10.1021/cr940534g 10.1021/acs.biomac.5b00470 10.1039/C4SM00729H 10.1021/la202855u 10.1016/j.progpolymsci.2007.05.004 10.1039/c2sm26156a 10.1021/acsmacrolett.5b00928 10.1021/ja00125a035 10.1021/mz500650c 10.1021/ma300773t 10.1021/ma301303b 10.1021/acsmacrolett.5b00225 10.1039/b714578k 10.1039/C3PY00995E 10.1021/ja408069v 10.1021/ma981694n 10.1021/acs.macromol.5b01893 10.1021/ma3001719 10.1021/ma201058t 10.1039/C4SC03334E 10.1021/ma301059r 10.1021/ma0712854 10.1021/ma2000674 10.1021/acs.chemrev.5b00396 10.1002/marc.201500028 10.1039/b415959d 10.1016/j.progpolymsci.2011.08.001 10.1021/jacs.5b13455 10.1039/b903040a 10.1021/ma300887r |
| ContentType | Journal Article |
| Copyright | Copyright © 2016 American Chemical
Society |
| Copyright_xml | – notice: Copyright © 2016 American Chemical Society |
| DBID | AAYXX CITATION 7S9 L.6 |
| DOI | 10.1021/acs.macromol.6b01966 |
| DatabaseName | CrossRef AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | AGRICOLA |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5835 |
| EndPage | 8615 |
| ExternalDocumentID | 10_1021_acs_macromol_6b01966 c305625207 |
| GroupedDBID | .K2 53G 55A 5GY 5VS 7~N AABXI ABFLS ABMVS ABPPZ ABPTK ABUCX ACGFS ACJ ACNCT ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CS3 DU5 EBS ED ED~ EJD F5P GNL IH9 IHE JG JG~ K2 LG6 P2P ROL TN5 TWZ UI2 VF5 VG9 W1F WH7 X YZZ -~X 4.4 AAHBH AAYXX ABBLG ABJNI ABLBI ABQRX ACBEA ACGFO ADHLV AGXLV AHGAQ CITATION CUPRZ GGK 7S9 L.6 |
| ID | FETCH-LOGICAL-a428t-3d1b096828e7bd01533c05ec27e022b83e719c0d1131874de53640d3b5924f833 |
| IEDL.DBID | ACS |
| ISSN | 0024-9297 1520-5835 |
| IngestDate | Fri Jul 11 06:58:13 EDT 2025 Tue Jul 01 03:46:39 EDT 2025 Thu Apr 24 23:11:35 EDT 2025 Thu Feb 04 21:42:56 EST 2021 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 22 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a428t-3d1b096828e7bd01533c05ec27e022b83e719c0d1131874de53640d3b5924f833 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PQID | 2084079550 |
| PQPubID | 24069 |
| PageCount | 11 |
| ParticipantIDs | proquest_miscellaneous_2084079550 crossref_primary_10_1021_acs_macromol_6b01966 crossref_citationtrail_10_1021_acs_macromol_6b01966 acs_journals_10_1021_acs_macromol_6b01966 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2016-11-22 |
| PublicationDateYYYYMMDD | 2016-11-22 |
| PublicationDate_xml | – month: 11 year: 2016 text: 2016-11-22 day: 22 |
| PublicationDecade | 2010 |
| PublicationTitle | Macromolecules |
| PublicationTitleAlternate | Macromolecules |
