Lithium Dicyclohexylamide in Transition-Metal-Free Fischer–Tropsch Chemistry
Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H2, effecting sequential C–C and C–H bond formations from CO or H2, thus providing a transition-metal-free avenue to the fundament...
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| Published in | Journal of the American Chemical Society Vol. 143; no. 2; pp. 634 - 638 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
20.01.2021
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| Abstract | Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H2, effecting sequential C–C and C–H bond formations from CO or H2, thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer–Tropsch process. Further experimental and computational data indicate that reactions with CO and H2 are thermodynamically accessible, with a kinetic bias toward CO homologation. |
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| AbstractList | Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H2, effecting sequential C–C and C–H bond formations from CO or H2, thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer–Tropsch process. Further experimental and computational data indicate that reactions with CO and H2 are thermodynamically accessible, with a kinetic bias toward CO homologation. Lithium dicyclohexylamide (Cy₂NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H₂, effecting sequential C–C and C–H bond formations from CO or H₂, thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer–Tropsch process. Further experimental and computational data indicate that reactions with CO and H₂ are thermodynamically accessible, with a kinetic bias toward CO homologation. Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H2, effecting sequential C-C and C-H bond formations from CO or H2, thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer-Tropsch process. Further experimental and computational data indicate that reactions with CO and H2 are thermodynamically accessible, with a kinetic bias toward CO homologation.Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H2, effecting sequential C-C and C-H bond formations from CO or H2, thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer-Tropsch process. Further experimental and computational data indicate that reactions with CO and H2 are thermodynamically accessible, with a kinetic bias toward CO homologation. Lithium dicyclohexylamide (Cy NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further with CO or H , effecting sequential C-C and C-H bond formations from CO or H , thus providing a transition-metal-free avenue to the fundamental reactions of the Fischer-Tropsch process. Further experimental and computational data indicate that reactions with CO and H are thermodynamically accessible, with a kinetic bias toward CO homologation. |
| Author | Xu, Maotong Qu, Zheng-wang Stephan, Douglas W Grimme, Stefan |
| AuthorAffiliation | Department of Chemistry Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie |
| AuthorAffiliation_xml | – name: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie – name: Department of Chemistry |
| Author_xml | – sequence: 1 givenname: Maotong surname: Xu fullname: Xu, Maotong organization: Department of Chemistry – sequence: 2 givenname: Zheng-wang orcidid: 0000-0001-6631-3681 surname: Qu fullname: Qu, Zheng-wang email: qu@thch.uni-bonn.de organization: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie – sequence: 3 givenname: Stefan orcidid: 0000-0002-5844-4371 surname: Grimme fullname: Grimme, Stefan organization: Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie – sequence: 4 givenname: Douglas W orcidid: 0000-0001-8140-8355 surname: Stephan fullname: Stephan, Douglas W email: dstephan@chem.utoronto.ca organization: Department of Chemistry |
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| Snippet | Lithium dicyclohexylamide (Cy2NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further... Lithium dicyclohexylamide (Cy NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further... Lithium dicyclohexylamide (Cy₂NLi) reacts with syn-gas or CO to generate transient intermediates with carbene character, which are capable of reacting further... |
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| Title | Lithium Dicyclohexylamide in Transition-Metal-Free Fischer–Tropsch Chemistry |
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