Characterization of oxide assemblages of a suite of granulites from Eastern Ghats Belt, India: Implication to the evolution of C–O–H–F fluids during retrogression
We document complex intergrowth involving spinel–ilmenite–magnetite–hematite–corundum–rutile in various combinations from a suite of granulite facies rocks of Eastern Ghats Belt, India. Individual oxide phase shows considerable compositional variation among textures and samples. These textures argua...
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| Published in | Lithos Vol. 113; no. 3-4; pp. 483 - 497 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.12.2009
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0024-4937 1872-6143 |
| DOI | 10.1016/j.lithos.2009.05.029 |
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| Abstract | We document complex intergrowth involving spinel–ilmenite–magnetite–hematite–corundum–rutile in various combinations from a suite of granulite facies rocks of Eastern Ghats Belt, India. Individual oxide phase shows considerable compositional variation among textures and samples. These textures arguably developed by oxidation reaction of early spinel and ilmenite solid solution from near-peak to subsequent retrogressive stages. Oxygen fugacity is measured at a constant pressure of 8 kbar and different temperatures estimated from geothermometric analyses involving oxide and silicate-bearing equilibria in different samples. The calculated fO2 values are 2–3 log units higher than the QFM buffer except for one sample. Uncertainties in fO2 calculation in some samples arise presumably due to extensive compositional readjustment of different oxide systematics at lower temperatures. The persistence of high fO2 in mineral assemblages could be inherited from an oxidized precursor, but field evidence and presence of H2O–CO2-rich fluid inclusions in the studied samples imply possible involvement of externally-derived oxidizing fluid in the later part of the retrograde history. Recent experimental and natural data suggest CO2 charged brine solution could be suitable for oxidation of mineral assemblages. Presence of brine inclusions are not detected, but fluorine enriched nature of biotite grains could possibly provide some indication for its presence. The mixed fluid possibly has its source in the crystallizing mafic magma emplaced at the lower crust that is exposed in the adjacent area. |
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| AbstractList | We document complex intergrowth involving spinel–ilmenite–magnetite–hematite–corundum–rutile in various combinations from a suite of granulite facies rocks of Eastern Ghats Belt, India. Individual oxide phase shows considerable compositional variation among textures and samples. These textures arguably developed by oxidation reaction of early spinel and ilmenite solid solution from near-peak to subsequent retrogressive stages. Oxygen fugacity is measured at a constant pressure of 8 kbar and different temperatures estimated from geothermometric analyses involving oxide and silicate-bearing equilibria in different samples. The calculated fO2 values are 2–3 log units higher than the QFM buffer except for one sample. Uncertainties in fO2 calculation in some samples arise presumably due to extensive compositional readjustment of different oxide systematics at lower temperatures. The persistence of high fO2 in mineral assemblages could be inherited from an oxidized precursor, but field evidence and presence of H2O–CO2-rich fluid inclusions in the studied samples imply possible involvement of externally-derived oxidizing fluid in the later part of the retrograde history. Recent experimental and natural data suggest CO2 charged brine solution could be suitable for oxidation of mineral assemblages. Presence of brine inclusions are not detected, but fluorine enriched nature of biotite grains could possibly provide some indication for its presence. The mixed fluid possibly has its source in the crystallizing mafic magma emplaced at the lower crust that is exposed in the adjacent area. We document complex intergrowth involving spinel-ilmenite-magnetite-hematite-corundum-rutile in various combinations from a suite of granulite facies rocks of Eastern Ghats Belt, India. Individual oxide phase shows considerable compositional variation among textures and samples. These textures arguably developed by oxidation reaction of early spinel and ilmenite solid solution from near-peak to subsequent retrogressive stages. Oxygen fugacity is measured at a constant pressure of 8 kbar and different temperatures estimated from geothermometric analyses involving oxide and silicate-bearing equilibria in different samples. The calculated fO sub(2 values are 2-3 log units higher than the QFM buffer except for one sample. Uncertainties in fO) sub(2) calculation in some samples arise presumably due to extensive compositional readjustment of different oxide systematics at lower temperatures. The persistence of high fO sub(2 in mineral assemblages could be inherited from an oxidized precursor, but field evidence and presence of H) sub(2)O-CO sub(2-rich fluid inclusions in the studied samples imply possible involvement of externally-derived oxidizing fluid in the later part of the retrograde history. Recent experimental and natural data suggest CO) sub(2) charged brine solution could be suitable for oxidation of mineral assemblages. Presence of brine inclusions are not detected, but fluorine enriched nature of biotite grains could possibly provide some indication for its presence. The mixed fluid possibly has its source in the crystallizing mafic magma emplaced at the lower crust that is exposed in the adjacent area. |
| Author | Dasgupta, Somnath Ohnishi, Ichiro Das, Kaushik Karmakar, Subrata Bose, Sankar Torimoto, Junji Shinoda, Keiji |
| Author_xml | – sequence: 1 givenname: Sankar surname: Bose fullname: Bose, Sankar email: sankar.bose@gmail.com organization: Department of Geology, Presidency College, Kolkata 700 073, India – sequence: 2 givenname: Kaushik surname: Das fullname: Das, Kaushik organization: Department of Geology, Bengal Engineering and Science University, Howrah, 711 103, India – sequence: 3 givenname: Ichiro surname: Ohnishi fullname: Ohnishi, Ichiro organization: Electron Optics Division, JEOL Ltd., Tokyo, 196-8558, Japan – sequence: 4 givenname: Junji surname: Torimoto fullname: Torimoto, Junji organization: Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan – sequence: 5 givenname: Subrata surname: Karmakar fullname: Karmakar, Subrata organization: Department of Geological Sciences, Jadavpur University, Kolkata 700 032, India – sequence: 6 givenname: Keiji surname: Shinoda fullname: Shinoda, Keiji organization: Department of Geoscience, Osaka City University, Osaka, 558-8585, Japan – sequence: 7 givenname: Somnath surname: Dasgupta fullname: Dasgupta, Somnath organization: Indian Institute of Science Education and Research, Kolkata, India |
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| Keywords | Oxygen fugacity Isobaric cooling Fe–Ti–Al oxides Eastern Ghats Belt |
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| Snippet | We document complex intergrowth involving spinel–ilmenite–magnetite–hematite–corundum–rutile in various combinations from a suite of granulite facies rocks of... We document complex intergrowth involving spinel-ilmenite-magnetite-hematite-corundum-rutile in various combinations from a suite of granulite facies rocks of... |
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| SubjectTerms | Eastern Ghats Belt Fe–Ti–Al oxides Isobaric cooling Oxygen fugacity |
| Title | Characterization of oxide assemblages of a suite of granulites from Eastern Ghats Belt, India: Implication to the evolution of C–O–H–F fluids during retrogression |
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