| PublicationYear | 2016 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref17/cit17b ref1/cit1h ref17/cit17c ref1/cit1e ref1/cit1d ref1/cit1g ref1/cit1f ref17/cit17a ref12/cit12b ref12/cit12a ref23/cit23 ref8/cit8 ref2/cit2b ref2/cit2a ref1/cit1a ref1/cit1c ref1/cit1b ref20/cit20 ref5/cit5b ref5/cit5c ref5/cit5a ref16/cit16b ref16/cit16a ref3/cit3b ref22/cit22a ref3/cit3c ref3/cit3a ref3/cit3f ref3/cit3g ref3/cit3d ref3/cit3e ref13/cit13 ref22/cit22b ref3/cit3j ref3/cit3h ref3/cit3i ref5/cit5j ref19/cit19a ref5/cit5h ref24/cit24 ref5/cit5i ref5/cit5f ref5/cit5g ref5/cit5d ref5/cit5e ref10/cit10h ref10/cit10i ref19/cit19b ref9/cit9c ref10/cit10d ref9/cit9b ref10/cit10e ref9/cit9a ref10/cit10f ref11/cit11 ref25/cit25d ref10/cit10g ref25/cit25e ref25/cit25b ref10/cit10a ref25/cit25c ref10/cit10b ref10/cit10c ref25/cit25a ref9/cit9k ref21/cit21b ref9/cit9j ref21/cit21c ref9/cit9i ref9/cit9h ref14/cit14 ref21/cit21a ref9/cit9g ref9/cit9f ref9/cit9e ref9/cit9d ref9/cit9p ref9/cit9o ref9/cit9n ref9/cit9m ref9/cit9l ref18/cit18d ref6/cit6d ref18/cit18b ref4/cit4a ref6/cit6e ref18/cit18c ref4/cit4b ref4/cit4c ref18/cit18a ref15/cit15 ref4/cit4d ref6/cit6a ref6/cit6b ref6/cit6c ref7/cit7 |
| References_xml | – ident: ref17/cit17c doi: 10.1021/jacs.5b11599 – ident: ref9/cit9j doi: 10.1039/c2sm27602j – ident: ref3/cit3b doi: 10.1039/b805764h – ident: ref5/cit5a doi: 10.1021/ma5019473 – ident: ref10/cit10f doi: 10.1016/j.jorganchem.2007.01.051 – ident: ref5/cit5f doi: 10.1007/s00396-014-3216-x – ident: ref23/cit23 doi: 10.1021/la100840a – ident: ref9/cit9b doi: 10.1021/ma300816m – ident: ref18/cit18c doi: 10.1038/nchem.257 – ident: ref1/cit1e doi: 10.1021/acs.macromol.5b02602 – ident: ref9/cit9c doi: 10.1021/ja407033x – ident: ref12/cit12a doi: 10.1021/ja0429364 – ident: ref12/cit12b doi: 10.1021/ma047389l – ident: ref1/cit1h doi: 10.1021/ma300713f – ident: ref16/cit16a doi: 10.1126/science.1202357 – ident: ref19/cit19b doi: 10.1021/ja00060a017 – ident: ref1/cit1d doi: 10.1021/ja502843f – ident: ref3/cit3c doi: 10.1039/C1SM06035J – ident: ref7/cit7 doi: 10.1016/j.physb.2006.06.049 – ident: ref1/cit1b doi: 10.1039/C2PY20612A – ident: ref6/cit6b doi: 10.1021/ma101136v – ident: ref6/cit6c doi: 10.1039/c1sm05771e – ident: ref10/cit10c doi: 10.1016/j.progpolymsci.2010.05.001 – ident: ref1/cit1a doi: 10.1016/j.progpolymsci.2015.10.002 – ident: ref8/cit8 doi: 10.1021/ja305150c – ident: ref20/cit20 doi: 10.1021/ma011651y – ident: ref3/cit3g doi: 10.1021/acs.macromol.5b00021 – ident: ref18/cit18b doi: 10.1002/poc.610080414 – ident: ref18/cit18a doi: 10.1002/poc.610080403 – ident: ref3/cit3i doi: 10.1021/acs.macromol.5b02789 – ident: ref5/cit5e doi: 10.1007/s00396-013-3154-z – ident: ref21/cit21b doi: 10.1021/mz200020c – ident: ref3/cit3h doi: 10.1021/ja303841f – ident: ref3/cit3j doi: 10.1021/ma201865s – ident: ref9/cit9g doi: 10.1021/mz500195u – ident: ref9/cit9i doi: 10.1021/acsmacrolett.6b00235 – ident: ref5/cit5i doi: 10.1039/b515267d – ident: ref5/cit5b doi: 10.1021/mz200035b – ident: ref25/cit25a doi: 10.1021/ja3024059 – ident: ref25/cit25e doi: 10.1021/ja501756h – ident: ref10/cit10g doi: 10.1021/cr050947p – ident: ref1/cit1c doi: 10.1002/marc.200800713 – ident: ref1/cit1g doi: 10.1039/c2sm25537e – ident: ref4/cit4b doi: 10.1021/ja100685s – ident: ref11/cit11 doi: 10.1021/ma010864k – ident: ref4/cit4d doi: 10.2478/s11532-009-0092-1 – ident: ref9/cit9h doi: 10.1021/acsmacrolett.5b00523 – ident: ref9/cit9k doi: 10.1021/ma5002386 – ident: ref3/cit3e doi: 10.1016/j.jcis.2014.11.058 – ident: ref21/cit21a doi: 10.1002/anie.201105317 – ident: ref5/cit5j doi: 10.1002/marc.200700230 – ident: ref9/cit9e doi: 10.1002/marc.201500122 – ident: ref15/cit15 doi: 10.1021/ma4022983 – ident: ref16/cit16b doi: 10.1002/anie.201410598 – ident: ref4/cit4a doi: 10.1021/ma800892e – ident: ref5/cit5c doi: 10.1021/ma4003159 – ident: ref21/cit21c doi: 10.1002/anie.201308686 – ident: ref5/cit5d doi: 10.1007/s00396-013-3056-0 – ident: ref25/cit25c doi: 10.1021/ma502230h – ident: ref2/cit2a doi: 10.1016/S0079-6700(03)00015-7 – ident: ref9/cit9o doi: 10.1021/acsmacrolett.5b00748 – ident: ref22/cit22b doi: 10.1039/c2sm25375e – ident: ref3/cit3d doi: 10.1039/c1cc13955j – ident: ref6/cit6d doi: 10.1002/anie.201000095 – ident: ref9/cit9a doi: 10.1021/ja410593n – ident: ref9/cit9d doi: 10.1039/c0sm00284d – ident: ref10/cit10i doi: 10.1021/cr940534g – ident: ref6/cit6e doi: 10.1021/acs.biomac.5b00470 – ident: ref25/cit25d doi: 10.1039/C4SM00729H – ident: ref22/cit22a doi: 10.1021/la202855u – ident: ref2/cit2b doi: 10.1016/j.progpolymsci.2007.05.004 – ident: ref25/cit25b doi: 10.1039/c2sm26156a – ident: ref3/cit3a doi: 10.1021/acsmacrolett.5b00928 – ident: ref10/cit10h doi: 10.1021/ja00125a035 – ident: ref9/cit9m doi: 10.1021/mz500650c – ident: ref17/cit17a doi: 10.1021/ma300773t – ident: ref14/cit14 doi: 10.1021/ma301303b – ident: ref9/cit9n doi: 10.1021/acsmacrolett.5b00225 – ident: ref10/cit10d doi: 10.1039/b714578k – ident: ref9/cit9l doi: 10.1039/C3PY00995E – ident: ref18/cit18d doi: 10.1021/ja408069v – ident: ref19/cit19a doi: 10.1021/ma981694n – ident: ref3/cit3f doi: 10.1021/acs.macromol.5b01893 – ident: ref10/cit10a doi: 10.1021/ma3001719 – ident: ref4/cit4c doi: 10.1021/ma201058t – ident: ref9/cit9p doi: 10.1039/C4SC03334E – ident: ref24/cit24 doi: 10.1021/ma301059r – ident: ref6/cit6a doi: 10.1021/ma0712854 – ident: ref9/cit9f doi: 10.1021/ma2000674 – ident: ref10/cit10b doi: 10.1021/acs.chemrev.5b00396 – ident: ref1/cit1f doi: 10.1002/marc.201500028 – ident: ref5/cit5g doi: 10.1039/b415959d – ident: ref10/cit10e doi: 10.1016/j.progpolymsci.2011.08.001 – ident: ref17/cit17b doi: 10.1021/jacs.5b13455 – ident: ref5/cit5h doi: 10.1039/b903040a – ident: ref13/cit13 doi: 10.1021/ma300887r |
| SSID | ssj0011543 |
| Score | 2.5623698 |
| Snippet | Polymerization-induced self-assembly (PISA) was achieved by conducting an initiators for continuous activator regeneration atom transfer radical polymerization... |
| SourceID | proquest crossref acs |
| SourceType | Aggregation Database Enrichment Source Index Database Publisher |
| StartPage | 8605 |
| SubjectTerms | ambient temperature catalysts composite polymers copper ethanol gel chromatography glass transition temperature light scattering polymerization stabilizers transmission electron microscopy |
