In Situ Thermal Cross-Linking of 9,9′-Spirobifluorene-Based Hole-Transporting Layer for Perovskite Solar Cells

A novel 9,9′-spirobifluorene derivative bearing thermally cross-linkable vinyl groups (V1382) was developed as a hole-transporting material for perovskite solar cells (PSCs). After thermal cross-linking, a smooth and solvent-resistant three-dimensional (3D) polymeric network is formed such that orth...

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Published inACS applied materials & interfaces Vol. 16; no. 1; pp. 1206 - 1216
Main Authors Daskeviciute-Geguziene, Sarune, Truong, Minh Anh, Rakstys, Kasparas, Daskeviciene, Maryte, Hashimoto, Ruito, Murdey, Richard, Yamada, Takumi, Kanemitsu, Yoshihiko, Jankauskas, Vygintas, Wakamiya, Atsushi, Getautis, Vytautas
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 10.01.2024
Subjects
Organic Electronic Devices
temperature
perovskite solar cell
hole-transporting layer
cross-linking
spirobifluorene
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Abstract A novel 9,9′-spirobifluorene derivative bearing thermally cross-linkable vinyl groups (V1382) was developed as a hole-transporting material for perovskite solar cells (PSCs). After thermal cross-linking, a smooth and solvent-resistant three-dimensional (3D) polymeric network is formed such that orthogonal solvents are no longer needed to process subsequent layers. Copolymerizing V1382 with 4,4′-thiobisbenzenethiol (dithiol) lowers the cross-linking temperature to 103 °C via the facile thiol–ene “click” reaction. The effectiveness of the cross-linked V1382/dithiol was demonstrated both as a hole-transporting material in p–i–n and as an interlayer between the perovskite and the hole-transporting layer in n–i–p PSC devices. Both devices exhibit better power conversion efficiencies and operational stability than devices using conventional PTAA or Spiro-OMeTAD hole-transporting materials.
AbstractList A novel 9,9'-spirobifluorene derivative bearing thermally cross-linkable vinyl groups ( ) was developed as a hole-transporting material for perovskite solar cells (PSCs). After thermal cross-linking, a smooth and solvent-resistant three-dimensional (3D) polymeric network is formed such that orthogonal solvents are no longer needed to process subsequent layers. Copolymerizing with 4,4'-thiobisbenzenethiol (dithiol) lowers the cross-linking temperature to 103 °C via the facile thiol-ene "click" reaction. The effectiveness of the cross-linked /dithiol was demonstrated both as a hole-transporting material in p-i-n and as an interlayer between the perovskite and the hole-transporting layer in n-i-p PSC devices. Both devices exhibit better power conversion efficiencies and operational stability than devices using conventional or hole-transporting materials.
A novel 9,9'-spirobifluorene derivative bearing thermally cross-linkable vinyl groups (V1382) was developed as a hole-transporting material for perovskite solar cells (PSCs). After thermal cross-linking, a smooth and solvent-resistant three-dimensional (3D) polymeric network is formed such that orthogonal solvents are no longer needed to process subsequent layers. Copolymerizing V1382 with 4,4'-thiobisbenzenethiol (dithiol) lowers the cross-linking temperature to 103 °C via the facile thiol-ene "click" reaction. The effectiveness of the cross-linked V1382/dithiol was demonstrated both as a hole-transporting material in p-i-n and as an interlayer between the perovskite and the hole-transporting layer in n-i-p PSC devices. Both devices exhibit better power conversion efficiencies and operational stability than devices using conventional PTAA or Spiro-OMeTAD hole-transporting materials.
A novel 9,9′-spirobifluorene derivative bearing thermally cross-linkable vinyl groups ( V1382 ) was developed as a hole-transporting material for perovskite solar cells (PSCs). After thermal cross-linking, a smooth and solvent-resistant three-dimensional (3D) polymeric network is formed such that orthogonal solvents are no longer needed to process subsequent layers. Copolymerizing V1382 with 4,4′-thiobisbenzenethiol (dithiol) lowers the cross-linking temperature to 103 °C via the facile thiol–ene “click” reaction. The effectiveness of the cross-linked V1382 /dithiol was demonstrated both as a hole-transporting material in p–i–n and as an interlayer between the perovskite and the hole-transporting layer in n–i–p PSC devices. Both devices exhibit better power conversion efficiencies and operational stability than devices using conventional PTAA or Spiro-OMeTAD hole-transporting materials.
