Supramolecular Gel Phase Controlled [4 + 2] Diels–Alder Photocycloaddition for Electroplex Mediated White Electroluminescence

• Published in: Journal of the American Chemical Society Vol. 141; no. 14; pp. 5635 - 5639
• Main Authors: Das, Satyajit, Okamura, Naoki, Yagi, Shigeyuki, Ajayaghosh, Ayyappanpillai
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 10.04.2019; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Multidisciplinary; color; cycloaddition reactions; electrochemiluminescence; gels; Physical Sciences; Science & Technology; white light; LIGHT; ENHANCEMENT; EXCIMER PHOSPHORESCENCE; PHOTOCHEMISTRY; PI; SINGLE-EMITTING-COMPONENT; COMPLEXES BEARING; EMISSION; PHOTOCYCLODIMERIZATION

Diels–Alder photocycloaddition of 9-phenyl­ethynyl­anthracene results in multiple [4 + 2] and [4 + 4] cycloaddition products in solution, which can be controlled to form specific products under a restricted environment. We have exploited the gel phase of a 9-phenylethynyl­anthracence derivative as a...