| Title | Polymerization-Induced Self-Assembly (PISA) Using ICAR ATRP at Low Catalyst Concentration |
| URI | http://dx.doi.org/10.1021/acs.macromol.6b01966 https://www.proquest.com/docview/2084079550 |
| Volume | 49 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LS8QwEA4-DnrxLb6J4EEPWdukm3aPpSgqoouroKfSJNOL3a7YLrL-eid9KCqi3kppSsikmfn6zXxDyIHkPvcC8JhITcq8tBewoIdXOpWJa8u-hK7UPq_k2Z13cd-9_wCKXxl87h4nuugMkyo5LetIZfVc5DSZ5TLwLdgKo8E7a4DhQM0oc4-h2_fbUrkf3mIdki4-O6TP53HlZE4XyXVbqlPnljx2xqXq6Nfvyo1_nP8SWWjiTRrWG2SZTEG-Quaits3bKnnoj7KJpW3qekxme3loMHQAWcosJTxU2YQe9s8H4RGtEgzoeRTe0PD2pk-Tkl6OXmhk_wFNipJGtggyb5R418jd6cltdMaafgssQRBSMmFchYgGMRj4yjg2EtROFzT3AT29CgT4bk87xnWF7eRnoCuk5xihugji0kCIdTKTj3LYIDSVkAa-FuBB4qHBFR4DxvDEIH4BF5xNcoTrEjffSxFXVDh3Y3uzXay4WaxNIloDxboRLrf9M7JfRrH3UU-1cMcvz--3to_RApY2SXIYjYuYOwiC_R5Cua1_zHqbzGNsJW3ZIuc7ZKZ8HsMuxi-l2qs27Rv1LeyV |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV1Lb9NAEB5V5VAuvBGlPBYJJHrYYO86tnPgEBmqhIYqalKpnIx3d3yp61TYURX-D3-F38WMYwcVCVUcKnGzVl5rvDO7883OC-B1qCIVxBhInbtcBvkglvGAnmweZj6nfWnbVPs8CkcnwafT_ukW_OhyYYiIir5UNU7839UF_Hc8dp41MWpFLzRc1iVsYykPcXVJllr1fvyB2PpGqYOP82Qk22YCMiOEXUvtfENwnQwMjIzzGOZYr49WRUhqzMQaI39gPef7mtvUOezrMPCcNn2yUPKY7z3ppL9F-EexjTdMZhtnBaGQtSNbBZLQRtRl6P2FataDtrqqB6-qgUa3HdyFn5tVaUJaznrL2vTs9z8KRv73y3YP7rToWgzX2-E-bGH5AHaSrqndQ_gyXRQrdlKts08ldy6x6MQMi1yyA_zcFCvxdjqeDfdFE04hiMxjMZwfT0VWi8niUiR847WqapFwymfZ1h1-BCc38mePYbtclPgERB5iHkdWY4BZQOJt6NBzTmWOrDX00duFfeJD2p4OVdo4_pWf8mDHnLRlzi7oTi5S25Zp524hxTWz5GbWxbpMyTXvv-pELiUOsJMoK3GxrFLlkckfDchwffoPVL-EndH88ySdjI8O9-A2ocqQEzaVegbb9bclPifkVpsXzb4R8PWmJe4XkpBLXA |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V3NTtwwELYQlWgvbemPSqGtK4FUDl4SO5tkDxxWoSu2ILRiQaKnNLbHl4YsIlmh5Y14FZ6KmWyyEpUqxIEDt8iKo4ln7PnG88fYZigjGcQQCOWsE4HrxSLu4ZNxYeZT2pcydbXPo3D_NPh11j1bYjdtLgwSUeKXytqJT7v6wrqmwoC_Q-PnWR2nlndCTaVdwiae8gBmV2itlbvDPWTtlpSDnyfJvmgaCogMUXYllPU1QnY0MiDS1iOoY7wuGBkBqjIdK4j8nvGs7ytqVWehq8LAs0p30UpxMd194mn_gjyFZOf1k_HCYYFIZO7MloFAxBG1WXr_oZp0oSnv68L7qqDWb4M37HaxMnVYy9_OtNIdc_1P0chnsXRv2esGZfP-fFussiUo3rGXSdvc7j37PZrkM3JWzbNQBXUwMWD5GHInyBF-rvMZ_zEajvvbvA6r4EjmMe-fHI94VvHDyRVP6OZrVlY8odTPoqk__IGdPsmffWTLxaSAT4y7EFwcGQUBZAGKucbDz1qZWbTawAdvjW0jH9LmlCjTOgBA-ikNtsxJG-asMdXKRmqacu3UNSR_YJZYzLqYlyt54P3vrdilyAFyFmUFTKZlKj00_aMeGrCfH0H1N7Yy2hukh8Ojg3X2CsFlSHmbUm6w5epyCl8QwFX6a711OPvz1AJ3B5_RTd8 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Polymerization-Induced+Self-Assembly+%28PISA%29+Using+ICAR+ATRP+at+Low+Catalyst+Concentration&rft.jtitle=Macromolecules&rft.au=Wang%2C+Guowei&rft.au=Schmitt%2C+Michael&rft.au=Wang%2C+Zongyu&rft.au=Lee%2C+Bongjoon&rft.date=2016-11-22&rft.issn=1520-5835&rft.volume=49&rft.issue=22+p.8605-8615&rft.spage=8605&rft.epage=8615&rft_id=info:doi/10.1021%2Facs.macromol.6b01966&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0024-9297&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0024-9297&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0024-9297&client=summon |