Author Hashimoto, Ruito
Yamada, Takumi
Jankauskas, Vygintas
Getautis, Vytautas
Murdey, Richard
Truong, Minh Anh
Daskeviciene, Maryte
Kanemitsu, Yoshihiko
Wakamiya, Atsushi
Daskeviciute-Geguziene, Sarune
Rakstys, Kasparas
AuthorAffiliation Institute of Chemical Physics
Department of Organic Chemistry
Institute for Chemical Research
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10.1039/C7TA01258F
10.1002/anie.201601757
10.1039/C7EE00826K
10.1002/aenm.201601165
10.1039/D0TA11564A
10.1039/C9EE00872A
10.1126/science.abl5676
10.1016/j.cej.2022.136760
10.1007/s11426-021-1059-1
10.1002/adma.202106540
10.1021/acs.chemmater.3c00708
10.1021/jacs.3c00805
10.1002/adma.202209422
10.1016/j.cej.2021.130124
10.1002/solr.202000573
10.1021/acsami.2c15989
10.1039/C8CS00262B
10.1039/D0EE02337J
10.1021/acsaem.2c01470
10.1039/D2CC02612K
10.1016/j.nanoen.2020.105462
10.1039/C9SC01184F
10.1021/jacs.0c06373
10.1021/acsaem.2c02880
10.1039/C8TA12060A
10.1002/aenm.202200666
10.1002/pip.2437
10.1002/solr.202200234
10.1021/acsaem.8b02047
10.1002/aenm.201700306
10.1021/acs.chemrev.0c00107
10.1002/adfm.202109968
10.1038/s41467-018-06204-2
10.1002/adma.202203794
10.1021/acsphotonics.1c00939
10.1038/s41560-018-0219-8
10.1038/s41467-023-36938-7
10.1039/C5TA01479D
10.1002/adma.202005410
10.1126/science.abm8566
10.1021/cm2024235
10.1016/j.orgel.2019.05.019
10.1039/C9TA02142F
10.1002/anie.201504666
10.1021/acs.jpclett.6b02847
10.1039/D1EE04022G
10.1038/s41560-023-01295-8
10.1039/C8EE01831F
10.1002/aenm.201801892
10.1021/cm071828o
10.1002/solr.202000597
10.1021/acsami.0c13576
10.1021/acsnano.9b07594
10.1021/acsaem.9b01997
10.1002/solr.202200647
10.1126/science.abd4016
10.1039/C5EE03911H
10.1126/science.aat8235
10.1002/solr.202300252
10.1021/acsami.8b04396
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Keywords temperature
perovskite solar cell
hole-transporting layer
cross-linking
spirobifluorene
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References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref56/cit56
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref59/cit59
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref60/cit60
ref17/cit17
ref10/cit10
ref35/cit35
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref61/cit61
ref24/cit24
ref38/cit38
ref50/cit50
ref54/cit54
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref57/cit57
ref5/cit5
ref51/cit51
ref43/cit43
ref28/cit28
ref40/cit40
ref26/cit26
ref55/cit55
ref12/cit12
ref15/cit15
ref62/cit62
ref41/cit41
ref58/cit58
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref24/cit24
  doi: 10.1039/C8TC02241K
– ident: ref11/cit11
  doi: 10.1039/C7TA01258F
– ident: ref10/cit10
  doi: 10.1002/anie.201601757
– ident: ref2/cit2
  doi: 10.1039/C7EE00826K
– ident: ref49/cit49
  doi: 10.1002/aenm.201601165
– ident: ref13/cit13
  doi: 10.1039/D0TA11564A
– ident: ref28/cit28
  doi: 10.1039/C9EE00872A
– ident: ref18/cit18
  doi: 10.1126/science.abl5676
– ident: ref30/cit30
  doi: 10.1016/j.cej.2022.136760
– ident: ref41/cit41
  doi: 10.1007/s11426-021-1059-1
– ident: ref6/cit6
  doi: 10.1002/adma.202106540
– ident: ref58/cit58
  doi: 10.1021/acs.chemmater.3c00708
– ident: ref34/cit34
  doi: 10.1021/jacs.3c00805
– ident: ref40/cit40
  doi: 10.1002/adma.202209422
– ident: ref43/cit43
  doi: 10.1016/j.cej.2021.130124
– ident: ref23/cit23
