Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries
While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to...
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| Published in | Journal of the American Chemical Society Vol. 141; no. 16; pp. 6680 - 6689 |
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| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
24.04.2019
American Chemical Society (ACS) |
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| Abstract | While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g–1 and a remarkably high capacity retention of ∼87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy. |
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| AbstractList | While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g–1 and a remarkably high capacity retention of ∼87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy. While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g–1 and a remarkably high capacity retention of ~87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy. While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2-Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g-1 and a remarkably high capacity retention of ∼87% after 80 cycles within a wide voltage range of 1.5-4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2-O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy.While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2-Na0.66Li0.18Fe0.12Mn0.7O2, which demonstrated a high capacity of 190 mAh g-1 and a remarkably high capacity retention of ∼87% after 80 cycles within a wide voltage range of 1.5-4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2-O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy. While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of the cathode is one of the bottlenecks in the development of SIBs. Following a strategy of using lithium doping in the transition-metal layer to stabilize the desodiated structure, we have designed and successfully synthesized a novel layered oxide cathode P2–Na₀.₆₆Li₀.₁₈Fe₀.₁₂Mn₀.₇O₂, which demonstrated a high capacity of 190 mAh g–¹ and a remarkably high capacity retention of ∼87% after 80 cycles within a wide voltage range of 1.5–4.5 V. The outstanding stability is attributed to the reversible migration of lithium during cycling and the elimination of the detrimental P2–O2 phase transition, revealed by ex situ and in situ X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy. |
| Author | Liu, Meilin Bai, Jianming Chen, Hailong Liu, Jue Ma, Xuetian Xu, Wenqian Xiong, Shan Li, Xiang Yang, Lufeng Liu, Pan Tang, Yuanzhi Hu, Yan-Yan |
| AuthorAffiliation | Neutron Scattering Division School of Materials Science and Engineering School of Earth and Atmospheric Sciences Department of Chemistry and Biochemistry National Synchrotron Light Source II The Woodruff School of Mechanical Engineering Argonne National Laboratory National High Magnetic Field Laboratory |
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| Author_xml | – sequence: 1 givenname: Lufeng surname: Yang fullname: Yang, Lufeng organization: The Woodruff School of Mechanical Engineering – sequence: 2 givenname: Xiang surname: Li fullname: Li, Xiang organization: Department of Chemistry and Biochemistry – sequence: 3 givenname: Jue orcidid: 0000-0002-4453-910X surname: Liu fullname: Liu, Jue organization: Neutron Scattering Division – sequence: 4 givenname: Shan surname: Xiong fullname: Xiong, Shan organization: The Woodruff School of Mechanical Engineering – sequence: 5 givenname: Xuetian surname: Ma fullname: Ma, Xuetian organization: The Woodruff School of Mechanical Engineering – sequence: 6 givenname: Pan surname: Liu fullname: Liu, Pan organization: School of Earth and Atmospheric Sciences – sequence: 7 givenname: Jianming surname: Bai fullname: Bai, Jianming organization: National Synchrotron Light Source II – sequence: 8 givenname: Wenqian surname: Xu fullname: Xu, Wenqian organization: Argonne National Laboratory – sequence: 9 givenname: Yuanzhi orcidid: 0000-0002-7741-8646 surname: Tang fullname: Tang, Yuanzhi organization: School of Earth and Atmospheric Sciences – sequence: 10 givenname: Yan-Yan orcidid: 0000-0003-0677-5897 surname: Hu fullname: Hu, Yan-Yan organization: National High Magnetic Field Laboratory – sequence: 11 givenname: Meilin orcidid: 0000-0002-6188-2372 surname: Liu fullname: Liu, Meilin organization: School of Materials Science and Engineering – sequence: 12 givenname: Hailong orcidid: 0000-0001-8283-2860 surname: Chen fullname: Chen, Hailong email: hailong.chen@me.gatech.edu organization: The Woodruff School of Mechanical Engineering |
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| Snippet | While sodium-ion batteries (SIBs) hold great promise for large-scale electric energy storage and low speed electric vehicles, the poor capacity retention of... |
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| SubjectTerms | batteries cathodes electric potential difference electric power electric vehicles ENERGY STORAGE lithium nuclear magnetic resonance spectroscopy phase transition X-ray diffraction |
| Title | Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries |
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