3D Porphyrin-Based Covalent Organic Frameworks

• Published in: Journal of the American Chemical Society Vol. 139; no. 25; pp. 8705 - 8709
• Main Authors: Lin, Guiqing, Ding, Huimin, Chen, Rufan, Peng, Zhengkang, Wang, Baoshan, Wang, Cheng
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 28.06.2017; Amer Chemical Soc
• Subjects: catalysts; Chemistry; Chemistry, Multidisciplinary; condensation reactions; imines; photocatalysis; photosensitivity; Physical Sciences; porous media; porphyrins; Science & Technology; singlet oxygen; topology; PLATFORM; CATALYSIS; DESIGN; REDUCTION; DIFFERENT KINDS; CONSTRUCTION; POLYMERIZATION; GENERATION; CRYSTALLINE; STORAGE APPLICATIONS

The design and synthesis of three-dimensional covalent organic frameworks (3D COFs) bearing photoelectric units have been considered as a big challenge. Herein, for the first time, we reported the targeted synthesis of two 3D porphyrin-based COFs (3D-Por-COF and 3D-CuPor-COF), starting from tetrahed...