Narrow Linewidth Excitonic Emission in Organic–Inorganic Lead Iodide Perovskite Single Crystals

Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3P...

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Published inThe journal of physical chemistry letters Vol. 7; no. 24; pp. 5093 - 5100
Main Authors Diab, Hiba, Trippé-Allard, Gaëlle, Lédée, Ferdinand, Jemli, Khaoula, Vilar, Christèle, Bouchez, Guillaume, Jacques, Vincent L.R, Tejeda, Antonio, Even, Jacky, Lauret, Jean-Sébastien, Deleporte, Emmanuelle, Garrot, Damien
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 15.12.2016
Subjects
Chemical Sciences
Condensed Matter
Materials Science
or physical chemistry
Physics
Theoretical and
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Abstract Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3PbI3 single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton–LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.
AbstractList Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3PbI3 single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton–LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.
Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH NH PbI single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton-LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.
Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3PbI3 single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton-LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3PbI3 single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton-LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.
Author Even, Jacky
Deleporte, Emmanuelle
Garrot, Damien
Trippé-Allard, Gaëlle
Lédée, Ferdinand
Vilar, Christèle
Tejeda, Antonio
Lauret, Jean-Sébastien
Jemli, Khaoula
Bouchez, Guillaume
Diab, Hiba
Jacques, Vincent L.R
AuthorAffiliation Laboratoire Aimé Cotton, CNRS
Université de Versailles Saint-Quentin-en-Yvelines, Université Paris-Saclay
Université Paris-Sud, ENS Cachan, Université Paris-Saclay
Groupe d’Etude de la Matiére Condensée, CNRS
Laboratoire de Physique des Solides
AuthorAffiliation_xml – name: Laboratoire de Physique des Solides
– name: Université Paris-Sud, ENS Cachan, Université Paris-Saclay
– name: Université de Versailles Saint-Quentin-en-Yvelines, Université Paris-Saclay
– name: Laboratoire Aimé Cotton, CNRS
– name: Groupe d’Etude de la Matiére Condensée, CNRS
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  orcidid: 0000-0002-4865-8536
  surname: Garrot
  fullname: Garrot, Damien
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Snippet Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress...
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SubjectTerms Chemical Sciences
Condensed Matter
Materials Science
or physical chemistry
Physics
Theoretical and
Title Narrow Linewidth Excitonic Emission in Organic–Inorganic Lead Iodide Perovskite Single Crystals
URI http://dx.doi.org/10.1021/acs.jpclett.6b02261
https://www.ncbi.nlm.nih.gov/pubmed/27973876
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Volume 7
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