Fluorenyl Based Macrocyclic Polyradicaloids

• Published in: Journal of the American Chemical Society Vol. 139; no. 37; pp. 13173 - 13183
• Main Authors: Lu, Xuefeng, Lee, Sangsu, Hong, Yongseok, Phan, Hoa, Gopalakrishna, Tullimilli Y, Herng, Tun Seng, Tanaka, Takayuki, Sandoval-Salinas, María Eugenia, Zeng, Wangdong, Ding, Jun, Casanova, David, Osuka, Atsuhiro, Kim, Dongho, Wu, Jishan
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 20.09.2017; Amer Chemical Soc
• Subjects: absorption; Chemistry; Chemistry, Multidisciplinary; electrochemistry; energy; ferrimagnetic materials; free radicals; gel chromatography; geometry; moieties; organic chemistry; physical properties; Physical Sciences; Science & Technology; QUINOIDAL OLIGOTHIOPHENES; POLYCYCLIC AROMATIC-HYDROCARBON; GROUND-STATE; BIRADICALOID CHARACTER; 2ND HYPERPOLARIZABILITIES; OPEN-SHELL; CLOSED-SHELL; CHAIN-LENGTH; EXTENDED P-QUINODIMETHANES; DIRADICAL CHARACTER

Synthesis of stable open-shell polyradicaloids including control of intramolecular spin–spin interactions is a challenging topic in organic chemistry and materials science. Herein, we report the synthesis and physical characterization of two series of fluorenyl based macrocyclic polyradicaloids. In...