Ester-Linked Crystalline Covalent Organic Frameworks

Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D s...

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Published inJournal of the American Chemical Society Vol. 142; no. 34; pp. 14450 - 14454
Main Authors Zhao, Chenfei, Lyu, Hao, Ji, Zhe, Zhu, Chenhui, Yaghi, Omar M
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 26.08.2020
American Chemical Society (ACS)
Subjects
Americans
aromatic compounds
coordination polymers
covalent organic frameworks
crystallization
Crystallography, X-Ray
Esters - chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
materials
Models, Molecular
Molecular Structure
organic compounds
Particle Size
phenol
physical and chemical processes
polyesters
Polyesters - chemistry
Polyethylene Terephthalates - chemistry
Porosity
surface area
Surface Properties
topology
transesterification
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Abstract Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal–organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
AbstractList Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal-organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal-organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal–organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m²/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal–organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in (COF-119) and (COF-120, 121, 122) topologies with surface areas of up to 2092 m /g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal-organic frameworks. This work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions between ditopic 2-pyridinyl aromatic carboxylates and tri- or tetratopic phenols gave the corresponding ester-linked COFs. They crystallize as 2D structures in kgm (COF-119) and hcb (COF-120, 121, 122) topologies with surface areas of up to 2092 m2/g. Notably, crystalline COF-122 comprises edges spanning over 10 phenylene units, an aspect that had only been achieved in metal-organic frameworks. Finally, this work expands the scope of reticular chemistry to include, for the first time, crystalline ester-linked COFs related to common polyesters.
Author Yaghi, Omar M
Ji, Zhe
Zhu, Chenhui
Lyu, Hao
Zhao, Chenfei
AuthorAffiliation Department of Chemistry, Kavli Energy Nanoscience Institute, and Berkeley Global Science Institute
Advanced Light Source
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/32786782$$D View this record in MEDLINE/PubMed
https://www.osti.gov/servlets/purl/1777958$$D View this record in Osti.gov
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Snippet Ester-linked, crystalline, porous covalent organic frameworks (COFs) have been synthesized and structurally characterized. Transesterification reactions...
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SubjectTerms Americans
aromatic compounds
coordination polymers
covalent organic frameworks
crystallization
Crystallography, X-Ray
Esters - chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
materials
Models, Molecular
Molecular Structure
organic compounds
Particle Size
phenol
physical and chemical processes
polyesters
Polyesters - chemistry
Polyethylene Terephthalates - chemistry
Porosity
surface area
Surface Properties
topology
transesterification
Title Ester-Linked Crystalline Covalent Organic Frameworks
URI http://dx.doi.org/10.1021/jacs.0c07015
https://www.ncbi.nlm.nih.gov/pubmed/32786782
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