  doi: 10.1002/solr.202000573
– ident: ref55/cit55
  doi: 10.1021/acsami.2c15989
– ident: ref9/cit9
  doi: 10.1039/C8CS00262B
– ident: ref12/cit12
  doi: 10.1039/D0EE02337J
– ident: ref52/cit52
  doi: 10.1021/acsaem.2c01470
– ident: ref42/cit42
  doi: 10.1039/D2CC02612K
– ident: ref60/cit60
  doi: 10.1016/j.nanoen.2020.105462
– ident: ref14/cit14
  doi: 10.1039/C9SC01184F
– ident: ref50/cit50
  doi: 10.1021/jacs.0c06373
– ident: ref57/cit57
  doi: 10.1021/acsaem.2c02880
– ident: ref45/cit45
  doi: 10.1039/C8TA12060A
– ident: ref16/cit16
  doi: 10.1002/aenm.202200666
– ident: ref3/cit3
  doi: 10.1002/pip.2437
– ident: ref20/cit20
  doi: 10.1002/solr.202200234
– ident: ref26/cit26
  doi: 10.1021/acsaem.8b02047
– ident: ref37/cit37
  doi: 10.1002/aenm.201700306
– ident: ref8/cit8
  doi: 10.1021/acs.chemrev.0c00107
– ident: ref32/cit32
  doi: 10.1002/adfm.202109968
– ident: ref19/cit19
  doi: 10.1038/s41467-018-06204-2
– ident: ref5/cit5
  doi: 10.1002/adma.202203794
– ident: ref15/cit15
  doi: 10.1021/acsphotonics.1c00939
– ident: ref22/cit22
  doi: 10.1038/s41560-018-0219-8
– ident: ref61/cit61
  doi: 10.1038/s41467-023-36938-7
– ident: ref48/cit48
  doi: 10.1039/C5TA01479D
– ident: ref4/cit4
  doi: 10.1002/adma.202005410
– ident: ref21/cit21
  doi: 10.1126/science.abm8566
– ident: ref38/cit38
  doi: 10.1021/cm2024235
– ident: ref25/cit25
  doi: 10.1016/j.orgel.2019.05.019
– ident: ref1/cit1
– ident: ref56/cit56
  doi: 10.1039/C9TA02142F
– ident: ref54/cit54
  doi: 10.1002/anie.201504666
– ident: ref62/cit62
  doi: 10.1021/acs.jpclett.6b02847
– ident: ref59/cit59
  doi: 10.1039/D1EE04022G
– ident: ref31/cit31
  doi: 10.1038/s41560-023-01295-8
– ident: ref33/cit33
  doi: 10.1039/C8EE01831F
– ident: ref36/cit36
  doi: 10.1002/aenm.201801892
– ident: ref39/cit39
  doi: 10.1021/cm071828o
– ident: ref44/cit44
  doi: 10.1002/solr.202000597
– ident: ref17/cit17
  doi: 10.1021/acsami.0c13576
– ident: ref29/cit29
  doi: 10.1021/acsnano.9b07594
– ident: ref51/cit51
  doi: 10.1021/acsaem.9b01997
– ident: ref27/cit27
  doi: 10.1002/solr.202200647
– ident: ref35/cit35
  doi: 10.1126/science.abd4016
– ident: ref53/cit53
  doi: 10.1039/C5EE03911H
– ident: ref7/cit7
  doi: 10.1126/science.aat8235
– ident: ref46/cit46
  doi: 10.1002/solr.202300252
– ident: ref47/cit47
  doi: 10.1021/acsami.8b04396
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Snippet A novel 9,9′-spirobifluorene derivative bearing thermally cross-linkable vinyl groups (V1382) was developed as a hole-transporting material for perovskite...
A novel 9,9'-spirobifluorene derivative bearing thermally cross-linkable vinyl groups ( ) was developed as a hole-transporting material for perovskite solar...
A novel 9,9'-spirobifluorene derivative bearing thermally cross-linkable vinyl groups (V1382) was developed as a hole-transporting material for perovskite...
A novel 9,9′-spirobifluorene derivative bearing thermally cross-linkable vinyl groups ( V1382 ) was developed as a hole-transporting material for perovskite...
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SubjectTerms Organic Electronic Devices
Title In Situ Thermal Cross-Linking of 9,9′-Spirobifluorene-Based Hole-Transporting Layer for Perovskite Solar Cells
URI http://dx.doi.org/10.1021/acsami.3c13950
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